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(E)-(4R,5S)-4-Benzyloxy-5-(tert-butyl-dimethyl-silanyloxy)-hex-2-enoic acid (E)-(1S,2R)-2-benzyloxy-1-methyl-4-[(S)-1-methyl-2-(2,2,2-trichloro-ethoxycarbonyl)-ethoxycarbonyl]-but-3-enyl ester

CAS号：434938-20-2

英文名：(E)-(4R,5S)-4-Benzyloxy-5-(tert-butyl-dimethyl-silanyloxy)-hex-2-enoic acid (E)-(1S,2R)-2-benzyloxy-1-methyl-4-[(S)-1-methyl-2-(2,2,2-trichloro-ethoxycarbonyl)-ethoxycarbonyl]-but-3-enyl ester

分子式：C38H51Cl3O9Si

分子量：786.251

合成路线

434938-15-5

(S)-3-Hydroxy-butyric acid 2,2,2-trichloro-ethyl ester

434938-20-2

(E)-(4R,5S)-4-Benzyloxy-5-(tert-butyl-dimethyl-silanyloxy)-hex-2-enoic acid (E)-(1S,2R)-2-benzyloxy-1-methyl-4-[(S)-1-methyl-2-(2,2,2-trichloro-ethoxycarbonyl)-ethoxycarbonyl]-but-3-enyl ester

434938-18-8

(E)-(4R,5S)-4-Benzyloxy-5-(tert-butyl-dimethyl-silanyloxy)-hex-2-enoic acid (S)-1-methyl-2-(2,2,2-trichloro-ethoxycarbonyl)-ethyl ester

434938-20-2

(E)-(4R,5S)-4-Benzyloxy-5-(tert-butyl-dimethyl-silanyloxy)-hex-2-enoic acid (E)-(1S,2R)-2-benzyloxy-1-methyl-4-[(S)-1-methyl-2-(2,2,2-trichloro-ethoxycarbonyl)-ethoxycarbonyl]-but-3-enyl ester

上游原料

(E)-(4R,5S)-4-Benzyloxy-5-(tert-butyl-dimethyl-silanyloxy)-hex-2-enoic acid (S)-1-methyl-2-(2,2,2-trichloro-ethoxycarbonyl)-ethyl ester (S)-3-Hydroxy-butyric acid 2,2,2-trichloro-ethyl ester

下游产品

(E)-(4R,5S)-4-Benzyloxy-5-hydroxy-hex-2-enoic acid (E)-(1S,2R)-2-benzyloxy-4-((S)-2-carboxy-1-methyl-ethoxycarbonyl)-1-methyl-but-3-enyl ester (E)-(4R,5S)-4-Benzyloxy-5-hydroxy-hex-2-enoic acid (E)-(1S,2R)-2-benzyloxy-1-methyl-4-[(S)-1-methyl-2-(2,2,2-trichloro-ethoxycarbonyl)-ethoxycarbonyl]-but-3-enyl ester (-)-dibenzyl macrosphelide A