百科

4-hydroxy-4-hydroxymethyl-7-methoxymethoxy-2,2-dimethyl-5-tert-butyldimethylsilyloxy-(3aS,4S,5S,7S,7aS)-perhydrobenzo[d][1,3]dioxol-4-ol

4-hydroxy-4-hydroxymethyl-7-methoxymethoxy-2,2-dimethyl-5-tert-butyldimethylsilyloxy-(3aS,4S,5S,7S,7aS)-perhydrobenzo[d][1,3]dioxol-4-ol

CAS号：385810-41-3

英文名：4-hydroxy-4-hydroxymethyl-7-methoxymethoxy-2,2-dimethyl-5-tert-butyldimethylsilyloxy-(3aS,4S,5S,7S,7aS)-perhydrobenzo[d][1,3]dioxol-4-ol

分子式：C18H36O7Si

分子量：392.56

合成路线

7-methoxymethoxy-2,2-dimethyl-4-methylene-5-tert-butyldimethylsilyloxy-(3aR,5S,7S,7aS)-perhydrobenzo[d][1,3]dioxole

7-methoxymethoxy-2,2-dimethyl-4-methylene-5-tert-butyldimethylsilyloxy-(3aR,5S,7S,7aS)-perhydrobenzo[d][1,3]dioxole

4-hydroxy-4-hydroxymethyl-7-methoxymethoxy-2,2-dimethyl-5-tert-butyldimethylsilyloxy-(3aS,4S,5S,7S,7aS)-perhydrobenzo[d][1,3]dioxol-4-ol

4-hydroxy-4-hydroxymethyl-7-methoxymethoxy-2,2-dimethyl-5-tert-butyldimethylsilyloxy-(3aS,4S,5S,7S,7aS)-perhydrobenzo[d][1,3]dioxol-4-ol

2-[6-chloromethyl-2,2-dimethyl-(3aS,4S,6S,6aS)-perhydrofuro[3,4-d][1,3]dioxol-4-yl]-1-ethanol

2-[6-chloromethyl-2,2-dimethyl-(3aS,4S,6S,6aS)-perhydrofuro[3,4-d][1,3]dioxol-4-yl]-1-ethanol

4-hydroxy-4-hydroxymethyl-7-methoxymethoxy-2,2-dimethyl-5-tert-butyldimethylsilyloxy-(3aS,4S,5S,7S,7aS)-perhydrobenzo[d][1,3]dioxol-4-ol

4-hydroxy-4-hydroxymethyl-7-methoxymethoxy-2,2-dimethyl-5-tert-butyldimethylsilyloxy-(3aS,4S,5S,7S,7aS)-perhydrobenzo[d][1,3]dioxol-4-ol

7-methoxymethoxy-2,2-dimethyl-4-methylene-(3aR,5S,7S,7aS)-perhydrobenzo[d][1,3]dioxol-5-ol

7-methoxymethoxy-2,2-dimethyl-4-methylene-(3aR,5S,7S,7aS)-perhydrobenzo[d][1,3]dioxol-5-ol

4-hydroxy-4-hydroxymethyl-7-methoxymethoxy-2,2-dimethyl-5-tert-butyldimethylsilyloxy-(3aS,4S,5S,7S,7aS)-perhydrobenzo[d][1,3]dioxol-4-ol

4-hydroxy-4-hydroxymethyl-7-methoxymethoxy-2,2-dimethyl-5-tert-butyldimethylsilyloxy-(3aS,4S,5S,7S,7aS)-perhydrobenzo[d][1,3]dioxol-4-ol

ethyl 2-[6-chloromethyl-2,2-dimethyl-(3aS,4S,6S,6aS)-perhydrofuro[3,4-d][1,3]dioxol-4-yl]acetate

ethyl 2-[6-chloromethyl-2,2-dimethyl-(3aS,4S,6S,6aS)-perhydrofuro[3,4-d][1,3]dioxol-4-yl]acetate

4-hydroxy-4-hydroxymethyl-7-methoxymethoxy-2,2-dimethyl-5-tert-butyldimethylsilyloxy-(3aS,4S,5S,7S,7aS)-perhydrobenzo[d][1,3]dioxol-4-ol

