百科

(5S,6R,7S)-3,3,9,9-tetraethyl-6-methyl-5-(2-(phenylsulfonyl)ethyl)-7-((S)-1-(trityloxy)propan-2-yl)-4,8-dioxa-3,9-disilaundecane

(5S,6R,7S)-3,3,9,9-tetraethyl-6-methyl-5-(2-(phenylsulfonyl)ethyl)-7-((S)-1-(trityloxy)propan-2-yl)-4,8-dioxa-3,9-disilaundecane

CAS号：423772-11-6

英文名：(5S,6R,7S)-3,3,9,9-tetraethyl-6-methyl-5-(2-(phenylsulfonyl)ethyl)-7-((S)-1-(trityloxy)propan-2-yl)-4,8-dioxa-3,9-disilaundecane

分子式：C46H66O5SSi2

分子量：787.249

合成路线

(5S,6R,7S)-3,3,9,9-tetraethyl-6-methyl-5-(2-(phenylthio)ethyl)-7-((S)-1-(trityloxy)propan-2-yl)-4,8-dioxa-3,9-disilaundecane

(5S,6R,7S)-3,3,9,9-tetraethyl-6-methyl-5-(2-(phenylthio)ethyl)-7-((S)-1-(trityloxy)propan-2-yl)-4,8-dioxa-3,9-disilaundecane

(5S,6R,7S)-3,3,9,9-tetraethyl-6-methyl-5-(2-(phenylsulfonyl)ethyl)-7-((S)-1-(trityloxy)propan-2-yl)-4,8-dioxa-3,9-disilaundecane

(5S,6R,7S)-3,3,9,9-tetraethyl-6-methyl-5-(2-(phenylsulfonyl)ethyl)-7-((S)-1-(trityloxy)propan-2-yl)-4,8-dioxa-3,9-disilaundecane

(2S,3S,4R,5S)-2,4-Dimethyl-7-phenylsulfanyl-1-trityloxy-heptane-3,5-diol

(2S,3S,4R,5S)-2,4-Dimethyl-7-phenylsulfanyl-1-trityloxy-heptane-3,5-diol

(5S,6R,7S)-3,3,9,9-tetraethyl-6-methyl-5-(2-(phenylsulfonyl)ethyl)-7-((S)-1-(trityloxy)propan-2-yl)-4,8-dioxa-3,9-disilaundecane

(5S,6R,7S)-3,3,9,9-tetraethyl-6-methyl-5-(2-(phenylsulfonyl)ethyl)-7-((S)-1-(trityloxy)propan-2-yl)-4,8-dioxa-3,9-disilaundecane

上游原料

(2S,3S,4R,5S)-2,4-Dimethyl-7-phenylsulfanyl-1-trityloxy-heptane-3,5-diol (5S,6R,7S)-3,3,9,9-tetraethyl-6-methyl-5-(2-(phenylthio)ethyl)-7-((S)-1-(trityloxy)propan-2-yl)-4,8-dioxa-3,9-disilaundecane

下游产品

(2E,4E,14E,20E)-(7R,8R,9R,10R,13S,17R,19R,23S,24R,25S,26S)-9-(tert-Butyl-dimethyl-silanyloxy)-23,25-dihydroxy-13,19-dimethoxy-8,10,17,24,26-pentamethyl-7-methylsulfanylmethoxy-27-trityloxy-heptacosa-2,4,14,20-tetraenoic acid ethyl ester (10E,16E)-(3R,4R,5R,6R,9S,13R,15R,19S,20R,21S,22S)-5-(tert-Butyl-dimethyl-silanyloxy)-9,15-dimethoxy-4,6,13,20,22-pentamethyl-3-methylsulfanylmethoxy-19,21-bis-triethylsilanyloxy-23-trityloxy-tricosa-10,16-dien-1-ol