百科

(1'S,6R,3aR,6aR)-6-[2'-t-butyldiphenylsilyloxy-1'-(4-methoxybenzyloxy)ethyl]-3a-(4-methoxybenzyloxymethyl)-2-phenyl-6,6a-dihydro-3aH-furo[3,4-d]oxazol-4-one

(1'S,6R,3aR,6aR)-6-[2'-t-butyldiphenylsilyloxy-1'-(4-methoxybenzyloxy)ethyl]-3a-(4-methoxybenzyloxymethyl)-2-phenyl-6,6a-dihydro-3aH-furo[3,4-d]oxazol-4-one

CAS号：389807-35-6

英文名：(1'S,6R,3aR,6aR)-6-[2'-t-butyldiphenylsilyloxy-1'-(4-methoxybenzyloxy)ethyl]-3a-(4-methoxybenzyloxymethyl)-2-phenyl-6,6a-dihydro-3aH-furo[3,4-d]oxazol-4-one

分子式：C46H49NO8Si

分子量：771.969

合成路线

methyl 2-benzamido-3-(dimethylphenylsilyl)propanoate

methyl 2-benzamido-3-(dimethylphenylsilyl)propanoate

(1'S,6R,3aR,6aR)-6-[2'-t-butyldiphenylsilyloxy-1'-(4-methoxybenzyloxy)ethyl]-3a-(4-methoxybenzyloxymethyl)-2-phenyl-6,6a-dihydro-3aH-furo[3,4-d]oxazol-4-one

(1'S,6R,3aR,6aR)-6-[2'-t-butyldiphenylsilyloxy-1'-(4-methoxybenzyloxy)ethyl]-3a-(4-methoxybenzyloxymethyl)-2-phenyl-6,6a-dihydro-3aH-furo[3,4-d]oxazol-4-one

(1'S,3S,4S,5R)-3-benzamido-3-(4-methoxybenzyloxy)-4-acetoxy-5-[2'-(t-butyldiphenylsilyloxy)-1'-(4-methoxybenzyloxy)ethyl]oxolan-2-one

(1'S,3S,4S,5R)-3-benzamido-3-(4-methoxybenzyloxy)-4-acetoxy-5-[2'-(t-butyldiphenylsilyloxy)-1'-(4-methoxybenzyloxy)ethyl]oxolan-2-one

(1'S,6R,3aR,6aR)-6-[2'-t-butyldiphenylsilyloxy-1'-(4-methoxybenzyloxy)ethyl]-3a-(4-methoxybenzyloxymethyl)-2-phenyl-6,6a-dihydro-3aH-furo[3,4-d]oxazol-4-one

(1'S,6R,3aR,6aR)-6-[2'-t-butyldiphenylsilyloxy-1'-(4-methoxybenzyloxy)ethyl]-3a-(4-methoxybenzyloxymethyl)-2-phenyl-6,6a-dihydro-3aH-furo[3,4-d]oxazol-4-one

methyl (4E,2S,3R)-3-acetoxy-2-benzamido-2-dimethylphenylsilylmethyl-6-(t-butyldiphenylsilyloxy)-4-hexenoate

methyl (4E,2S,3R)-3-acetoxy-2-benzamido-2-dimethylphenylsilylmethyl-6-(t-butyldiphenylsilyloxy)-4-hexenoate

(1'S,6R,3aR,6aR)-6-[2'-t-butyldiphenylsilyloxy-1'-(4-methoxybenzyloxy)ethyl]-3a-(4-methoxybenzyloxymethyl)-2-phenyl-6,6a-dihydro-3aH-furo[3,4-d]oxazol-4-one

(1'S,6R,3aR,6aR)-6-[2'-t-butyldiphenylsilyloxy-1'-(4-methoxybenzyloxy)ethyl]-3a-(4-methoxybenzyloxymethyl)-2-phenyl-6,6a-dihydro-3aH-furo[3,4-d]oxazol-4-one

上游原料

methyl 2-benzamido-3-(dimethylphenylsilyl)propanoate (1'S,3S,4S,5R)-3-benzamido-3-(4-methoxybenzyloxy)-4-acetoxy-5-[2'-(t-butyldiphenylsilyloxy)-1'-(4-methoxybenzyloxy)ethyl]oxolan-2-one methyl (4E,2S,3R)-3-acetoxy-2-benzamido-2-dimethylphenylsilylmethyl-6-(t-butyldiphenylsilyloxy)-4-hexenoate

下游产品

(2'E,1'S,6R,3aS,6aR)-6-[3'iodo-1'-(4-methoxybenzyloxy)prop-2'-en-1'-yl]-3a-(4-methoxybenzyloxymethyl)-2-phenyl-6,6a-dihydro-3aH-furo[3,4-d]oxazol-4-one (1'S,6R,3aS,6aR)-6-[2'-hydroxy-1'-(4-methoxybenzyloxy)ethyl]-3a-(4-methoxybenzyloxymethyl)-2-phenyl-6,6a-dihydro-3aH-furo[3,4-d]oxazol-4-one