百科

(5S,6R,7S)-3,3,9,9-tetraethyl-6-methyl-5-(2-(phenylthio)ethyl)-7-((S)-1-(trityloxy)propan-2-yl)-4,8-dioxa-3,9-disilaundecane

CAS号：423772-10-5

英文名：(5S,6R,7S)-3,3,9,9-tetraethyl-6-methyl-5-(2-(phenylthio)ethyl)-7-((S)-1-(trityloxy)propan-2-yl)-4,8-dioxa-3,9-disilaundecane

分子式：C46H66O3SSi2

分子量：755.25

合成路线

423772-05-8

(2S,3S,4R,5S)-7-Benzyloxy-2,4-dimethyl-1-triisopropylsilanyloxy-heptane-3,5-diol

423772-10-5

(5S,6R,7S)-3,3,9,9-tetraethyl-6-methyl-5-(2-(phenylthio)ethyl)-7-((S)-1-(trityloxy)propan-2-yl)-4,8-dioxa-3,9-disilaundecane

213385-38-7

(2S,4R,5S)-7-Benzyloxy-5-hydroxy-2,4-dimethyl-1-triisopropylsilanyloxy-heptan-3-one

423772-10-5

(5S,6R,7S)-3,3,9,9-tetraethyl-6-methyl-5-(2-(phenylthio)ethyl)-7-((S)-1-(trityloxy)propan-2-yl)-4,8-dioxa-3,9-disilaundecane

423772-08-1

(2S,3S,4R,5S)-2,4-Dimethyl-7-phenylsulfanyl-heptane-1,3,5-triol

423772-10-5

(5S,6R,7S)-3,3,9,9-tetraethyl-6-methyl-5-(2-(phenylthio)ethyl)-7-((S)-1-(trityloxy)propan-2-yl)-4,8-dioxa-3,9-disilaundecane

423772-06-9

(3S,4R,5S,6S)-4,6-Dimethyl-7-triisopropylsilanyloxy-heptane-1,3,5-triol

423772-10-5

(5S,6R,7S)-3,3,9,9-tetraethyl-6-methyl-5-(2-(phenylthio)ethyl)-7-((S)-1-(trityloxy)propan-2-yl)-4,8-dioxa-3,9-disilaundecane

423772-07-0

(2S,3S,4R,5S)-2,4-Dimethyl-7-phenylsulfanyl-1-triisopropylsilanyloxy-heptane-3,5-diol

423772-10-5

(5S,6R,7S)-3,3,9,9-tetraethyl-6-methyl-5-(2-(phenylthio)ethyl)-7-((S)-1-(trityloxy)propan-2-yl)-4,8-dioxa-3,9-disilaundecane

上游原料

(2S,3S,4R,5S)-2,4-Dimethyl-7-phenylsulfanyl-1-triisopropylsilanyloxy-heptane-3,5-diol (2S,3S,4R,5S)-2,4-Dimethyl-7-phenylsulfanyl-heptane-1,3,5-triol (2S,4R,5S)-7-Benzyloxy-5-hydroxy-2,4-dimethyl-1-triisopropylsilanyloxy-heptan-3-one (2S,3S,4R,5S)-7-Benzyloxy-2,4-dimethyl-1-triisopropylsilanyloxy-heptane-3,5-diol (3S,4R,5S,6S)-4,6-Dimethyl-7-triisopropylsilanyloxy-heptane-1,3,5-triol

下游产品

(5S,6R,7S)-3,3,9,9-tetraethyl-6-methyl-5-(2-(phenylsulfonyl)ethyl)-7-((S)-1-(trityloxy)propan-2-yl)-4,8-dioxa-3,9-disilaundecane 2,2-Dimethyl-propionic acid (10E,16E)-(3R,4R,5R,6R,9S,13R,15R,19S,20R,21S,22S)-5-(tert-butyl-dimethyl-silanyloxy)-9,15-dimethoxy-4,6,13,20,22-pentamethyl-3-methylsulfanylmethoxy-19,21-bis-triethylsilanyloxy-23-trityloxy-tricosa-10,16-dienyl ester (2E,4E,14E,20E)-(7R,8R,9R,10R,13S,17R,19R,23S,24R,25S,26S)-9-(tert-Butyl-dimethyl-silanyloxy)-23,25-dihydroxy-13,19-dimethoxy-8,10,17,24,26-pentamethyl-7-methylsulfanylmethoxy-27-trityloxy-heptacosa-2,4,14,20-tetraenoic acid ethyl ester (10E,16E)-(3R,4R,5R,6R,9S,13R,15R,19S,20R,21S,22S)-5-(tert-Butyl-dimethyl-silanyloxy)-9,15-dimethoxy-4,6,13,20,22-pentamethyl-3-methylsulfanylmethoxy-19,21-bis-triethylsilanyloxy-23-trityloxy-tricosa-10,16-dien-1-ol (10E,16E)-(3R,4R,5R,6R,9S,13R,15R,19S,20R,21S,22S)-5-(tert-Butyl-dimethyl-silanyloxy)-9,15-dimethoxy-4,6,13,20,22-pentamethyl-3-methylsulfanylmethoxy-19,21-bis-triethylsilanyloxy-23-trityloxy-tricosa-10,16-dienal (3E,5E,15E,21E)-(8R,9R,10R,11R,14S,18R,20R,24S,25R,26S)-10-(tert-Butyl-dimethyl-silanyloxy)-24-hydroxy-14,20-dimethoxy-9,11,18,25-tetramethyl-8-methylsulfanylmethoxy-26-((S)-1-methyl-2-trityloxy-ethyl)-oxacyclohexacosa-3,5,15,21-tetraen-2-one (2E,4E,14E,20E)-(7R,8R,9R,10R,13S,17R,19R,23S,24R,25S,26S)-9-(tert-Butyl-dimethyl-silanyloxy)-13,19-dimethoxy-8,10,17,24,26-pentamethyl-7-methylsulfanylmethoxy-23,25-bis-triethylsilanyloxy-27-trityloxy-heptacosa-2,4,14,20-tetraenoic acid ethyl ester