百科

3-O-allyl-6-O-tert-butyldimethylsilyl-1,2-O-isopropylidene-5-C-vinyl-α-D-glucofuranose

3-O-allyl-6-O-tert-butyldimethylsilyl-1,2-O-isopropylidene-5-C-vinyl-α-D-glucofuranose

CAS号：403724-99-2

英文名：3-O-allyl-6-O-tert-butyldimethylsilyl-1,2-O-isopropylidene-5-C-vinyl-α-D-glucofuranose

分子式：C20H36O6Si

分子量：400.582

合成路线

3-O-allyl-1,2-O-isopropylidene-α-D-glucofuranose

3-O-allyl-1,2-O-isopropylidene-α-D-glucofuranose

3-O-allyl-6-O-tert-butyldimethylsilyl-1,2-O-isopropylidene-5-C-vinyl-α-D-glucofuranose

3-O-allyl-6-O-tert-butyldimethylsilyl-1,2-O-isopropylidene-5-C-vinyl-α-D-glucofuranose

(1R)-1-(3aR,5R,6S,6aR)-6-(allyloxy)-2,2-dimethyltetrahydrofuro[2,3-d][1,3]dioxol-5-yl-2-((tert-butyldimethylsilyl)oxy)ethanol

(1R)-1-(3aR,5R,6S,6aR)-6-(allyloxy)-2,2-dimethyltetrahydrofuro[2,3-d][1,3]dioxol-5-yl-2-((tert-butyldimethylsilyl)oxy)ethanol

3-O-allyl-6-O-tert-butyldimethylsilyl-1,2-O-isopropylidene-5-C-vinyl-α-D-glucofuranose

3-O-allyl-6-O-tert-butyldimethylsilyl-1,2-O-isopropylidene-5-C-vinyl-α-D-glucofuranose

上游原料

(1R)-1-(3aR,5R,6S,6aR)-6-(allyloxy)-2,2-dimethyltetrahydrofuro[2,3-d][1,3]dioxol-5-yl-2-((tert-butyldimethylsilyl)oxy)ethanol 3-O-allyl-1,2-O-isopropylidene-α-D-glucofuranose

下游产品

methyl 2,3,6-tri-O-benzyl-4-O-(3-O-acetyl-2-O-methyl-5-C-vinyl-β-D-glucopyranosyl)-α-D-glucopyranoside methyl 2,3,6-tri-O-benzyl-4-O-(2,4,6-tri-O-acetyl-3-O-allyl-5-C-vinyl-β-D-glucopyranosyl)-α-D-glucopyranoside methyl 2,3,6-tri-O-benzyl-4-O-(3-O-allyl-4,6-O-isopropylidene-2-O-methyl-5-C-vinyl-β-D-glucopyranosyl)-α-D-glucopyranoside methyl 2,3,6-tri-O-benzyl-4-O-(4,6-O-isopropylidene-2-O-methyl-5-C-vinyl-β-D-glucopyranosyl)-α-D-glucopyranoside methyl 2,3,6-tri-O-benzyl-4-O-(3-O-allyl-4,6-O-isopropylidene-5-C-vinyl-β-D-glucopyranosyl)-α-D-glucopyranoside methyl 2,3,6-tri-O-benzyl-4-O-(3-O-5-C-methylene-2-O-methyl-5-C-vinyl-α-L-idopyranosyl)-α-D-glucopyranoside methyl 2,3,6-tri-O-benzyl-4-O-(benzyl 2-O-methyl-3-O-5-C-methylene-α-L-idopyranosyluronate)-α-D-glucopyranoside