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(4R,4aR,6S,8aS)-8a-Methoxy-4a,6-dimethyl-5-methylene-4-vinyl-octahydro-chromene-6-carboxylic acid methyl ester
CAS号:397322-77-9
英文名:(4R,4aR,6S,8aS)-8a-Methoxy-4a,6-dimethyl-5-methylene-4-vinyl-octahydro-chromene-6-carboxylic acid methyl ester
分子式:C17H26O4
分子量:294.386
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合成路线
397322-74-6
(-)-(2R,4S)-2-[(3R,E)-5-(tert-butyldiphenylsiloxy)penten-3-yl]-2,4-dimethyl-3-methylene-4-carbomethoxycyclohexanone
397322-77-9
(4R,4aR,6S,8aS)-8a-Methoxy-4a,6-dimethyl-5-methylene-4-vinyl-octahydro-chromene-6-carboxylic acid methyl ester
上游原料
(-)-(2R,4S)-2-[(3R,E)-5-(tert-butyldiphenylsiloxy)penten-3-yl]-2,4-dimethyl-3-methylene-4-carbomethoxycyclohexanone
下游产品
methyl (1S,2S,6R,7R,9R)-7-[2-(acetyloxy)ethyl]-9-(3-furanyl)-2,6-dimethyl-5-oxo-10,12-dioxatricyclo[7.2.1.0(1,6)]dodecane-2-carboxylate
(-)-(3R,4S,8R)-methyl 8-[(1R)-1-[2-(acetyloxy)ethyl]-3-(3-furanyl)-3-oxopropyl]-4,8-dimethyl-7-oxo-1-oxaspiro[2.5]octane-4-carboxylate
methyl (3R,4S,8R)-8-((4R)-2-(furan-3-yl)-2-hydroxytetrahydro-2H-pyran-4-yl)-4,8-dimethyl-7-oxo-1-oxaspiro[2.5]octane-4-carboxylate
(1S,2S,6R,7R,9R)-9-Furan-3-yl-7-(2-hydroxy-ethyl)-2,6-dimethyl-5-oxo-10,12-dioxa-tricyclo[7.2.1.01,6]dodecane-2-carboxylic acid methyl ester
methyl (3aS,3a1S,5R,7aS,8S)-5-(furan-3-yl)-3a1,8-dimethyl-2-oxo-2,3,3a,3a1,4,5,8,9-octahydro-7H-5,7a-epoxyoxepino[5,4,3-de]chromene-8-carboxylate
methyl (3S,3aS,3a1S,5R,7aS,8S)-5-(furan-3-yl)-3,3a1,8-trimethyl-2-oxo-2,3,3a,3a1,4,5,8,9-octahydro-7H-5,7a-epoxyoxepino[5,4,3-de]chromene-8-carboxylate