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{(1S,2S,3S,5R)-3,5-Bis-(tert-butyl-dimethyl-silanyloxy)-2-[(Z)-5-(tetrahydro-pyran-2-yloxy)-pent-2-enyl]-cyclopentyl}-methanol

{(1S,2S,3S,5R)-3,5-Bis-(tert-butyl-dimethyl-silanyloxy)-2-[(Z)-5-(tetrahydro-pyran-2-yloxy)-pent-2-enyl]-cyclopentyl}-methanol

CAS号：390746-22-2

英文名：{(1S,2S,3S,5R)-3,5-Bis-(tert-butyl-dimethyl-silanyloxy)-2-[(Z)-5-(tetrahydro-pyran-2-yloxy)-pent-2-enyl]-cyclopentyl}-methanol

分子式：C28H56O5Si2

分子量：528.912

合成路线

(E)-(4S,6R)-4,6-Bis-(tert-butyl-dimethyl-silanyloxy)-6-((S)-2-thioxo-[1,3]dioxolan-4-yl)-hex-2-enoic acid methyl ester

(E)-(4S,6R)-4,6-Bis-(tert-butyl-dimethyl-silanyloxy)-6-((S)-2-thioxo-[1,3]dioxolan-4-yl)-hex-2-enoic acid methyl ester

{(1S,2S,3S,5R)-3,5-Bis-(tert-butyl-dimethyl-silanyloxy)-2-[(Z)-5-(tetrahydro-pyran-2-yloxy)-pent-2-enyl]-cyclopentyl}-methanol

{(1S,2S,3S,5R)-3,5-Bis-(tert-butyl-dimethyl-silanyloxy)-2-[(Z)-5-(tetrahydro-pyran-2-yloxy)-pent-2-enyl]-cyclopentyl}-methanol

(4aS,5S,7R,7aS)-5,7-Bis-(tert-butyl-dimethyl-silanyloxy)-hexahydro-cyclopenta[c]pyran-3-one

(4aS,5S,7R,7aS)-5,7-Bis-(tert-butyl-dimethyl-silanyloxy)-hexahydro-cyclopenta[c]pyran-3-one

{(1S,2S,3S,5R)-3,5-Bis-(tert-butyl-dimethyl-silanyloxy)-2-[(Z)-5-(tetrahydro-pyran-2-yloxy)-pent-2-enyl]-cyclopentyl}-methanol

{(1S,2S,3S,5R)-3,5-Bis-(tert-butyl-dimethyl-silanyloxy)-2-[(Z)-5-(tetrahydro-pyran-2-yloxy)-pent-2-enyl]-cyclopentyl}-methanol

上游原料

(E)-(4S,6R)-4,6-Bis-(tert-butyl-dimethyl-silanyloxy)-6-((S)-2-thioxo-[1,3]dioxolan-4-yl)-hex-2-enoic acid methyl ester (4aS,5S,7R,7aS)-5,7-Bis-(tert-butyl-dimethyl-silanyloxy)-hexahydro-cyclopenta[c]pyran-3-one

下游产品

(Z)-5-{(1S,2R,3R,5S)-3,5-Bis-(tert-butyl-dimethyl-silanyloxy)-2-[(E)-(S)-3-(tert-butyl-dimethyl-silanyloxy)-oct-1-enyl]-cyclopentyl}-pent-3-en-1-ol