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2,2-Dimethyl-propionic acid (3E,5Z)-6-[(2R,3S,4S,6S)-4-(tert-butyl-dimethyl-silanyloxy)-6-((E)-3-iodo-allyl)-3-methyl-tetrahydro-pyran-2-yl]-5-methyl-hexa-3,5-dienyl ester
CAS号:398517-10-7
英文名:2,2-Dimethyl-propionic acid (3E,5Z)-6-[(2R,3S,4S,6S)-4-(tert-butyl-dimethyl-silanyloxy)-6-((E)-3-iodo-allyl)-3-methyl-tetrahydro-pyran-2-yl]-5-methyl-hexa-3,5-dienyl ester
分子式:C27H47IO4Si
分子量:590.65
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合成路线
632357-82-5
[(2R,4S,5S,6S)-4-(tert-Butyl-dimethyl-silanyloxy)-6-(tert-butyl-dimethyl-silanyloxymethyl)-5-methyl-tetrahydro-pyran-2-yl]-acetic acid ethyl ester
398517-10-7
2,2-Dimethyl-propionic acid (3E,5Z)-6-[(2R,3S,4S,6S)-4-(tert-butyl-dimethyl-silanyloxy)-6-((E)-3-iodo-allyl)-3-methyl-tetrahydro-pyran-2-yl]-5-methyl-hexa-3,5-dienyl ester
398516-93-3
(2S,3S,4S)-1,4-Bis-benzyloxy-3-methyl-hex-5-en-2-ol
398517-10-7
2,2-Dimethyl-propionic acid (3E,5Z)-6-[(2R,3S,4S,6S)-4-(tert-butyl-dimethyl-silanyloxy)-6-((E)-3-iodo-allyl)-3-methyl-tetrahydro-pyran-2-yl]-5-methyl-hexa-3,5-dienyl ester
398516-96-6
((2R,4S,5R,6S)-4-Benzyloxy-6-benzyloxymethyl-5-methyl-tetrahydro-pyran-2-yl)-acetic acid ethyl ester
398517-10-7
2,2-Dimethyl-propionic acid (3E,5Z)-6-[(2R,3S,4S,6S)-4-(tert-butyl-dimethyl-silanyloxy)-6-((E)-3-iodo-allyl)-3-methyl-tetrahydro-pyran-2-yl]-5-methyl-hexa-3,5-dienyl ester
632357-80-3
(E)-3-((1S,2R,3R)-3-Benzyloxy-1-benzyloxymethyl-4-hydroxy-2-methyl-butoxy)-acrylic acid ethyl ester
398517-10-7
2,2-Dimethyl-propionic acid (3E,5Z)-6-[(2R,3S,4S,6S)-4-(tert-butyl-dimethyl-silanyloxy)-6-((E)-3-iodo-allyl)-3-methyl-tetrahydro-pyran-2-yl]-5-methyl-hexa-3,5-dienyl ester
398516-95-5
(E)-3-((1S,2S,3R)-3-Benzyloxy-1-benzyloxymethyl-4-bromo-2-methyl-butoxy)-acrylic acid ethyl ester
398517-10-7
2,2-Dimethyl-propionic acid (3E,5Z)-6-[(2R,3S,4S,6S)-4-(tert-butyl-dimethyl-silanyloxy)-6-((E)-3-iodo-allyl)-3-methyl-tetrahydro-pyran-2-yl]-5-methyl-hexa-3,5-dienyl ester
398516-94-4
(2S,3S,4R)-1,4-Bis-benzyloxy-5-(tert-butyl-dimethyl-silanyloxy)-3-methyl-pentan-2-ol
398517-10-7
2,2-Dimethyl-propionic acid (3E,5Z)-6-[(2R,3S,4S,6S)-4-(tert-butyl-dimethyl-silanyloxy)-6-((E)-3-iodo-allyl)-3-methyl-tetrahydro-pyran-2-yl]-5-methyl-hexa-3,5-dienyl ester
632357-70-1
((2R,4S,5R,6S)-4-Hydroxy-6-hydroxymethyl-5-methyl-tetrahydro-pyran-2-yl)-acetic acid ethyl ester
