百科

1-{2-[(3S,4R,7S)-9-benzyloxy-4-(tert-butyldimethylsilyl)oxy-3-hydroxy-4-methyl-7-(triethylsilyloxy)nonyl]-1,3-dithian-2-yl}-4-hepten-6-one

1-{2-[(3S,4R,7S)-9-benzyloxy-4-(tert-butyldimethylsilyl)oxy-3-hydroxy-4-methyl-7-(triethylsilyloxy)nonyl]-1,3-dithian-2-yl}-4-hepten-6-one

CAS号：389086-24-2

英文名：1-{2-[(3S,4R,7S)-9-benzyloxy-4-(tert-butyldimethylsilyl)oxy-3-hydroxy-4-methyl-7-(triethylsilyloxy)nonyl]-1,3-dithian-2-yl}-4-hepten-6-one

分子式：C40H72O5S2Si2

分子量：753.298

合成路线

(R)-4-benzyloxy-2-(triethysilyloxy)butanal

(R)-4-benzyloxy-2-(triethysilyloxy)butanal

1-{2-[(3S,4R,7S)-9-benzyloxy-4-(tert-butyldimethylsilyl)oxy-3-hydroxy-4-methyl-7-(triethylsilyloxy)nonyl]-1,3-dithian-2-yl}-4-hepten-6-one

1-{2-[(3S,4R,7S)-9-benzyloxy-4-(tert-butyldimethylsilyl)oxy-3-hydroxy-4-methyl-7-(triethylsilyloxy)nonyl]-1,3-dithian-2-yl}-4-hepten-6-one

(S)-2,2-diethyl-5-(2-{2-[4-(tetrahydropyran-2-yloxy)butyl]-1,3-dithian-2-yl}ethyl)-1,3-dioxolane

(S)-2,2-diethyl-5-(2-{2-[4-(tetrahydropyran-2-yloxy)butyl]-1,3-dithian-2-yl}ethyl)-1,3-dioxolane

1-{2-[(3S,4R,7S)-9-benzyloxy-4-(tert-butyldimethylsilyl)oxy-3-hydroxy-4-methyl-7-(triethylsilyloxy)nonyl]-1,3-dithian-2-yl}-4-hepten-6-one

1-{2-[(3S,4R,7S)-9-benzyloxy-4-(tert-butyldimethylsilyl)oxy-3-hydroxy-4-methyl-7-(triethylsilyloxy)nonyl]-1,3-dithian-2-yl}-4-hepten-6-one

(Z)-(3S,7R)-9-Benzyloxy-3-(4-methoxy-benzyloxy)-7-triethylsilanyloxy-1-[2-(4-triethylsilanyloxy-butyl)-[1,3]dithian-2-yl]-non-5-en-4-one

(Z)-(3S,7R)-9-Benzyloxy-3-(4-methoxy-benzyloxy)-7-triethylsilanyloxy-1-[2-(4-triethylsilanyloxy-butyl)-[1,3]dithian-2-yl]-non-5-en-4-one

1-{2-[(3S,4R,7S)-9-benzyloxy-4-(tert-butyldimethylsilyl)oxy-3-hydroxy-4-methyl-7-(triethylsilyloxy)nonyl]-1,3-dithian-2-yl}-4-hepten-6-one

1-{2-[(3S,4R,7S)-9-benzyloxy-4-(tert-butyldimethylsilyl)oxy-3-hydroxy-4-methyl-7-(triethylsilyloxy)nonyl]-1,3-dithian-2-yl}-4-hepten-6-one

上游原料

(Z)-(3S,7R)-9-Benzyloxy-3-(4-methoxy-benzyloxy)-7-triethylsilanyloxy-1-[2-(4-triethylsilanyloxy-butyl)-[1,3]dithian-2-yl]-non-5-en-4-one (S)-2,2-diethyl-5-(2-{2-[4-(tetrahydropyran-2-yloxy)butyl]-1,3-dithian-2-yl}ethyl)-1,3-dioxolane (R)-4-benzyloxy-2-(triethysilyloxy)butanal

下游产品

1-[10-(2-benzyloxy)ethyl-13-(tert-butyldimethylsilyl)oxy-13-methyl-1,7,9-trioxadispiro[5.1.5.2]pentadec-2-yl]-5-(tert-butyldimethylsilyl)oxy-5-[5-(tert-butyldiphenylsilyloxymethyl)-2,2-dimethyl-1,3-dioxolan-4-yl]-4-methylpentan-2-one