百科

(2R,5Z,11R,12S)-1,2-bis(tert-butyldimethylsilyloxy)-11,12-methylene-5-docosene

(2R,5Z,11R,12S)-1,2-bis(tert-butyldimethylsilyloxy)-11,12-methylene-5-docosene

CAS号：400051-72-1

英文名：(2R,5Z,11R,12S)-1,2-bis(tert-butyldimethylsilyloxy)-11,12-methylene-5-docosene

分子式：C35H72O2Si2

分子量：581.116

合成路线

(6R,7S)-6,7-methylene-1-heptadecanol

(6R,7S)-6,7-methylene-1-heptadecanol

(2R,5Z,11R,12S)-1,2-bis(tert-butyldimethylsilyloxy)-11,12-methylene-5-docosene

(2R,5Z,11R,12S)-1,2-bis(tert-butyldimethylsilyloxy)-11,12-methylene-5-docosene

(6R,7S)-1-bromo-6,7-methyleneheptadecane

(6R,7S)-1-bromo-6,7-methyleneheptadecane

(2R,5Z,11R,12S)-1,2-bis(tert-butyldimethylsilyloxy)-11,12-methylene-5-docosene

(2R,5Z,11R,12S)-1,2-bis(tert-butyldimethylsilyloxy)-11,12-methylene-5-docosene

(4R,3'Z,9'R,10'S)-4-(9',10'-methylene-3'-icosenyl)-2,2-dimethyl-1,3-dioxolane

(4R,3'Z,9'R,10'S)-4-(9',10'-methylene-3'-icosenyl)-2,2-dimethyl-1,3-dioxolane

(2R,5Z,11R,12S)-1,2-bis(tert-butyldimethylsilyloxy)-11,12-methylene-5-docosene

(2R,5Z,11R,12S)-1,2-bis(tert-butyldimethylsilyloxy)-11,12-methylene-5-docosene

上游原料

(4R,3'Z,9'R,10'S)-4-(9',10'-methylene-3'-icosenyl)-2,2-dimethyl-1,3-dioxolane (6R,7S)-6,7-methylene-1-heptadecanol (6R,7S)-1-bromo-6,7-methyleneheptadecane

下游产品

(2R,5Z)-2-[(tert-butyl)dimethylsilyloxy]-10-[(1R,2S)-2-decylcyclopropyl]dec-5-en-1-ol (2R,5Z,11R,12S)-11,12-methylene-5-docosene-1,2-diol (2R,5Z)-2-[(tert-butyl)dimethylsilyloxy]-10-[(1R,2S)-2-decylcyclopropyl]dec-5-enal (2S,3R,11R,12S,2'''R,5'''Z,11'''R,12'''S)-1-O-[3',4',6'-tri-O-acetyl-2'-O-(2''-chloroacetyl)-β-D-galactopyranosyl]-3,2'''-bis(tert-butyldimethylsilyloxy)-11,12-methylene-2-(11''',12'''-methylene-5'''-docosenoylamido)docosane (2S,3R,11R,12S,2'R,5'Z,11'R,12'S)-3,2'-bis(tert-butyldimethylsilyloxy)-11,12-methylene-2-(11',12'-methylene-5'-docosenoylamido)-1-docosanol (2R,5Z,11R,12S)-2-tert-butyldimethylsilyloxy-11,12-methylene-5-docosenoic acid (2S,3R,11R,12S,2'''R,5'''Z,11'''R,12'''S)-1-O-[3',4',6'-tri-O-acetyl-2'-O-(3''-methyl-2''-butenyl)-β-D-galactopyranosyl]-3,2'''-bis(tert-butyldimethylsilyloxy)-11,12-methylene-2-(11''',12'''-methylene-5'''-docosenoylamido)docosane (2S,3R,11R,12S,2'''R,5'''Z,11'''R,12'''S)-1-O-[3',4',6'-tri-O-acetyl-β-D-galactopyranosyl]-3,2'''-bis(tert-butyldimethylsilyloxy)-11,12-methylene-2-(11''',12'''-methylene-5'''-docosenoylamido)docosane