百科

(2S,3R,11R,12S,2'R,5'Z,11'R,12'S)-3,2'-bis(tert-butyldimethylsilyloxy)-11,12-methylene-2-(11',12'-methylene-5'-docosenoylamido)-1-docosanol

(2S,3R,11R,12S,2'R,5'Z,11'R,12'S)-3,2'-bis(tert-butyldimethylsilyloxy)-11,12-methylene-2-(11',12'-methylene-5'-docosenoylamido)-1-docosanol

CAS号：400051-74-3

英文名：(2S,3R,11R,12S,2'R,5'Z,11'R,12'S)-3,2'-bis(tert-butyldimethylsilyloxy)-11,12-methylene-2-(11',12'-methylene-5'-docosenoylamido)-1-docosanol

分子式：C58H115NO4Si2

分子量：946.709

合成路线

(2R,5Z,11R,12S)-1,2-bis(tert-butyldimethylsilyloxy)-11,12-methylene-5-docosene

(2R,5Z,11R,12S)-1,2-bis(tert-butyldimethylsilyloxy)-11,12-methylene-5-docosene

(2S,3R,11R,12S,2'R,5'Z,11'R,12'S)-3,2'-bis(tert-butyldimethylsilyloxy)-11,12-methylene-2-(11',12'-methylene-5'-docosenoylamido)-1-docosanol

(2S,3R,11R,12S,2'R,5'Z,11'R,12'S)-3,2'-bis(tert-butyldimethylsilyloxy)-11,12-methylene-2-(11',12'-methylene-5'-docosenoylamido)-1-docosanol

(2S,3R,11R,12S)-2-amino-1,3-bis(tert-butyldimethylsilyloxy)-11,12-methylenedocosane

(2S,3R,11R,12S)-2-amino-1,3-bis(tert-butyldimethylsilyloxy)-11,12-methylenedocosane

(2S,3R,11R,12S,2'R,5'Z,11'R,12'S)-3,2'-bis(tert-butyldimethylsilyloxy)-11,12-methylene-2-(11',12'-methylene-5'-docosenoylamido)-1-docosanol

(2S,3R,11R,12S,2'R,5'Z,11'R,12'S)-3,2'-bis(tert-butyldimethylsilyloxy)-11,12-methylene-2-(11',12'-methylene-5'-docosenoylamido)-1-docosanol

(2R,5Z,11R,12S)-11,12-methylene-5-docosene-1,2-diol

(2R,5Z,11R,12S)-11,12-methylene-5-docosene-1,2-diol

(2S,3R,11R,12S,2'R,5'Z,11'R,12'S)-3,2'-bis(tert-butyldimethylsilyloxy)-11,12-methylene-2-(11',12'-methylene-5'-docosenoylamido)-1-docosanol

(2S,3R,11R,12S,2'R,5'Z,11'R,12'S)-3,2'-bis(tert-butyldimethylsilyloxy)-11,12-methylene-2-(11',12'-methylene-5'-docosenoylamido)-1-docosanol

(2R,5Z,11R,12S)-2-tert-butyldimethylsilyloxy-11,12-methylene-5-docosenoic acid

(2R,5Z,11R,12S)-2-tert-butyldimethylsilyloxy-11,12-methylene-5-docosenoic acid

(2S,3R,11R,12S,2'R,5'Z,11'R,12'S)-3,2'-bis(tert-butyldimethylsilyloxy)-11,12-methylene-2-(11',12'-methylene-5'-docosenoylamido)-1-docosanol

(2S,3R,11R,12S,2'R,5'Z,11'R,12'S)-3,2'-bis(tert-butyldimethylsilyloxy)-11,12-methylene-2-(11',12'-methylene-5'-docosenoylamido)-1-docosanol

上游原料

(2R,5Z,11R,12S)-11,12-methylene-5-docosene-1,2-diol (2R,5Z,11R,12S)-1,2-bis(tert-butyldimethylsilyloxy)-11,12-methylene-5-docosene (2S,3R,11R,12S)-2-amino-1,3-bis(tert-butyldimethylsilyloxy)-11,12-methylenedocosane (2R,5Z,11R,12S)-2-tert-butyldimethylsilyloxy-11,12-methylene-5-docosenoic acid

下游产品

(2S,3R,11R,12S,2'''R,5'''Z,11'''R,12'''S)-1-O-[3',4',6'-tri-O-acetyl-β-D-galactopyranosyl]-3,2'''-bis(tert-butyldimethylsilyloxy)-11,12-methylene-2-(11''',12'''-methylene-5'''-docosenoylamido)docosane