百科

(2R,4aR,6R,7R,8R,8aS)-8-((2S,3S,4R,5R,6R)-4,5-Bis-benzyloxy-6-benzyloxymethyl-3-hydroxy-tetrahydro-pyran-2-ylmethyl)-6-methoxy-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-7-ol

(2R,4aR,6R,7R,8R,8aS)-8-((2S,3S,4R,5R,6R)-4,5-Bis-benzyloxy-6-benzyloxymethyl-3-hydroxy-tetrahydro-pyran-2-ylmethyl)-6-methoxy-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-7-ol

CAS号：384819-77-6

英文名：(2R,4aR,6R,7R,8R,8aS)-8-((2S,3S,4R,5R,6R)-4,5-Bis-benzyloxy-6-benzyloxymethyl-3-hydroxy-tetrahydro-pyran-2-ylmethyl)-6-methoxy-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-7-ol

分子式：C42H48O10

分子量：712.825

合成路线

((3R,4S,5R,6R)-4,5-Bis-benzyloxy-6-benzyloxymethyl-2-methylene-tetrahydro-pyran-3-yloxy)-((2R,4aR,6R,7S,8R,8aR)-8-iodo-6-methoxy-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-7-yloxy)-dimethyl-silane

((3R,4S,5R,6R)-4,5-Bis-benzyloxy-6-benzyloxymethyl-2-methylene-tetrahydro-pyran-3-yloxy)-((2R,4aR,6R,7S,8R,8aR)-8-iodo-6-methoxy-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-7-yloxy)-dimethyl-silane

(2R,4aR,6R,7R,8R,8aS)-8-((2S,3S,4R,5R,6R)-4,5-Bis-benzyloxy-6-benzyloxymethyl-3-hydroxy-tetrahydro-pyran-2-ylmethyl)-6-methoxy-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-7-ol

(2R,4aR,6R,7R,8R,8aS)-8-((2S,3S,4R,5R,6R)-4,5-Bis-benzyloxy-6-benzyloxymethyl-3-hydroxy-tetrahydro-pyran-2-ylmethyl)-6-methoxy-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-7-ol

2,6-anhydro-4,5,7-tri-O-benzyl-1-deoxy-D-gluco-1-heptenitol

2,6-anhydro-4,5,7-tri-O-benzyl-1-deoxy-D-gluco-1-heptenitol

(2R,4aR,6R,7R,8R,8aS)-8-((2S,3S,4R,5R,6R)-4,5-Bis-benzyloxy-6-benzyloxymethyl-3-hydroxy-tetrahydro-pyran-2-ylmethyl)-6-methoxy-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-7-ol

(2R,4aR,6R,7R,8R,8aS)-8-((2S,3S,4R,5R,6R)-4,5-Bis-benzyloxy-6-benzyloxymethyl-3-hydroxy-tetrahydro-pyran-2-ylmethyl)-6-methoxy-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-7-ol

2-O-acetyl-3,4,6-tri-O-benzyl-D-glucono-1,5-lactone

2-O-acetyl-3,4,6-tri-O-benzyl-D-glucono-1,5-lactone

(2R,4aR,6R,7R,8R,8aS)-8-((2S,3S,4R,5R,6R)-4,5-Bis-benzyloxy-6-benzyloxymethyl-3-hydroxy-tetrahydro-pyran-2-ylmethyl)-6-methoxy-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-7-ol

(2R,4aR,6R,7R,8R,8aS)-8-((2S,3S,4R,5R,6R)-4,5-Bis-benzyloxy-6-benzyloxymethyl-3-hydroxy-tetrahydro-pyran-2-ylmethyl)-6-methoxy-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-7-ol

上游原料

((3R,4S,5R,6R)-4,5-Bis-benzyloxy-6-benzyloxymethyl-2-methylene-tetrahydro-pyran-3-yloxy)-((2R,4aR,6R,7S,8R,8aR)-8-iodo-6-methoxy-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-7-yloxy)-dimethyl-silane 2-O-acetyl-3,4,6-tri-O-benzyl-D-glucono-1,5-lactone 2,6-anhydro-4,5,7-tri-O-benzyl-1-deoxy-D-gluco-1-heptenitol

下游产品

(2S,3R,4R,5S,6R)-2-((2R,3S,4S,5R,6R)-3,5-Dihydroxy-2-hydroxymethyl-6-methoxy-tetrahydro-pyran-4-ylmethyl)-6-hydroxymethyl-tetrahydro-pyran-3,4,5-triol