百科

(2S,4S,6R,8S,10S)-2-[(R)-4-(4-Methoxy-benzyloxy)-3-methyl-2-methylene-butyl]-4-methyl-8-[2-(naphthalen-2-ylmethoxy)-ethyl]-1,7-dioxa-spiro[5.5]undecane-4,10-diol

(2S,4S,6R,8S,10S)-2-[(R)-4-(4-Methoxy-benzyloxy)-3-methyl-2-methylene-butyl]-4-methyl-8-[2-(naphthalen-2-ylmethoxy)-ethyl]-1,7-dioxa-spiro[5.5]undecane-4,10-diol

CAS号：410077-51-9

英文名：(2S,4S,6R,8S,10S)-2-[(R)-4-(4-Methoxy-benzyloxy)-3-methyl-2-methylene-butyl]-4-methyl-8-[2-(naphthalen-2-ylmethoxy)-ethyl]-1,7-dioxa-spiro[5.5]undecane-4,10-diol

分子式：C37H48O7

分子量：604.773

合成路线

Carbonic acid tert-butyl ester (S)-1-(tert-butyl-diphenyl-silanyloxymethyl)-1-methyl-but-3-enyl ester

Carbonic acid tert-butyl ester (S)-1-(tert-butyl-diphenyl-silanyloxymethyl)-1-methyl-but-3-enyl ester

(2S,4S,6R,8S,10S)-2-[(R)-4-(4-Methoxy-benzyloxy)-3-methyl-2-methylene-butyl]-4-methyl-8-[2-(naphthalen-2-ylmethoxy)-ethyl]-1,7-dioxa-spiro[5.5]undecane-4,10-diol

(2S,4S,6R,8S,10S)-2-[(R)-4-(4-Methoxy-benzyloxy)-3-methyl-2-methylene-butyl]-4-methyl-8-[2-(naphthalen-2-ylmethoxy)-ethyl]-1,7-dioxa-spiro[5.5]undecane-4,10-diol

(4S,6R)-4-(tert-Butyl-diphenyl-silanyloxymethyl)-6-iodomethyl-4-methyl-[1,3]dioxan-2-one

(4S,6R)-4-(tert-Butyl-diphenyl-silanyloxymethyl)-6-iodomethyl-4-methyl-[1,3]dioxan-2-one

(2S,4S,6R,8S,10S)-2-[(R)-4-(4-Methoxy-benzyloxy)-3-methyl-2-methylene-butyl]-4-methyl-8-[2-(naphthalen-2-ylmethoxy)-ethyl]-1,7-dioxa-spiro[5.5]undecane-4,10-diol

(2S,4S,6R,8S,10S)-2-[(R)-4-(4-Methoxy-benzyloxy)-3-methyl-2-methylene-butyl]-4-methyl-8-[2-(naphthalen-2-ylmethoxy)-ethyl]-1,7-dioxa-spiro[5.5]undecane-4,10-diol

(2S,4S,7R)-1-(tert-Butyl-diphenyl-silanyloxy)-8-(4-methoxy-benzyloxy)-2,7-dimethyl-6-methylene-octane-2,4-diol

(2S,4S,7R)-1-(tert-Butyl-diphenyl-silanyloxy)-8-(4-methoxy-benzyloxy)-2,7-dimethyl-6-methylene-octane-2,4-diol

(2S,4S,6R,8S,10S)-2-[(R)-4-(4-Methoxy-benzyloxy)-3-methyl-2-methylene-butyl]-4-methyl-8-[2-(naphthalen-2-ylmethoxy)-ethyl]-1,7-dioxa-spiro[5.5]undecane-4,10-diol

(2S,4S,6R,8S,10S)-2-[(R)-4-(4-Methoxy-benzyloxy)-3-methyl-2-methylene-butyl]-4-methyl-8-[2-(naphthalen-2-ylmethoxy)-ethyl]-1,7-dioxa-spiro[5.5]undecane-4,10-diol

Carbonic acid tert-butyl ester (R)-1-[2-(naphthalen-2-ylmethoxy)-ethyl]-but-3-enyl ester

Carbonic acid tert-butyl ester (R)-1-[2-(naphthalen-2-ylmethoxy)-ethyl]-but-3-enyl ester

(2S,4S,6R,8S,10S)-2-[(R)-4-(4-Methoxy-benzyloxy)-3-methyl-2-methylene-butyl]-4-methyl-8-[2-(naphthalen-2-ylmethoxy)-ethyl]-1,7-dioxa-spiro[5.5]undecane-4,10-diol

(2S,4S,6R,8S,10S)-2-[(R)-4-(4-Methoxy-benzyloxy)-3-methyl-2-methylene-butyl]-4-methyl-8-[2-(naphthalen-2-ylmethoxy)-ethyl]-1,7-dioxa-spiro[5.5]undecane-4,10-diol

上游原料

(2S,4S,7R)-1-(tert-Butyl-diphenyl-silanyloxy)-8-(4-methoxy-benzyloxy)-2,7-dimethyl-6-methylene-octane-2,4-diol (4S,6R)-4-(tert-Butyl-diphenyl-silanyloxymethyl)-6-iodomethyl-4-methyl-[1,3]dioxan-2-one Carbonic acid tert-butyl ester (S)-1-(tert-butyl-diphenyl-silanyloxymethyl)-1-methyl-but-3-enyl ester Carbonic acid tert-butyl ester (R)-1-[2-(naphthalen-2-ylmethoxy)-ethyl]-but-3-enyl ester

下游产品

triisopropylsilyl 2-((2R,4S,6S,8S,10S)-4-acetoxy-8-((R)-4-((4-methoxybenzyl)oxy)-3-methyl-2-methylenebutyl)-10-methyl-10-((triethylsilyl)oxy)-1,7-dioxaspiro[5.5]undecan-2-yl)acetate