百科

[(2S,3R,5S,6R)-5-Benzyloxy-6-benzyloxymethyl-2-((R)-1-benzyloxy-2-(2R,4aR,8aS)-4,4a,6,8a-tetrahydro-pyrano[3,2-d][1,3]dioxin-2-yl-ethyl)-2-methyl-tetrahydro-pyran-3-yloxy]-triisopropyl-silane

CAS号：438002-56-3

英文名：[(2S,3R,5S,6R)-5-Benzyloxy-6-benzyloxymethyl-2-((R)-1-benzyloxy-2-(2R,4aR,8aS)-4,4a,6,8a-tetrahydro-pyrano[3,2-d][1,3]dioxin-2-yl-ethyl)-2-methyl-tetrahydro-pyran-3-yloxy]-triisopropyl-silane

分子式：C46H64O8Si

分子量：773.081

合成路线

131310-61-7

(2R,4aR,6S,7R,8aS)-6-Methyl-2-phenyl-6-vinyl-hexahydro-pyrano[3,2-d][1,3]dioxin-7-ol

438002-56-3

[(2S,3R,5S,6R)-5-Benzyloxy-6-benzyloxymethyl-2-((R)-1-benzyloxy-2-(2R,4aR,8aS)-4,4a,6,8a-tetrahydro-pyrano[3,2-d][1,3]dioxin-2-yl-ethyl)-2-methyl-tetrahydro-pyran-3-yloxy]-triisopropyl-silane

438002-76-7

(2R,3S,5R,6S)-2-Hydroxymethyl-6-methyl-5-triisopropylsilanyloxy-6-vinyl-tetrahydro-pyran-3-ol

438002-56-3

[(2S,3R,5S,6R)-5-Benzyloxy-6-benzyloxymethyl-2-((R)-1-benzyloxy-2-(2R,4aR,8aS)-4,4a,6,8a-tetrahydro-pyrano[3,2-d][1,3]dioxin-2-yl-ethyl)-2-methyl-tetrahydro-pyran-3-yloxy]-triisopropyl-silane

上游原料

(2R,4aR,6S,7R,8aS)-6-Methyl-2-phenyl-6-vinyl-hexahydro-pyrano[3,2-d][1,3]dioxin-7-ol (2R,3S,5R,6S)-2-Hydroxymethyl-6-methyl-5-triisopropylsilanyloxy-6-vinyl-tetrahydro-pyran-3-ol

下游产品

(E)-3-{(2S,3R,5S,6R)-5-Benzyloxy-6-benzyloxymethyl-2-[(1R,3S)-1-benzyloxy-3-phenylsulfanyl-3-((2R,3S)-2-triisopropylsilanyloxymethyl-3,6-dihydro-2H-pyran-3-yloxy)-propyl]-2-methyl-tetrahydro-pyran-3-yloxy}-acrylic acid methyl ester (2R,3R,5S,6R)-5-Benzyloxy-2-[(1R,3S)-1-benzyloxy-3-((2R,3S)-2-hydroxymethyl-3,6-dihydro-2H-pyran-3-yloxy)-3-phenylselanyl-propyl]-6-benzyloxymethyl-2-methyl-tetrahydro-pyran-3-ol