4-hydroxy-4-hydroxymethyl-7-methoxymethoxy-2,2-dimethyl-5-tert-butyldimethylsilyloxy-(3aS,4S,5S,7S,7aS)-perhydrobenzo[d][1,3]dioxol-4-ol

1-[5-(1-ethynyl)-2,2-dimethyl-(4S,5R)-1,3-dioxolan-4-yl]-3-tert-butyldimethylsilyloxy-(1S)-propan-1-ol

1-[5-(1-ethynyl)-2,2-dimethyl-(4S,5R)-1,3-dioxolan-4-yl]-3-tert-butyldimethylsilyloxy-(1S)-propan-1-ol

4-hydroxy-4-hydroxymethyl-7-methoxymethoxy-2,2-dimethyl-5-tert-butyldimethylsilyloxy-(3aS,4S,5S,7S,7aS)-perhydrobenzo[d][1,3]dioxol-4-ol

4-hydroxy-4-hydroxymethyl-7-methoxymethoxy-2,2-dimethyl-5-tert-butyldimethylsilyloxy-(3aS,4S,5S,7S,7aS)-perhydrobenzo[d][1,3]dioxol-4-ol

4-(1-ethynyl)-5-(1-methoxymethoxy-3-tert-butyldimethylsilyloxy-(1S)-propyl)-2,2-dimethyl-(4R,5S)-1,3-dioxolane

4-(1-ethynyl)-5-(1-methoxymethoxy-3-tert-butyldimethylsilyloxy-(1S)-propyl)-2,2-dimethyl-(4R,5S)-1,3-dioxolane

4-hydroxy-4-hydroxymethyl-7-methoxymethoxy-2,2-dimethyl-5-tert-butyldimethylsilyloxy-(3aS,4S,5S,7S,7aS)-perhydrobenzo[d][1,3]dioxol-4-ol

4-hydroxy-4-hydroxymethyl-7-methoxymethoxy-2,2-dimethyl-5-tert-butyldimethylsilyloxy-(3aS,4S,5S,7S,7aS)-perhydrobenzo[d][1,3]dioxol-4-ol

上游原料

7-methoxymethoxy-2,2-dimethyl-4-methylene-(3aR,5S,7S,7aS)-perhydrobenzo[d][1,3]dioxol-5-ol 4-(1-ethynyl)-5-(1-methoxymethoxy-3-tert-butyldimethylsilyloxy-(1S)-propyl)-2,2-dimethyl-(4R,5S)-1,3-dioxolane ethyl 2-[6-chloromethyl-2,2-dimethyl-(3aS,4S,6S,6aS)-perhydrofuro[3,4-d][1,3]dioxol-4-yl]acetate 2-[6-chloromethyl-2,2-dimethyl-(3aS,4S,6S,6aS)-perhydrofuro[3,4-d][1,3]dioxol-4-yl]-1-ethanol 7-methoxymethoxy-2,2-dimethyl-4-methylene-5-tert-butyldimethylsilyloxy-(3aR,5S,7S,7aS)-perhydrobenzo[d][1,3]dioxole 1-[5-(1-ethynyl)-2,2-dimethyl-(4S,5R)-1,3-dioxolan-4-yl]-3-tert-butyldimethylsilyloxy-(1S)-propan-1-ol

下游产品

7-methoxymethoxy-2,2-dimethyl-5-tert-butyldimethylsilyloxy-(3aS,5S,7S,7aS)-perhydrobenzo[d][1,3]dioxol-4-one 7-methoxymethoxy-2,2-dimethyl-5-tert-butyldimethylsilyloxy-(3aR,4R,5S,7S,7aS)-perhydrobenzo[d][1,3]dioxol-4-ol 7-methoxymethoxy-2,2-dimethyl-4-(4-nitrophenylcarbonyloxy)-5-tert-butyldimethylsilyloxy-(3aS,4S,5S,7S,7aS)-perhydrobenzo[d][1,3]dioxol 7-methoxymethoxy-2,2-dimethyl-5-tert-butyldimethylsilyloxy-(3aR,4S,5S,7S,7aS)-perhydrobenzo[d][1,3]dioxolol-4-ol