百科

(2R,3R,4R,6S)-4-(((2R,4R,5R,6R)-5-(benzoyloxy)-4-((tert-butyldimethylsilyl)oxy)-6-methyltetrahydro-2H-pyran-2-yl)oxy)-6-methoxy-2-methyltetrahydro-2H-pyran-3-yl benzoate

(2R,3R,4R,6S)-4-(((2R,4R,5R,6R)-5-(benzoyloxy)-4-((tert-butyldimethylsilyl)oxy)-6-methyltetrahydro-2H-pyran-2-yl)oxy)-6-methoxy-2-methyltetrahydro-2H-pyran-3-yl benzoate

CAS号：381727-56-6

英文名：(2R,3R,4R,6S)-4-(((2R,4R,5R,6R)-5-(benzoyloxy)-4-((tert-butyldimethylsilyl)oxy)-6-methyltetrahydro-2H-pyran-2-yl)oxy)-6-methoxy-2-methyltetrahydro-2H-pyran-3-yl benzoate

分子式：C33H46O9Si

分子量：614.798

合成路线

Benzoic acid (2R,3R,4R,6S)-4-(tert-butyl-dimethyl-silanyloxy)-6-methoxy-2-methyl-tetrahydro-pyran-3-yl ester

Benzoic acid (2R,3R,4R,6S)-4-(tert-butyl-dimethyl-silanyloxy)-6-methoxy-2-methyl-tetrahydro-pyran-3-yl ester

(2R,3R,4R,6S)-4-(((2R,4R,5R,6R)-5-(benzoyloxy)-4-((tert-butyldimethylsilyl)oxy)-6-methyltetrahydro-2H-pyran-2-yl)oxy)-6-methoxy-2-methyltetrahydro-2H-pyran-3-yl benzoate

(2R,3R,4R,6S)-4-(((2R,4R,5R,6R)-5-(benzoyloxy)-4-((tert-butyldimethylsilyl)oxy)-6-methyltetrahydro-2H-pyran-2-yl)oxy)-6-methoxy-2-methyltetrahydro-2H-pyran-3-yl benzoate

(2R,3R,4R,6S)-4-(((2R,3S,4S,5R,6R)-5-(benzoyloxy)-4-((tert-butyldimethylsilyl)oxy)-3-iodo-6-methyltetrahydro-2H-pyran-2-yl)oxy)-6-methoxy-2-methyltetrahydro-2H-pyran-3-yl benzoate

(2R,3R,4R,6S)-4-(((2R,3S,4S,5R,6R)-5-(benzoyloxy)-4-((tert-butyldimethylsilyl)oxy)-3-iodo-6-methyltetrahydro-2H-pyran-2-yl)oxy)-6-methoxy-2-methyltetrahydro-2H-pyran-3-yl benzoate

(2R,3R,4R,6S)-4-(((2R,4R,5R,6R)-5-(benzoyloxy)-4-((tert-butyldimethylsilyl)oxy)-6-methyltetrahydro-2H-pyran-2-yl)oxy)-6-methoxy-2-methyltetrahydro-2H-pyran-3-yl benzoate

(2R,3R,4R,6S)-4-(((2R,4R,5R,6R)-5-(benzoyloxy)-4-((tert-butyldimethylsilyl)oxy)-6-methyltetrahydro-2H-pyran-2-yl)oxy)-6-methoxy-2-methyltetrahydro-2H-pyran-3-yl benzoate

methyl 4-O-benzoyl-2,6-dideoxy-α-D-arabino-hexopyranoside

methyl 4-O-benzoyl-2,6-dideoxy-α-D-arabino-hexopyranoside

(2R,3R,4R,6S)-4-(((2R,4R,5R,6R)-5-(benzoyloxy)-4-((tert-butyldimethylsilyl)oxy)-6-methyltetrahydro-2H-pyran-2-yl)oxy)-6-methoxy-2-methyltetrahydro-2H-pyran-3-yl benzoate

(2R,3R,4R,6S)-4-(((2R,4R,5R,6R)-5-(benzoyloxy)-4-((tert-butyldimethylsilyl)oxy)-6-methyltetrahydro-2H-pyran-2-yl)oxy)-6-methoxy-2-methyltetrahydro-2H-pyran-3-yl benzoate

methyl 4-O-benzoyl-3-O-tert-butyldimethylsilyl-2,6-dideoxy-2-iodo-α-D-manno-hexopyranoside

methyl 4-O-benzoyl-3-O-tert-butyldimethylsilyl-2,6-dideoxy-2-iodo-α-D-manno-hexopyranoside

(2R,3R,4R,6S)-4-(((2R,4R,5R,6R)-5-(benzoyloxy)-4-((tert-butyldimethylsilyl)oxy)-6-methyltetrahydro-2H-pyran-2-yl)oxy)-6-methoxy-2-methyltetrahydro-2H-pyran-3-yl benzoate

(2R,3R,4R,6S)-4-(((2R,4R,5R,6R)-5-(benzoyloxy)-4-((tert-butyldimethylsilyl)oxy)-6-methyltetrahydro-2H-pyran-2-yl)oxy)-6-methoxy-2-methyltetrahydro-2H-pyran-3-yl benzoate

上游原料

methyl 4-O-benzoyl-2,6-dideoxy-α-D-arabino-hexopyranoside (2R,3R,4R,6S)-4-(((2R,3S,4S,5R,6R)-5-(benzoyloxy)-4-((tert-butyldimethylsilyl)oxy)-3-iodo-6-methyltetrahydro-2H-pyran-2-yl)oxy)-6-methoxy-2-methyltetrahydro-2H-pyran-3-yl benzoate Benzoic acid (2R,3R,4R,6S)-4-(tert-butyl-dimethyl-silanyloxy)-6-methoxy-2-methyl-tetrahydro-pyran-3-yl ester methyl 4-O-benzoyl-3-O-tert-butyldimethylsilyl-2,6-dideoxy-2-iodo-α-D-manno-hexopyranoside

下游产品

(2R,3R,4R,6S)-4-(((2R,4R,5S,6R)-5-(benzoyloxy)-4-hydroxy-6-methyltetrahydro-2H-pyran-2-yl)oxy)-6-methoxy-2-methyltetrahydro-2H-pyran-3-yl benzoate