百科

(1S,4'R,6R,6'R)-3-(((tert-butyldiphenylsilyl)oxy)methyl)-4',6'-dimethyl-4-((E)-pent-1-en-1-yl)-7-oxaspiro[bicyclo[4.1.0]heptane-2,2'-[1,3]dioxan]-3-en-5-one

(1S,4'R,6R,6'R)-3-(((tert-butyldiphenylsilyl)oxy)methyl)-4',6'-dimethyl-4-((E)-pent-1-en-1-yl)-7-oxaspiro[bicyclo[4.1.0]heptane-2,2'-[1,3]dioxan]-3-en-5-one

CAS号：382654-99-1

英文名：(1S,4'R,6R,6'R)-3-(((tert-butyldiphenylsilyl)oxy)methyl)-4',6'-dimethyl-4-((E)-pent-1-en-1-yl)-7-oxaspiro[bicyclo[4.1.0]heptane-2,2'-[1,3]dioxan]-3-en-5-one

分子式：C33H42O5Si

分子量：546.769

合成路线

2-Bromo-3-(tert-butyl-diphenyl-silanyloxymethyl)-4,4-dimethoxy-cyclohexa-2,5-dienone

2-Bromo-3-(tert-butyl-diphenyl-silanyloxymethyl)-4,4-dimethoxy-cyclohexa-2,5-dienone

(1S,4'R,6R,6'R)-3-(((tert-butyldiphenylsilyl)oxy)methyl)-4',6'-dimethyl-4-((E)-pent-1-en-1-yl)-7-oxaspiro[bicyclo[4.1.0]heptane-2,2'-[1,3]dioxan]-3-en-5-one

(1S,4'R,6R,6'R)-3-(((tert-butyldiphenylsilyl)oxy)methyl)-4',6'-dimethyl-4-((E)-pent-1-en-1-yl)-7-oxaspiro[bicyclo[4.1.0]heptane-2,2'-[1,3]dioxan]-3-en-5-one

(2R,4R)-8-Bromo-7-(tert-butyl-diphenyl-silanyloxymethyl)-2,4-dimethyl-1,5-dioxa-spiro[5.5]undeca-7,10-dien-9-one

(2R,4R)-8-Bromo-7-(tert-butyl-diphenyl-silanyloxymethyl)-2,4-dimethyl-1,5-dioxa-spiro[5.5]undeca-7,10-dien-9-one

(1S,4'R,6R,6'R)-3-(((tert-butyldiphenylsilyl)oxy)methyl)-4',6'-dimethyl-4-((E)-pent-1-en-1-yl)-7-oxaspiro[bicyclo[4.1.0]heptane-2,2'-[1,3]dioxan]-3-en-5-one

(1S,4'R,6R,6'R)-3-(((tert-butyldiphenylsilyl)oxy)methyl)-4',6'-dimethyl-4-((E)-pent-1-en-1-yl)-7-oxaspiro[bicyclo[4.1.0]heptane-2,2'-[1,3]dioxan]-3-en-5-one

2-bromo-3-[[[(1,1-dimethylethyl)diphenylsilyl]oxy]methyl]-4-methoxyphenol

2-bromo-3-[[[(1,1-dimethylethyl)diphenylsilyl]oxy]methyl]-4-methoxyphenol

(1S,4'R,6R,6'R)-3-(((tert-butyldiphenylsilyl)oxy)methyl)-4',6'-dimethyl-4-((E)-pent-1-en-1-yl)-7-oxaspiro[bicyclo[4.1.0]heptane-2,2'-[1,3]dioxan]-3-en-5-one

(1S,4'R,6R,6'R)-3-(((tert-butyldiphenylsilyl)oxy)methyl)-4',6'-dimethyl-4-((E)-pent-1-en-1-yl)-7-oxaspiro[bicyclo[4.1.0]heptane-2,2'-[1,3]dioxan]-3-en-5-one

上游原料

(2R,4R)-8-Bromo-7-(tert-butyl-diphenyl-silanyloxymethyl)-2,4-dimethyl-1,5-dioxa-spiro[5.5]undeca-7,10-dien-9-one 2-Bromo-3-(tert-butyl-diphenyl-silanyloxymethyl)-4,4-dimethoxy-cyclohexa-2,5-dienone 2-bromo-3-[[[(1,1-dimethylethyl)diphenylsilyl]oxy]methyl]-4-methoxyphenol

下游产品

(1S,5R,6S)-3-(tert-Butyl-diphenyl-silanyloxymethyl)-5-hydroxy-4-((2R,3R)-3-propyl-oxiranyl)-7-oxa-bicyclo[4.1.0]hept-3-en-2-one