methyl (2R,3S,4S,5R,6S,7R,8E,10S)-7,11-bis[(1,1-dimethylethyl)dimethylsilyloxy]-2,3-dihydroxy-5-(4-methoxybenzyloxy)-4,6,8,10-tetramethyl-8-undecenoate

CAS号：385443-59-4

英文名：methyl (2R,3S,4S,5R,6S,7R,8E,10S)-7,11-bis[(1,1-dimethylethyl)dimethylsilyloxy]-2,3-dihydroxy-5-(4-methoxybenzyloxy)-4,6,8,10-tetramethyl-8-undecenoate

分子式：C36H66O8Si2

分子量：683.075

合成路线

385443-64-1

(2S,3R,4R,5R,6E,8S)-9-[(1,1-dimethylethyl)dimethylsilyloxy]-5-hydroxy-1,3-(4-methoxybenzylidenedioxy)-2,4,6,8-tetramethyl-6-nonene

385443-59-4

methyl (2R,3S,4S,5R,6S,7R,8E,10S)-7,11-bis[(1,1-dimethylethyl)dimethylsilyloxy]-2,3-dihydroxy-5-(4-methoxybenzyloxy)-4,6,8,10-tetramethyl-8-undecenoate

385443-58-3

(2S,3R,4S,5R,6E,8S)-5,9-bis[(1,1-dimethylethyl)dimethylsilyloxy]-3-(4-methoxybenzyloxy)-2,4,6,8-tetramethyl-6-nonenol

385443-59-4

methyl (2R,3S,4S,5R,6S,7R,8E,10S)-7,11-bis[(1,1-dimethylethyl)dimethylsilyloxy]-2,3-dihydroxy-5-(4-methoxybenzyloxy)-4,6,8,10-tetramethyl-8-undecenoate

385443-61-8

(2E,4S)-5-[(1,1-dimethylethyl)dimethylsilyloxy]-2,4-dimethylpentenol

385443-59-4

methyl (2R,3S,4S,5R,6S,7R,8E,10S)-7,11-bis[(1,1-dimethylethyl)dimethylsilyloxy]-2,3-dihydroxy-5-(4-methoxybenzyloxy)-4,6,8,10-tetramethyl-8-undecenoate

385443-74-3

methyl (2E,4S,5R,6S,7R,8E,10S)-7,11-bis[(1,1-dimethylethyl)dimethylsilyloxy]-5-(4-methoxybenzyloxy)-4,6,8,10-tetramethyl-2,8-undecadienoate

385443-59-4

methyl (2R,3S,4S,5R,6S,7R,8E,10S)-7,11-bis[(1,1-dimethylethyl)dimethylsilyloxy]-2,3-dihydroxy-5-(4-methoxybenzyloxy)-4,6,8,10-tetramethyl-8-undecenoate

385443-54-9

(2S,3R,4S,5R,6E,8S)-9-[(1,1-dimethylethyl)dimethylsilyloxy]-1-(4-methoxybenzyloxy)-2,4,6,8-tetramethyl-6-nonene-3,5-diol

385443-59-4

methyl (2R,3S,4S,5R,6S,7R,8E,10S)-7,11-bis[(1,1-dimethylethyl)dimethylsilyloxy]-2,3-dihydroxy-5-(4-methoxybenzyloxy)-4,6,8,10-tetramethyl-8-undecenoate

385443-62-9

(2S,4R,5R,6E,8S)-9-[(1,1-dimethylethyl)dimethylsilyloxy]-5-hydroxy-1-(4-methoxybenzyloxy)-2,4,6,8-tetramethyl-6-nonen-3-one

385443-59-4

methyl (2R,3S,4S,5R,6S,7R,8E,10S)-7,11-bis[(1,1-dimethylethyl)dimethylsilyloxy]-2,3-dihydroxy-5-(4-methoxybenzyloxy)-4,6,8,10-tetramethyl-8-undecenoate

上游原料

(2S,3R,4S,5R,6E,8S)-9-[(1,1-dimethylethyl)dimethylsilyloxy]-1-(4-methoxybenzyloxy)-2,4,6,8-tetramethyl-6-nonene-3,5-diol (2S,3R,4S,5R,6E,8S)-5,9-bis[(1,1-dimethylethyl)dimethylsilyloxy]-3-(4-methoxybenzyloxy)-2,4,6,8-tetramethyl-6-nonenol (2S,4R,5R,6E,8S)-9-[(1,1-dimethylethyl)dimethylsilyloxy]-5-hydroxy-1-(4-methoxybenzyloxy)-2,4,6,8-tetramethyl-6-nonen-3-one (2E,4S)-5-[(1,1-dimethylethyl)dimethylsilyloxy]-2,4-dimethylpentenol methyl (2E,4S,5R,6S,7R,8E,10S)-7,11-bis[(1,1-dimethylethyl)dimethylsilyloxy]-5-(4-methoxybenzyloxy)-4,6,8,10-tetramethyl-2,8-undecadienoate (2S,3R,4R,5R,6E,8S)-9-[(1,1-dimethylethyl)dimethylsilyloxy]-5-hydroxy-1,3-(4-methoxybenzylidenedioxy)-2,4,6,8-tetramethyl-6-nonene

下游产品

methyl (2R,3S,4R,5R,6S,7R,8E,10S)-2,7-bis[(1,1-dimethylethyl)dimethylsilyloxy]-11-hydroxy-3-methoxy-5-(4-methoxybenzyloxy)-4,6,8,10-tetramethyl-8-dodecenoate methyl (2R,3S,4R,5R,6S,7R,8E,10S)-2,7-bis[(1,1-dimethylethyl)dimethylsilyloxy]-11-hydroxy-3-methoxy-5-(4-methoxybenzyloxy)-4,6,8,10-tetramethyl-8-undecenoate