(((S)-3-((2R,3R,4R,5R,6R)-4,5-bis((4-methoxybenzyl)oxy)-3-methyl-6-(2-methylallyl)tetrahydro-2H-pyran-2-yl)-3-((4-methoxybenzyl)oxy)prop-1-en-2-yl)oxy)dicyclohexylborane

(((S)-3-((2R,3R,4R,5R,6R)-4,5-bis((4-methoxybenzyl)oxy)-3-methyl-6-(2-methylallyl)tetrahydro-2H-pyran-2-yl)-3-((4-methoxybenzyl)oxy)prop-1-en-2-yl)oxy)dicyclohexylborane

CAS号：392692-58-9

英文名：(((S)-3-((2R,3R,4R,5R,6R)-4,5-bis((4-methoxybenzyl)oxy)-3-methyl-6-(2-methylallyl)tetrahydro-2H-pyran-2-yl)-3-((4-methoxybenzyl)oxy)prop-1-en-2-yl)oxy)dicyclohexylborane

分子式：C49H67BO8

分子量：794.862

合成路线

(S)-1-[(2R,3R,4R,5R,6R)-4,5-Bis-(4-methoxy-benzyloxy)-3-methyl-6-(2-methyl-allyl)-tetrahydro-pyran-2-yl]-1-(4-methoxy-benzyloxy)-propan-2-one

(S)-1-[(2R,3R,4R,5R,6R)-4,5-Bis-(4-methoxy-benzyloxy)-3-methyl-6-(2-methyl-allyl)-tetrahydro-pyran-2-yl]-1-(4-methoxy-benzyloxy)-propan-2-one

B-bromodicyclohexylborane

B-bromodicyclohexylborane

(((S)-3-((2R,3R,4R,5R,6R)-4,5-bis((4-methoxybenzyl)oxy)-3-methyl-6-(2-methylallyl)tetrahydro-2H-pyran-2-yl)-3-((4-methoxybenzyl)oxy)prop-1-en-2-yl)oxy)dicyclohexylborane

(((S)-3-((2R,3R,4R,5R,6R)-4,5-bis((4-methoxybenzyl)oxy)-3-methyl-6-(2-methylallyl)tetrahydro-2H-pyran-2-yl)-3-((4-methoxybenzyl)oxy)prop-1-en-2-yl)oxy)dicyclohexylborane

(2R,4R,5R)-4-benzyloxy-5-hydroxy-1-(p-methoxybenzyloxy)-2-methyl-3-hexanone

(2R,4R,5R)-4-benzyloxy-5-hydroxy-1-(p-methoxybenzyloxy)-2-methyl-3-hexanone

(((S)-3-((2R,3R,4R,5R,6R)-4,5-bis((4-methoxybenzyl)oxy)-3-methyl-6-(2-methylallyl)tetrahydro-2H-pyran-2-yl)-3-((4-methoxybenzyl)oxy)prop-1-en-2-yl)oxy)dicyclohexylborane

(((S)-3-((2R,3R,4R,5R,6R)-4,5-bis((4-methoxybenzyl)oxy)-3-methyl-6-(2-methylallyl)tetrahydro-2H-pyran-2-yl)-3-((4-methoxybenzyl)oxy)prop-1-en-2-yl)oxy)dicyclohexylborane

1-[(2R,3R,4R,5R,6R)-6-[(1R,2R)-2-Hydroxy-1-(4-methoxy-benzyloxy)-propyl]-3,4-bis-(4-methoxy-benzyloxy)-5-methyl-tetrahydro-pyran-2-yl]-propan-2-one

1-[(2R,3R,4R,5R,6R)-6-[(1R,2R)-2-Hydroxy-1-(4-methoxy-benzyloxy)-propyl]-3,4-bis-(4-methoxy-benzyloxy)-5-methyl-tetrahydro-pyran-2-yl]-propan-2-one

(((S)-3-((2R,3R,4R,5R,6R)-4,5-bis((4-methoxybenzyl)oxy)-3-methyl-6-(2-methylallyl)tetrahydro-2H-pyran-2-yl)-3-((4-methoxybenzyl)oxy)prop-1-en-2-yl)oxy)dicyclohexylborane

(((S)-3-((2R,3R,4R,5R,6R)-4,5-bis((4-methoxybenzyl)oxy)-3-methyl-6-(2-methylallyl)tetrahydro-2H-pyran-2-yl)-3-((4-methoxybenzyl)oxy)prop-1-en-2-yl)oxy)dicyclohexylborane

上游原料

(S)-1-[(2R,3R,4R,5R,6R)-4,5-Bis-(4-methoxy-benzyloxy)-3-methyl-6-(2-methyl-allyl)-tetrahydro-pyran-2-yl]-1-(4-methoxy-benzyloxy)-propan-2-one B-bromodicyclohexylborane (2R,4R,5R)-4-benzyloxy-5-hydroxy-1-(p-methoxybenzyloxy)-2-methyl-3-hexanone 1-[(2R,3R,4R,5R,6R)-6-[(1R,2R)-2-Hydroxy-1-(4-methoxy-benzyloxy)-propyl]-3,4-bis-(4-methoxy-benzyloxy)-5-methyl-tetrahydro-pyran-2-yl]-propan-2-one

下游产品

(2R,4S,5R,6R)-6-(4-chlorobutyl)-2-methoxy-2-[[4,5-(R,R)-bis-(p-methoxybenzyloxy)-3-(R)-methyl-6-(R)-(2-methylallyl)-tetrahydropyran-2-(R)-yl]-((S)-p-methoxybenzyloxy)-methyl]-5-methyl-tetrahydropyran-4-ol