百科

(1S,2S,4R,5R,6R)-5-Hydroxymethyl-4-methoxymethoxy-5-methyl-6-((S)-2,2,5,5-tetramethyl-[1,3]dioxolan-4-yl)-bicyclo[2.2.1]heptan-2-ol

(1S,2S,4R,5R,6R)-5-Hydroxymethyl-4-methoxymethoxy-5-methyl-6-((S)-2,2,5,5-tetramethyl-[1,3]dioxolan-4-yl)-bicyclo[2.2.1]heptan-2-ol

CAS号：434342-89-9

英文名：(1S,2S,4R,5R,6R)-5-Hydroxymethyl-4-methoxymethoxy-5-methyl-6-((S)-2,2,5,5-tetramethyl-[1,3]dioxolan-4-yl)-bicyclo[2.2.1]heptan-2-ol

分子式：C18H32O6

分子量：344.443

合成路线

(1R,2S,3R,4S)-1-Methoxymethoxy-2-methyl-5-oxo-3-((S)-2,2,5,5-tetramethyl-[1,3]dioxolan-4-yl)-bicyclo[2.2.1]heptane-2-carboxylic acid ethyl ester

(1R,2S,3R,4S)-1-Methoxymethoxy-2-methyl-5-oxo-3-((S)-2,2,5,5-tetramethyl-[1,3]dioxolan-4-yl)-bicyclo[2.2.1]heptane-2-carboxylic acid ethyl ester

(1S,2S,4R,5R,6R)-5-Hydroxymethyl-4-methoxymethoxy-5-methyl-6-((S)-2,2,5,5-tetramethyl-[1,3]dioxolan-4-yl)-bicyclo[2.2.1]heptan-2-ol

(1S,2S,4R,5R,6R)-5-Hydroxymethyl-4-methoxymethoxy-5-methyl-6-((S)-2,2,5,5-tetramethyl-[1,3]dioxolan-4-yl)-bicyclo[2.2.1]heptan-2-ol

(E)-2-Methyl-3-((S)-2,2,5,5-tetramethyl-[1,3]dioxolan-4-yl)-acrylic acid ethyl ester

(E)-2-Methyl-3-((S)-2,2,5,5-tetramethyl-[1,3]dioxolan-4-yl)-acrylic acid ethyl ester

(1S,2S,4R,5R,6R)-5-Hydroxymethyl-4-methoxymethoxy-5-methyl-6-((S)-2,2,5,5-tetramethyl-[1,3]dioxolan-4-yl)-bicyclo[2.2.1]heptan-2-ol

(1S,2S,4R,5R,6R)-5-Hydroxymethyl-4-methoxymethoxy-5-methyl-6-((S)-2,2,5,5-tetramethyl-[1,3]dioxolan-4-yl)-bicyclo[2.2.1]heptan-2-ol

(4'S)-(2',2',5',5'-tetramethyl-1',3'-dioxolan-4'-yl)methanol

(4'S)-(2',2',5',5'-tetramethyl-1',3'-dioxolan-4'-yl)methanol

(1S,2S,4R,5R,6R)-5-Hydroxymethyl-4-methoxymethoxy-5-methyl-6-((S)-2,2,5,5-tetramethyl-[1,3]dioxolan-4-yl)-bicyclo[2.2.1]heptan-2-ol

(1S,2S,4R,5R,6R)-5-Hydroxymethyl-4-methoxymethoxy-5-methyl-6-((S)-2,2,5,5-tetramethyl-[1,3]dioxolan-4-yl)-bicyclo[2.2.1]heptan-2-ol

上游原料

(E)-2-Methyl-3-((S)-2,2,5,5-tetramethyl-[1,3]dioxolan-4-yl)-acrylic acid ethyl ester (1R,2S,3R,4S)-1-Methoxymethoxy-2-methyl-5-oxo-3-((S)-2,2,5,5-tetramethyl-[1,3]dioxolan-4-yl)-bicyclo[2.2.1]heptane-2-carboxylic acid ethyl ester (4'S)-(2',2',5',5'-tetramethyl-1',3'-dioxolan-4'-yl)methanol

下游产品

(S)-1-((1S,2R,3R,4R,6S)-6-Benzyloxy-3-benzyloxymethyl-4-hydroxy-3-methyl-bicyclo[2.2.1]hept-2-yl)-2-methyl-propane-1,2-diol