百科

2-((1R,2S,4S,5S)-3-Methylene-1,2,4,5-tetrakis-triethylsilanyloxy-7-trimethylsilanyl-hept-6-ynyl)-[1,3]dithiane

2-((1R,2S,4S,5S)-3-Methylene-1,2,4,5-tetrakis-triethylsilanyloxy-7-trimethylsilanyl-hept-6-ynyl)-[1,3]dithiane

CAS号：423158-98-9

英文名：2-((1R,2S,4S,5S)-3-Methylene-1,2,4,5-tetrakis-triethylsilanyloxy-7-trimethylsilanyl-hept-6-ynyl)-[1,3]dithiane

分子式：C39H82O4S2Si5

分子量：819.623

合成路线

(2S,4S,5R,6S)-4,5-Bis-benzyloxy-6-methoxy-3-methylene-tetrahydro-pyran-2-carbaldehyde

(2S,4S,5R,6S)-4,5-Bis-benzyloxy-6-methoxy-3-methylene-tetrahydro-pyran-2-carbaldehyde

2-((1R,2S,4S,5S)-3-Methylene-1,2,4,5-tetrakis-triethylsilanyloxy-7-trimethylsilanyl-hept-6-ynyl)-[1,3]dithiane

2-((1R,2S,4S,5S)-3-Methylene-1,2,4,5-tetrakis-triethylsilanyloxy-7-trimethylsilanyl-hept-6-ynyl)-[1,3]dithiane

(2S,3R,4S,6S)-6-((S)-1-Hydroxy-3-trimethylsilanyl-prop-2-ynyl)-2-methoxy-5-methylene-tetrahydro-pyran-3,4-diol

(2S,3R,4S,6S)-6-((S)-1-Hydroxy-3-trimethylsilanyl-prop-2-ynyl)-2-methoxy-5-methylene-tetrahydro-pyran-3,4-diol

2-((1R,2S,4S,5S)-3-Methylene-1,2,4,5-tetrakis-triethylsilanyloxy-7-trimethylsilanyl-hept-6-ynyl)-[1,3]dithiane

2-((1R,2S,4S,5S)-3-Methylene-1,2,4,5-tetrakis-triethylsilanyloxy-7-trimethylsilanyl-hept-6-ynyl)-[1,3]dithiane

(S)-1-((2S,4S,5R,6S)-4,5-Bis-benzyloxy-6-methoxy-3-methylene-tetrahydro-pyran-2-yl)-3-trimethylsilanyl-prop-2-yn-1-ol

(S)-1-((2S,4S,5R,6S)-4,5-Bis-benzyloxy-6-methoxy-3-methylene-tetrahydro-pyran-2-yl)-3-trimethylsilanyl-prop-2-yn-1-ol

2-((1R,2S,4S,5S)-3-Methylene-1,2,4,5-tetrakis-triethylsilanyloxy-7-trimethylsilanyl-hept-6-ynyl)-[1,3]dithiane

2-((1R,2S,4S,5S)-3-Methylene-1,2,4,5-tetrakis-triethylsilanyloxy-7-trimethylsilanyl-hept-6-ynyl)-[1,3]dithiane

上游原料

(2S,3R,4S,6S)-6-((S)-1-Hydroxy-3-trimethylsilanyl-prop-2-ynyl)-2-methoxy-5-methylene-tetrahydro-pyran-3,4-diol (S)-1-((2S,4S,5R,6S)-4,5-Bis-benzyloxy-6-methoxy-3-methylene-tetrahydro-pyran-2-yl)-3-trimethylsilanyl-prop-2-yn-1-ol (2S,4S,5R,6S)-4,5-Bis-benzyloxy-6-methoxy-3-methylene-tetrahydro-pyran-2-carbaldehyde

下游产品

(3R,4S,6S,7S)-5-Methylene-3,4,6,7-tetrakis-triethylsilanyloxy-9-trimethylsilanyl-non-8-yn-2-one (2R,3S,5S,6S)-4-Methylene-2,3,5,6-tetrakis-triethylsilanyloxy-8-trimethylsilanyl-oct-7-ynal