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((2R,3aS,5S,5'R,6S,6''S,7aS)-2-(((tert-butyldiphenylsilyl)oxy)methyl)-6-methyldecahydro-4''H-trispiro[furo[3,2-b]pyran-5,2'-furan-5',2''-pyran-3'',2'''-[1,3]dithian]-6''-yl)methanol
CAS号:392663-34-2
英文名:((2R,3aS,5S,5'R,6S,6''S,7aS)-2-(((tert-butyldiphenylsilyl)oxy)methyl)-6-methyldecahydro-4''H-trispiro[furo[3,2-b]pyran-5,2'-furan-5',2''-pyran-3'',2'''-[1,3]dithian]-6''-yl)methanol
分子式:C36H50O6S2Si
分子量:670.994
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合成路线
392663-28-4
(S)-4-(2-[1,3]Dithian-2-yl-ethyl)-2,2-dimethyl-[1,3]dioxolane
392663-34-2
((2R,3aS,5S,5'R,6S,6''S,7aS)-2-(((tert-butyldiphenylsilyl)oxy)methyl)-6-methyldecahydro-4''H-trispiro[furo[3,2-b]pyran-5,2'-furan-5',2''-pyran-3'',2'''-[1,3]dithian]-6''-yl)methanol
上游原料
(S)-4-(2-[1,3]Dithian-2-yl-ethyl)-2,2-dimethyl-[1,3]dioxolane
下游产品
((2R,3aS,3''R,5S,5'R,6S,6''S,7aS)-2-(((tert-butyldiphenylsilyl)oxy)methyl)-3''-hydroxy-6-methyldodecahydrodispiro[furo[3,2-b]pyran-5,2'-furan-5',2''-pyran]-6''-yl)methyl benzoate
perfluorophenyl (2R,3aS,5R,5'R,6S,6''S,7aS)-6-methyl-6''-((E)-5-(pivaloyloxy)pent-1-en-1-yl)-2,3,3a,3',4',5'',6,6'',7,7a-decahydrodispiro[furo[3,2-b]pyran-5,2'-furan-5',2''-pyran]-2-carboxylate
((2R,3aS,5R,5'R,6S,6''S,7aS)-2-(((tert-butyldiphenylsilyl)oxy)methyl)-6-methyl-3''-(((trifluoromethyl)sulfonyl)oxy)-2,3,3a,3',4',5'',6,6'',7,7a-decahydrodispiro[furo[3,2-b]pyran-5,2'-furan-5',2''-pyran]-6''-yl)methyl benzoate
((2R,3aS,3''R,5R,5'R,6S,6''S,7aS)-2-(((tert-butyldiphenylsilyl)oxy)methyl)-3''-hydroxy-6-methyldodecahydrodispiro[furo[3,2-b]pyran-5,2'-furan-5',2''-pyran]-6''-yl)methyl benzoate
((2R,3aS,5S,5'R,6S,6''S,7aS)-2-(((tert-butyldiphenylsilyl)oxy)methyl)-6-methyl-3''-oxododecahydrodispiro[furo[3,2-b]pyran-5,2'-furan-5',2''-pyran]-6''-yl)methyl benzoate
(2R,3aS,5R,5'R,6S,6''S,7aS)-6-methyl-6''-((E)-5-(pivaloyloxy)pent-1-en-1-yl)-2,3,3a,3',4',5'',6,6'',7,7a-decahydrodispiro[furo[3,2-b]pyran-5,2'-furan-5',2''-pyran]-2-carboxylic acid
tert-butyl(((2R,3aS,3''R,5R,5'R,6S,6''S,7aS)-6-methyl-3''-((triethylsilyl)oxy)-6''-vinyldodecahydrodispiro[furo[3,2-b]pyran-5,2'-furan-5',2''-pyran]-2-yl)methoxy)diphenylsilane
