百科

Acetic acid (2S,4S,6R,8S,10S)-10-hydroxy-8-[(R)-4-(4-methoxy-benzyloxy)-3-methyl-2-methylene-butyl]-10-methyl-2-[2-(naphthalen-2-ylmethoxy)-ethyl]-1,7-dioxa-spiro[5.5]undec-4-yl ester

CAS号：410077-71-3

英文名：Acetic acid (2S,4S,6R,8S,10S)-10-hydroxy-8-[(R)-4-(4-methoxy-benzyloxy)-3-methyl-2-methylene-butyl]-10-methyl-2-[2-(naphthalen-2-ylmethoxy)-ethyl]-1,7-dioxa-spiro[5.5]undec-4-yl ester

分子式：C39H50O8

分子量：646.809

合成路线

410077-35-9

Carbonic acid tert-butyl ester (S)-1-(tert-butyl-diphenyl-silanyloxymethyl)-1-methyl-but-3-enyl ester

410077-71-3

Acetic acid (2S,4S,6R,8S,10S)-10-hydroxy-8-[(R)-4-(4-methoxy-benzyloxy)-3-methyl-2-methylene-butyl]-10-methyl-2-[2-(naphthalen-2-ylmethoxy)-ethyl]-1,7-dioxa-spiro[5.5]undec-4-yl ester

410077-37-1

(4S,6R)-4-(tert-Butyl-diphenyl-silanyloxymethyl)-6-iodomethyl-4-methyl-[1,3]dioxan-2-one

410077-71-3

Acetic acid (2S,4S,6R,8S,10S)-10-hydroxy-8-[(R)-4-(4-methoxy-benzyloxy)-3-methyl-2-methylene-butyl]-10-methyl-2-[2-(naphthalen-2-ylmethoxy)-ethyl]-1,7-dioxa-spiro[5.5]undec-4-yl ester

410077-45-1

(2S,4S,7R)-1-(tert-Butyl-diphenyl-silanyloxy)-8-(4-methoxy-benzyloxy)-2,7-dimethyl-6-methylene-octane-2,4-diol

410077-71-3

Acetic acid (2S,4S,6R,8S,10S)-10-hydroxy-8-[(R)-4-(4-methoxy-benzyloxy)-3-methyl-2-methylene-butyl]-10-methyl-2-[2-(naphthalen-2-ylmethoxy)-ethyl]-1,7-dioxa-spiro[5.5]undec-4-yl ester

410077-66-6

Carbonic acid tert-butyl ester (R)-1-[2-(naphthalen-2-ylmethoxy)-ethyl]-but-3-enyl ester

410077-71-3

Acetic acid (2S,4S,6R,8S,10S)-10-hydroxy-8-[(R)-4-(4-methoxy-benzyloxy)-3-methyl-2-methylene-butyl]-10-methyl-2-[2-(naphthalen-2-ylmethoxy)-ethyl]-1,7-dioxa-spiro[5.5]undec-4-yl ester

410077-49-5

(2S,4S,7R)-8-(4-Methoxy-benzyloxy)-2,7-dimethyl-6-methylene-1-{2-[(2S,4S)-6-(naphthalen-2-ylmethoxy)-2,4-bis-triethylsilanyloxy-hexyl]-[1,3]dithian-2-yl}-octane-2,4-diol

410077-71-3

Acetic acid (2S,4S,6R,8S,10S)-10-hydroxy-8-[(R)-4-(4-methoxy-benzyloxy)-3-methyl-2-methylene-butyl]-10-methyl-2-[2-(naphthalen-2-ylmethoxy)-ethyl]-1,7-dioxa-spiro[5.5]undec-4-yl ester

上游原料

(2S,4S,7R)-1-(tert-Butyl-diphenyl-silanyloxy)-8-(4-methoxy-benzyloxy)-2,7-dimethyl-6-methylene-octane-2,4-diol (2S,4S,7R)-8-(4-Methoxy-benzyloxy)-2,7-dimethyl-6-methylene-1-{2-[(2S,4S)-6-(naphthalen-2-ylmethoxy)-2,4-bis-triethylsilanyloxy-hexyl]-[1,3]dithian-2-yl}-octane-2,4-diol (4S,6R)-4-(tert-Butyl-diphenyl-silanyloxymethyl)-6-iodomethyl-4-methyl-[1,3]dioxan-2-one Carbonic acid tert-butyl ester (S)-1-(tert-butyl-diphenyl-silanyloxymethyl)-1-methyl-but-3-enyl ester Carbonic acid tert-butyl ester (R)-1-[2-(naphthalen-2-ylmethoxy)-ethyl]-but-3-enyl ester

下游产品

triisopropylsilyl 2-((2R,4S,6S,8S,10S)-4-acetoxy-8-((R)-4-((4-methoxybenzyl)oxy)-3-methyl-2-methylenebutyl)-10-methyl-10-((triethylsilyl)oxy)-1,7-dioxaspiro[5.5]undecan-2-yl)acetate