百科

(1S,6R)-4-bromo-3-(((tert-butyldiphenylsilyl)oxy)methyl)-5',5'-diethyl-7-oxaspiro[bicyclo[4.1.0]heptane-2,2'-[1,3]dioxan]-3-en-5-one

(1S,6R)-4-bromo-3-(((tert-butyldiphenylsilyl)oxy)methyl)-5',5'-diethyl-7-oxaspiro[bicyclo[4.1.0]heptane-2,2'-[1,3]dioxan]-3-en-5-one

CAS号：382654-92-4

英文名：(1S,6R)-4-bromo-3-(((tert-butyldiphenylsilyl)oxy)methyl)-5',5'-diethyl-7-oxaspiro[bicyclo[4.1.0]heptane-2,2'-[1,3]dioxan]-3-en-5-one

分子式：C30H37BrO5Si

分子量：585.601

合成路线

8-Bromo-7-(tert-butyl-diphenyl-silanyloxymethyl)-3,3-diethyl-1,5-dioxa-spiro[5.5]undeca-7,10-dien-9-one

8-Bromo-7-(tert-butyl-diphenyl-silanyloxymethyl)-3,3-diethyl-1,5-dioxa-spiro[5.5]undeca-7,10-dien-9-one

(1S,6R)-4-bromo-3-(((tert-butyldiphenylsilyl)oxy)methyl)-5',5'-diethyl-7-oxaspiro[bicyclo[4.1.0]heptane-2,2'-[1,3]dioxan]-3-en-5-one

(1S,6R)-4-bromo-3-(((tert-butyldiphenylsilyl)oxy)methyl)-5',5'-diethyl-7-oxaspiro[bicyclo[4.1.0]heptane-2,2'-[1,3]dioxan]-3-en-5-one

(1R,6S)-4-bromo-3-(((tert-butyldiphenylsilyl)oxy)methyl)-5',5'-diethyl-7-oxaspiro[bicyclo[4.1.0]heptane-2,2'-[1,3]dioxan]-3-en-5-one

(1R,6S)-4-bromo-3-(((tert-butyldiphenylsilyl)oxy)methyl)-5',5'-diethyl-7-oxaspiro[bicyclo[4.1.0]heptane-2,2'-[1,3]dioxan]-3-en-5-one

上游原料

8-Bromo-7-(tert-butyl-diphenyl-silanyloxymethyl)-3,3-diethyl-1,5-dioxa-spiro[5.5]undeca-7,10-dien-9-one

下游产品

(1S,5R,6S)-5-Hydroxy-3-hydroxymethyl-4-((E)-propenyl)-7-oxa-bicyclo[4.1.0]hept-3-en-2-one (1S,5R,6S)-3-(tert-Butyl-diphenyl-silanyloxymethyl)-5-hydroxy-4-((2R,3R)-3-propyl-oxiranyl)-7-oxa-bicyclo[4.1.0]hept-3-en-2-one