百科

(S)-1-((1S,2R,3R,4R,6S)-6-Benzyloxy-3-benzyloxymethyl-4-hydroxy-3-methyl-bicyclo[2.2.1]hept-2-yl)-2-methyl-propane-1,2-diol

(S)-1-((1S,2R,3R,4R,6S)-6-Benzyloxy-3-benzyloxymethyl-4-hydroxy-3-methyl-bicyclo[2.2.1]hept-2-yl)-2-methyl-propane-1,2-diol

CAS号：434342-90-2

英文名：(S)-1-((1S,2R,3R,4R,6S)-6-Benzyloxy-3-benzyloxymethyl-4-hydroxy-3-methyl-bicyclo[2.2.1]hept-2-yl)-2-methyl-propane-1,2-diol

分子式：C27H36O5

分子量：440.572

合成路线

434342-76-4

(S)-1-((1S,2R,3R,4R,6S)-6-Benzyloxy-3-benzyloxymethyl-4-hydroxy-3-methyl-bicyclo[2.2.1]hept-2-yl)-2-methyl-propane-1,2-diol

(S)-1-((1S,2R,3R,4R,6S)-6-Benzyloxy-3-benzyloxymethyl-4-hydroxy-3-methyl-bicyclo[2.2.1]hept-2-yl)-2-methyl-propane-1,2-diol

(4'S)-(2',2',5',5'-tetramethyl-1',3'-dioxolan-4'-yl)methanol

(4'S)-(2',2',5',5'-tetramethyl-1',3'-dioxolan-4'-yl)methanol

(S)-1-((1S,2R,3R,4R,6S)-6-Benzyloxy-3-benzyloxymethyl-4-hydroxy-3-methyl-bicyclo[2.2.1]hept-2-yl)-2-methyl-propane-1,2-diol

(S)-1-((1S,2R,3R,4R,6S)-6-Benzyloxy-3-benzyloxymethyl-4-hydroxy-3-methyl-bicyclo[2.2.1]hept-2-yl)-2-methyl-propane-1,2-diol

(4R)-2,2,5,5-Tetramethyl-1,3-dioxolane-4-carboxaldehyde

(4R)-2,2,5,5-Tetramethyl-1,3-dioxolane-4-carboxaldehyde

(S)-1-((1S,2R,3R,4R,6S)-6-Benzyloxy-3-benzyloxymethyl-4-hydroxy-3-methyl-bicyclo[2.2.1]hept-2-yl)-2-methyl-propane-1,2-diol

(S)-1-((1S,2R,3R,4R,6S)-6-Benzyloxy-3-benzyloxymethyl-4-hydroxy-3-methyl-bicyclo[2.2.1]hept-2-yl)-2-methyl-propane-1,2-diol

(E)-2-Methyl-3-((S)-2,2,5,5-tetramethyl-[1,3]dioxolan-4-yl)-acrylic acid ethyl ester

(E)-2-Methyl-3-((S)-2,2,5,5-tetramethyl-[1,3]dioxolan-4-yl)-acrylic acid ethyl ester

(S)-1-((1S,2R,3R,4R,6S)-6-Benzyloxy-3-benzyloxymethyl-4-hydroxy-3-methyl-bicyclo[2.2.1]hept-2-yl)-2-methyl-propane-1,2-diol

(S)-1-((1S,2R,3R,4R,6S)-6-Benzyloxy-3-benzyloxymethyl-4-hydroxy-3-methyl-bicyclo[2.2.1]hept-2-yl)-2-methyl-propane-1,2-diol

(1S,2S,4R,5R,6R)-5-Hydroxymethyl-4-methoxymethoxy-5-methyl-6-((S)-2,2,5,5-tetramethyl-[1,3]dioxolan-4-yl)-bicyclo[2.2.1]heptan-2-ol

