百科

(10E,16E)-(3R,4R,5R,6R,9S,13R,15R)-5-(tert-Butyl-dimethyl-silanyloxy)-9,15-dimethoxy-4,6,13-trimethyl-3-methylsulfanylmethoxy-19-triethylsilanyloxy-nonadeca-10,16-dien-1-ol

(10E,16E)-(3R,4R,5R,6R,9S,13R,15R)-5-(tert-Butyl-dimethyl-silanyloxy)-9,15-dimethoxy-4,6,13-trimethyl-3-methylsulfanylmethoxy-19-triethylsilanyloxy-nonadeca-10,16-dien-1-ol

CAS号：423772-26-3

英文名：(10E,16E)-(3R,4R,5R,6R,9S,13R,15R)-5-(tert-Butyl-dimethyl-silanyloxy)-9,15-dimethoxy-4,6,13-trimethyl-3-methylsulfanylmethoxy-19-triethylsilanyloxy-nonadeca-10,16-dien-1-ol

分子式：C38H78O6SSi2

分子量：719.258

合成路线

2,2-Dimethyl-propionic acid (E)-(3R,4R,5R,6R,9S,13R,15R)-5-(tert-butyl-dimethyl-silanyloxy)-9,15-dimethoxy-4,6,13-trimethyl-3-methylsulfanylmethoxy-16-trityloxy-hexadec-10-enyl ester

2,2-Dimethyl-propionic acid (E)-(3R,4R,5R,6R,9S,13R,15R)-5-(tert-butyl-dimethyl-silanyloxy)-9,15-dimethoxy-4,6,13-trimethyl-3-methylsulfanylmethoxy-16-trityloxy-hexadec-10-enyl ester

(10E,16E)-(3R,4R,5R,6R,9S,13R,15R)-5-(tert-Butyl-dimethyl-silanyloxy)-9,15-dimethoxy-4,6,13-trimethyl-3-methylsulfanylmethoxy-19-triethylsilanyloxy-nonadeca-10,16-dien-1-ol

(10E,16E)-(3R,4R,5R,6R,9S,13R,15R)-5-(tert-Butyl-dimethyl-silanyloxy)-9,15-dimethoxy-4,6,13-trimethyl-3-methylsulfanylmethoxy-19-triethylsilanyloxy-nonadeca-10,16-dien-1-ol

2,2-Dimethyl-propionic acid (10E,16E)-(3R,4R,5R,6R,9S,13R,15R)-5-(tert-butyl-dimethyl-silanyloxy)-9,15-dimethoxy-4,6,13-trimethyl-3-methylsulfanylmethoxy-19-triethylsilanyloxy-nonadeca-10,16-dienyl ester

2,2-Dimethyl-propionic acid (10E,16E)-(3R,4R,5R,6R,9S,13R,15R)-5-(tert-butyl-dimethyl-silanyloxy)-9,15-dimethoxy-4,6,13-trimethyl-3-methylsulfanylmethoxy-19-triethylsilanyloxy-nonadeca-10,16-dienyl ester

(10E,16E)-(3R,4R,5R,6R,9S,13R,15R)-5-(tert-Butyl-dimethyl-silanyloxy)-9,15-dimethoxy-4,6,13-trimethyl-3-methylsulfanylmethoxy-19-triethylsilanyloxy-nonadeca-10,16-dien-1-ol

(10E,16E)-(3R,4R,5R,6R,9S,13R,15R)-5-(tert-Butyl-dimethyl-silanyloxy)-9,15-dimethoxy-4,6,13-trimethyl-3-methylsulfanylmethoxy-19-triethylsilanyloxy-nonadeca-10,16-dien-1-ol

((((2R,4S)-2-methoxy-4-methyl-6-(phenylsulfonyl)hexyl)oxy)methanetriyl)tribenzene

((((2R,4S)-2-methoxy-4-methyl-6-(phenylsulfonyl)hexyl)oxy)methanetriyl)tribenzene

(10E,16E)-(3R,4R,5R,6R,9S,13R,15R)-5-(tert-Butyl-dimethyl-silanyloxy)-9,15-dimethoxy-4,6,13-trimethyl-3-methylsulfanylmethoxy-19-triethylsilanyloxy-nonadeca-10,16-dien-1-ol

(10E,16E)-(3R,4R,5R,6R,9S,13R,15R)-5-(tert-Butyl-dimethyl-silanyloxy)-9,15-dimethoxy-4,6,13-trimethyl-3-methylsulfanylmethoxy-19-triethylsilanyloxy-nonadeca-10,16-dien-1-ol

上游原料

2,2-Dimethyl-propionic acid (10E,16E)-(3R,4R,5R,6R,9S,13R,15R)-5-(tert-butyl-dimethyl-silanyloxy)-9,15-dimethoxy-4,6,13-trimethyl-3-methylsulfanylmethoxy-19-triethylsilanyloxy-nonadeca-10,16-dienyl ester 2,2-Dimethyl-propionic acid (E)-(3R,4R,5R,6R,9S,13R,15R)-5-(tert-butyl-dimethyl-silanyloxy)-9,15-dimethoxy-4,6,13-trimethyl-3-methylsulfanylmethoxy-16-trityloxy-hexadec-10-enyl ester ((((2R,4S)-2-methoxy-4-methyl-6-(phenylsulfonyl)hexyl)oxy)methanetriyl)tribenzene

下游产品

(2E,4E,14E,20E)-(7R,8R,9R,10R,13S,17R,19R)-9-(tert-Butyl-dimethyl-silanyloxy)-23-hydroxy-13,19-dimethoxy-8,10,17-trimethyl-7-methylsulfanylmethoxy-tricosa-2,4,14,20-tetraenoic acid ethyl ester