398517-10-7
2,2-Dimethyl-propionic acid (3E,5Z)-6-[(2R,3S,4S,6S)-4-(tert-butyl-dimethyl-silanyloxy)-6-((E)-3-iodo-allyl)-3-methyl-tetrahydro-pyran-2-yl]-5-methyl-hexa-3,5-dienyl ester
632357-83-6
(2S,3S,4S,6S)-4-(tert-Butyl-dimethyl-silanyloxy)-6-((E)-3-iodo-allyl)-3-methyl-tetrahydro-pyran-2-carbaldehyde
398517-10-7
2,2-Dimethyl-propionic acid (3E,5Z)-6-[(2R,3S,4S,6S)-4-(tert-butyl-dimethyl-silanyloxy)-6-((E)-3-iodo-allyl)-3-methyl-tetrahydro-pyran-2-yl]-5-methyl-hexa-3,5-dienyl ester
632358-08-8
[(2R,4S,5S,6S)-4-(tert-Butyl-dimethyl-silanyloxy)-6-(tert-butyl-dimethyl-silanyloxymethyl)-5-methyl-tetrahydro-pyran-2-yl]-acetaldehyde
398517-10-7
2,2-Dimethyl-propionic acid (3E,5Z)-6-[(2R,3S,4S,6S)-4-(tert-butyl-dimethyl-silanyloxy)-6-((E)-3-iodo-allyl)-3-methyl-tetrahydro-pyran-2-yl]-5-methyl-hexa-3,5-dienyl ester
398516-98-8
(Z)-3-[(2R,3S,4S,6S)-4-(tert-Butyl-dimethyl-silanyloxy)-6-((E)-3-iodo-allyl)-3-methyl-tetrahydro-pyran-2-yl]-2-methyl-acrylic acid methyl ester
398517-10-7
2,2-Dimethyl-propionic acid (3E,5Z)-6-[(2R,3S,4S,6S)-4-(tert-butyl-dimethyl-silanyloxy)-6-((E)-3-iodo-allyl)-3-methyl-tetrahydro-pyran-2-yl]-5-methyl-hexa-3,5-dienyl ester
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上游原料
(Z)-3-[(2R,3S,4S,6S)-4-(tert-Butyl-dimethyl-silanyloxy)-6-((E)-3-iodo-allyl)-3-methyl-tetrahydro-pyran-2-yl]-2-methyl-prop-2-en-1-ol
(2S,3S,4S,6S)-4-(tert-Butyl-dimethyl-silanyloxy)-2-(tert-butyl-dimethyl-silanyloxymethyl)-6-((E)-3-iodo-allyl)-3-methyl-tetrahydro-pyran
(2R,3S,4S)-2,5-Bis-benzyloxy-3-methyl-pentane-1,4-diol
(2S,3S,4S,6S)-4-(tert-Butyl-dimethyl-silanyloxy)-6-((E)-3-iodo-allyl)-3-methyl-tetrahydro-pyran-2-carbaldehyde
(Z)-3-[(2R,3S,4S,6S)-4-(tert-Butyl-dimethyl-silanyloxy)-6-((E)-3-iodo-allyl)-3-methyl-tetrahydro-pyran-2-yl]-2-methyl-acrylic acid methyl ester
(E)-3-((1S,2S,3R)-3-Benzyloxy-1-benzyloxymethyl-4-bromo-2-methyl-butoxy)-acrylic acid ethyl ester
((2R,4S,5R,6S)-4-Benzyloxy-6-benzyloxymethyl-5-methyl-tetrahydro-pyran-2-yl)-acetic acid ethyl ester
(2S,3S,4S)-1,4-Bis-benzyloxy-3-methyl-hex-5-en-2-ol
(2S,3R,4S)-1-Benzyloxy-3-methyl-hex-5-ene-2,4-diol
(2S,3S,4R)-1,4-Bis-benzyloxy-5-(tert-butyl-dimethyl-silanyloxy)-3-methyl-pentan-2-ol
2-[(2S,4S,5S,6S)-4-(tert-Butyl-dimethyl-silanyloxy)-6-(tert-butyl-dimethyl-silanyloxymethyl)-5-methyl-tetrahydro-pyran-2-yl]-ethanol