(1S,2S,4R,5R,6R)-5-Hydroxymethyl-4-methoxymethoxy-5-methyl-6-((S)-2,2,5,5-tetramethyl-[1,3]dioxolan-4-yl)-bicyclo[2.2.1]heptan-2-ol

(S)-1-((1S,2R,3R,4R,6S)-6-Benzyloxy-3-benzyloxymethyl-4-hydroxy-3-methyl-bicyclo[2.2.1]hept-2-yl)-2-methyl-propane-1,2-diol

(S)-1-((1S,2R,3R,4R,6S)-6-Benzyloxy-3-benzyloxymethyl-4-hydroxy-3-methyl-bicyclo[2.2.1]hept-2-yl)-2-methyl-propane-1,2-diol

(1R,2S,3R,4S)-1-Methoxymethoxy-2-methyl-5-oxo-3-((S)-2,2,5,5-tetramethyl-[1,3]dioxolan-4-yl)-bicyclo[2.2.1]heptane-2-carboxylic acid ethyl ester

(1R,2S,3R,4S)-1-Methoxymethoxy-2-methyl-5-oxo-3-((S)-2,2,5,5-tetramethyl-[1,3]dioxolan-4-yl)-bicyclo[2.2.1]heptane-2-carboxylic acid ethyl ester

(S)-1-((1S,2R,3R,4R,6S)-6-Benzyloxy-3-benzyloxymethyl-4-hydroxy-3-methyl-bicyclo[2.2.1]hept-2-yl)-2-methyl-propane-1,2-diol

(S)-1-((1S,2R,3R,4R,6S)-6-Benzyloxy-3-benzyloxymethyl-4-hydroxy-3-methyl-bicyclo[2.2.1]hept-2-yl)-2-methyl-propane-1,2-diol

上游原料

(E)-2-Methyl-3-((S)-2,2,5,5-tetramethyl-[1,3]dioxolan-4-yl)-acrylic acid ethyl ester (1R,2S,3R,4S)-1-Methoxymethoxy-2-methyl-5-oxo-3-((S)-2,2,5,5-tetramethyl-[1,3]dioxolan-4-yl)-bicyclo[2.2.1]heptane-2-carboxylic acid ethyl ester (4R)-2,2,5,5-Tetramethyl-1,3-dioxolane-4-carboxaldehyde (4'S)-(2',2',5',5'-tetramethyl-1',3'-dioxolan-4'-yl)methanol (1S,2S,4R,5R,6R)-5-Hydroxymethyl-4-methoxymethoxy-5-methyl-6-((S)-2,2,5,5-tetramethyl-[1,3]dioxolan-4-yl)-bicyclo[2.2.1]heptan-2-ol

下游产品

(1S,2S,3R,4R,6S)-2-Allyl-6-benzyloxy-3-benzyloxymethyl-4-methoxymethoxy-3-methyl-bicyclo[2.2.1]heptane-2-carbaldehyde (1R,2R,3R,4S,5S)-5-Benzyloxy-2-benzyloxymethyl-1-methoxymethoxy-2-methyl-3-phenylsulfanylmethyl-bicyclo[2.2.1]heptane (1R,2R,4S,5S)-3-[1-Allyloxy-meth-(E)-ylidene]-5-benzyloxy-2-benzyloxymethyl-1-methoxymethoxy-2-methyl-bicyclo[2.2.1]heptane (1S,2R,3R,4R,6S)-6-Benzyloxy-3-benzyloxymethyl-4-hydroxy-3-methyl-bicyclo[2.2.1]heptane-2-carbaldehyde (1R,2R,3R,4S,5S)-3-Benzenesulfinylmethyl-5-benzyloxy-2-benzyloxymethyl-1-methoxymethoxy-2-methyl-bicyclo[2.2.1]heptane ((1S,2R,3R,4R,6S)-6-Benzyloxy-3-benzyloxymethyl-4-methoxymethoxy-3-methyl-bicyclo[2.2.1]hept-2-yl)-methanol