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(3aR,4R,5R,6S,6aS)-ethyl 5-benzylsulfanyl-6-hydroxy-2,2-dimethyltetrahydro-3aH-cyclopenta[1,3]dioxole-4-carboxylate

(3aR,4R,5R,6S,6aS)-ethyl 5-benzylsulfanyl-6-hydroxy-2,2-dimethyltetrahydro-3aH-cyclopenta[1,3]dioxole-4-carboxylate

CAS号：384343-93-5

英文名：(3aR,4R,5R,6S,6aS)-ethyl 5-benzylsulfanyl-6-hydroxy-2,2-dimethyltetrahydro-3aH-cyclopenta[1,3]dioxole-4-carboxylate

分子式：C18H24O5S

分子量：352.445

合成路线

(E)-ethyl (4R,5R)-4,5-dihydroxy-6-(4-methoxybenzyloxy)hex-2-enoate

(E)-ethyl (4R,5R)-4,5-dihydroxy-6-(4-methoxybenzyloxy)hex-2-enoate

(3aR,4R,5R,6S,6aS)-ethyl 5-benzylsulfanyl-6-hydroxy-2,2-dimethyltetrahydro-3aH-cyclopenta[1,3]dioxole-4-carboxylate

(3aR,4R,5R,6S,6aS)-ethyl 5-benzylsulfanyl-6-hydroxy-2,2-dimethyltetrahydro-3aH-cyclopenta[1,3]dioxole-4-carboxylate

(E)-ethyl 3-[(4R,5R)-5-(4-methoxybenzyloxymethyl)-2,2-dimethyl-1,3-dioxolan-4-yl]prop-2-enoate

(E)-ethyl 3-[(4R,5R)-5-(4-methoxybenzyloxymethyl)-2,2-dimethyl-1,3-dioxolan-4-yl]prop-2-enoate

(3aR,4R,5R,6S,6aS)-ethyl 5-benzylsulfanyl-6-hydroxy-2,2-dimethyltetrahydro-3aH-cyclopenta[1,3]dioxole-4-carboxylate

(3aR,4R,5R,6S,6aS)-ethyl 5-benzylsulfanyl-6-hydroxy-2,2-dimethyltetrahydro-3aH-cyclopenta[1,3]dioxole-4-carboxylate

(E)-ethyl (4R,5R)-4,5-bis(tert-butyldimethylsiloxy)-6-hydroxyhex-2-enoate

(E)-ethyl (4R,5R)-4,5-bis(tert-butyldimethylsiloxy)-6-hydroxyhex-2-enoate

(3aR,4R,5R,6S,6aS)-ethyl 5-benzylsulfanyl-6-hydroxy-2,2-dimethyltetrahydro-3aH-cyclopenta[1,3]dioxole-4-carboxylate

(3aR,4R,5R,6S,6aS)-ethyl 5-benzylsulfanyl-6-hydroxy-2,2-dimethyltetrahydro-3aH-cyclopenta[1,3]dioxole-4-carboxylate

(E)-ethyl (4R,5R)-4,5-bis(tert-butyldimethylsiloxy)-6-(4-methoxybenzyloxy)hex-2-enoate

(E)-ethyl (4R,5R)-4,5-bis(tert-butyldimethylsiloxy)-6-(4-methoxybenzyloxy)hex-2-enoate

(3aR,4R,5R,6S,6aS)-ethyl 5-benzylsulfanyl-6-hydroxy-2,2-dimethyltetrahydro-3aH-cyclopenta[1,3]dioxole-4-carboxylate

(3aR,4R,5R,6S,6aS)-ethyl 5-benzylsulfanyl-6-hydroxy-2,2-dimethyltetrahydro-3aH-cyclopenta[1,3]dioxole-4-carboxylate

(1R,2R,3S,4R,5R)-ethyl 2-benzylsulfanyl-3,4-bis(tert-butyldimethylsiloxy)-5-hydroxycyclopentanecarboxylate

(1R,2R,3S,4R,5R)-ethyl 2-benzylsulfanyl-3,4-bis(tert-butyldimethylsiloxy)-5-hydroxycyclopentanecarboxylate

(3aR,4R,5R,6S,6aS)-ethyl 5-benzylsulfanyl-6-hydroxy-2,2-dimethyltetrahydro-3aH-cyclopenta[1,3]dioxole-4-carboxylate

(3aR,4R,5R,6S,6aS)-ethyl 5-benzylsulfanyl-6-hydroxy-2,2-dimethyltetrahydro-3aH-cyclopenta[1,3]dioxole-4-carboxylate

(1R,2R,3S,4R,5R)-ethyl 2-benzylsulfanyl-3,5-bis(tert-butyldimethylsiloxy)-4-hydroxycyclopentanecarboxylate

(1R,2R,3S,4R,5R)-ethyl 2-benzylsulfanyl-3,5-bis(tert-butyldimethylsiloxy)-4-hydroxycyclopentanecarboxylate

(3aR,4R,5R,6S,6aS)-ethyl 5-benzylsulfanyl-6-hydroxy-2,2-dimethyltetrahydro-3aH-cyclopenta[1,3]dioxole-4-carboxylate

(3aR,4R,5R,6S,6aS)-ethyl 5-benzylsulfanyl-6-hydroxy-2,2-dimethyltetrahydro-3aH-cyclopenta[1,3]dioxole-4-carboxylate

上游原料

(E)-ethyl (4R,5R)-4,5-bis(tert-butyldimethylsiloxy)-6-(4-methoxybenzyloxy)hex-2-enoate (E)-ethyl (4R,5R)-4,5-dihydroxy-6-(4-methoxybenzyloxy)hex-2-enoate (E)-ethyl (4R,5R)-4,5-bis(tert-butyldimethylsiloxy)-6-hydroxyhex-2-enoate (1R,2R,3S,4R,5R)-ethyl 2-benzylsulfanyl-3,5-bis(tert-butyldimethylsiloxy)-4-hydroxycyclopentanecarboxylate (1R,2R,3S,4R,5R)-ethyl 2-benzylsulfanyl-3,4-bis(tert-butyldimethylsiloxy)-5-hydroxycyclopentanecarboxylate (E)-ethyl 3-[(4R,5R)-5-(4-methoxybenzyloxymethyl)-2,2-dimethyl-1,3-dioxolan-4-yl]prop-2-enoate

下游产品

(3aR,6aR)-ethyl 2,2-dimethyl-6-oxo-6,6a-dihydro-3aH-cyclopenta[1,3]dioxole-4-carboxylate (3aS,4S,6aR)-6-hydroxymethyl-2,2-dimethyl-4,6a-dihydro-3aH-cyclopenta[1,3]dioxol-4-ol (3aS,4S,6aR)-6-{{[(1,1-dimethylethyl)dimethylsilyl]oxy}methyl}-3a,6a-dihydro-2,2-dimethyl-4H-cyclopenta[d]-1,3-dioxol-4-ol (3aR,6R,6aS)-ethyl 6-hydroxy-2,2-dimethyl-6,6a-dihydro-3aH-cyclopenta[1,3]dioxole-4-carboxylate