(4S,5S)-6-Benzyloxy-5-hydroxy-4-methyl-hex-1-en-3-one
(E)-3-((1S,2R,3R)-3-Benzyloxy-1-benzyloxymethyl-4-hydroxy-2-methyl-butoxy)-acrylic acid ethyl ester
((2R,4S,5R,6S)-4-Hydroxy-6-hydroxymethyl-5-methyl-tetrahydro-pyran-2-yl)-acetic acid ethyl ester
[(2R,4S,5S,6S)-4-(tert-Butyl-dimethyl-silanyloxy)-6-(tert-butyl-dimethyl-silanyloxymethyl)-5-methyl-tetrahydro-pyran-2-yl]-acetaldehyde
[(2R,4S,5S,6S)-4-(tert-Butyl-dimethyl-silanyloxy)-6-(tert-butyl-dimethyl-silanyloxymethyl)-5-methyl-tetrahydro-pyran-2-yl]-acetic acid ethyl ester
[(2S,3S,4S,6S)-4-(tert-Butyl-dimethyl-silanyloxy)-6-((E)-3-iodo-allyl)-3-methyl-tetrahydro-pyran-2-yl]-methanol
下游产品
2,2-dimethyl-propionic acid 2-(6-{7-[4-(tert-butyl-dimethyl-silanyloxy)-6-(3-iodo-allyl)-3-methyl-tetrahydro-pyran-2-yl]-6-methyl-hepta-1,4,6-trienyl}-4-hydroxy-3-hydroxymethyl-3-methyl-tetrahydro-pyran-2-yl)-ethyl ester
tert-Butyl-[(2R,3S,4S,6S)-6-((E)-3-iodo-allyl)-2-((1Z,3E)-6-iodo-2-methyl-hexa-1,3-dienyl)-3-methyl-tetrahydro-pyran-4-yloxy]-dimethyl-silane
(4E,6E,14Z,16E,19Z)-(1R,9S,11S,12S,13R,21S,23S,24S)-11-(tert-Butyl-dimethyl-silanyloxy)-24-(tert-butyl-dimethyl-silanyloxymethyl)-23-(2-hydroxy-ethyl)-12,15,24-trimethyl-2,22,26-trioxa-tricyclo[19.3.1.19,13]hexacosa-4,6,14,16,19-pentaen-3-one
2,2-dimethyl-propionic acid 2-(7-{7-[4-(tert-butyl-dimethyl-silanyloxy)-6-(3-iodo-allyl)-3-methyl-tetrahydro-pyran-2-yl]-6-methyl-hepta-1,4,6-trienyl}-2,2,4a-trimethyl-tetrahydro-pyrano[4,3-d][1,3]dioxin-5-yl)-ethyl ester
2,2-dimethyl-propionic acid 2-[6-{7-[4-(tert-butyl-dimethyl-silanyloxy)-6-(3-iodo-allyl)-3-methyl-tetrahydro-pyran-2-yl]-6-methyl-hepta-1,4,6-trienyl}-3-(tert-butyl-dimethyl-silanyloxymethyl)-4-hydroxy-3-methyl-tetrahydro-pyran-2-yl]-ethyl ester
(3E,5Z)-6-[(2R,3S,4S,6S)-4-(tert-Butyl-dimethyl-silanyloxy)-6-((E)-3-iodo-allyl)-3-methyl-tetrahydro-pyran-2-yl]-5-methyl-hexa-3,5-dien-1-ol
2,2-dimethyl-propionic acid 2-[11-(tert-butyl-dimethyl-silanyloxy)-24-(tert-butyl-dimethyl-silanyloxymethyl)-12,15,24-trimethyl-3-oxo-2,22,26-trioxa-tricyclo[19.3.1.19,13]hexacosa-4,6,14,16,19-pentaen-23-yl]-ethyl ester
[(4E,6E,14Z,16E,19Z)-(1R,9S,11S,12S,13R,21S,23S,24S)-11-(tert-Butyl-dimethyl-silanyloxy)-24-(tert-butyl-dimethyl-silanyloxymethyl)-12,15,24-trimethyl-3-oxo-2,22,26-trioxa-tricyclo[19.3.1.19,13]hexacosa-4,6,14,16,19-pentaen-23-yl]-acetaldehyde