(2R,3aS,5R,5'R,6S,6''S,7aS)-6-methyl-6''-((pivaloyloxy)methyl)-2,3,3a,3',4',5'',6,6'',7,7a-decahydrodispiro[furo[3,2-b]pyran-5,2'-furan-5',2''-pyran]-2-carboxylic acid
((2R,3aS,3''R,5R,5'R,6S,6''S,7aS)-2-(((tert-butyldiphenylsilyl)oxy)methyl)-6-methyl-3''-((triethylsilyl)oxy)dodecahydrodispiro[furo[3,2-b]pyran-5,2'-furan-5',2''-pyran]-6''-yl)methanol
methyl (E)-5-((2R,3aS,5R,5'R,6S,6''S,7aS)-2-(((tert-butyldiphenylsilyl)oxy)methyl)-6-methyl-2,3,3a,3',4',5'',6,6'',7,7a-decahydrodispiro[furo[3,2-b]pyran-5,2'-furan-5',2''-pyran]-6''-yl)-2-(phenylsulfonyl)pent-4-enoate
((2R,3aS,5R,5'R,6S,6''S,7aS)-2-formyl-6-methyl-2,3,3a,3',4',5'',6,6'',7,7a-decahydrodispiro[furo[3,2-b]pyran-5,2'-furan-5',2''-pyran]-6''-yl)methyl pivalate
(E)-5-((2R,3aS,3''R,5R,5'R,6S,6''S,7aS)-2-(((tert-butyldiphenylsilyl)oxy)methyl)-6-methyl-3''-((triethylsilyl)oxy)dodecahydrodispiro[furo[3,2-b]pyran-5,2'-furan-5',2''-pyran]-6''-yl)pent-4-en-1-yl pivalate
(E)-5-((2R,3aS,3''R,5R,5'R,6S,6''S,7aS)-2-(((tert-butyldiphenylsilyl)oxy)methyl)-3''-hydroxy-6-methyldodecahydrodispiro[furo[3,2-b]pyran-5,2'-furan-5',2''-pyran]-6''-yl)pent-4-en-1-yl pivalate
perfluorophenyl (2R,3aS,5R,5'R,6S,6''S,7aS)-6-methyl-6''-((pivaloyloxy)methyl)-2,3,3a,3',4',5'',6,6'',7,7a-decahydrodispiro[furo[3,2-b]pyran-5,2'-furan-5',2''-pyran]-2-carboxylate
((2R,3aS,3''R,5R,5'R,6S,6''S,7aS)-2-(((tert-butyldiphenylsilyl)oxy)methyl)-6-methyl-3''-((triethylsilyl)oxy)dodecahydrodispiro[furo[3,2-b]pyran-5,2'-furan-5',2''-pyran]-6''-yl)methyl pivalate
((2R,3aS,5R,5'R,6S,6''S,7aS)-2-(hydroxymethyl)-6-methyl-2,3,3a,3',4',5'',6,6'',7,7a-decahydrodispiro[furo[3,2-b]pyran-5,2'-furan-5',2''-pyran]-6''-yl)methyl pivalate
(E)-5-((2R,3aS,5R,5'R,6S,6''S,7aS)-2-(hydroxymethyl)-6-methyl-2,3,3a,3',4',5'',6,6'',7,7a-decahydrodispiro[furo[3,2-b]pyran-5,2'-furan-5',2''-pyran]-6''-yl)pent-4-en-1-yl pivalate
(E)-5-((2R,3aS,5R,5'R,6S,6''S,7aS)-2-formyl-6-methyl-2,3,3a,3',4',5'',6,6'',7,7a-decahydrodispiro[furo[3,2-b]pyran-5,2'-furan-5',2''-pyran]-6''-yl)pent-4-en-1-yl pivalate
((2R,3aS,5R,5'R,6S,6''S,7aS)-2-(((tert-butyldiphenylsilyl)oxy)methyl)-6-methyl-3''-oxododecahydrodispiro[furo[3,2-b]pyran-5,2'-furan-5',2''-pyran]-6''-yl)methyl benzoate