百科

(2R,3R,5S,6R)-5-Benzyloxy-2-[(1R,3S)-1-benzyloxy-3-((2R,3S)-2-hydroxymethyl-3,6-dihydro-2H-pyran-3-yloxy)-3-phenylselanyl-propyl]-6-benzyloxymethyl-2-methyl-tetrahydro-pyran-3-ol

CAS号：438002-90-5

英文名：(2R,3R,5S,6R)-5-Benzyloxy-2-[(1R,3S)-1-benzyloxy-3-((2R,3S)-2-hydroxymethyl-3,6-dihydro-2H-pyran-3-yloxy)-3-phenylselanyl-propyl]-6-benzyloxymethyl-2-methyl-tetrahydro-pyran-3-ol

分子式：C43H50O8Se

分子量：773.812

合成路线

438002-76-7

(2R,3S,5R,6S)-2-Hydroxymethyl-6-methyl-5-triisopropylsilanyloxy-6-vinyl-tetrahydro-pyran-3-ol

438002-90-5

(2R,3R,5S,6R)-5-Benzyloxy-2-[(1R,3S)-1-benzyloxy-3-((2R,3S)-2-hydroxymethyl-3,6-dihydro-2H-pyran-3-yloxy)-3-phenylselanyl-propyl]-6-benzyloxymethyl-2-methyl-tetrahydro-pyran-3-ol

438002-60-9

{(2R,3S)-3-[(1S,3R)-3-Benzyloxy-3-((2S,3R,5S,6R)-5-benzyloxy-6-benzyloxymethyl-2-methyl-3-triisopropylsilanyloxy-tetrahydro-pyran-2-yl)-1-phenylselanyl-propoxy]-3,6-dihydro-2H-pyran-2-yl}-methanol

438002-90-5

(2R,3R,5S,6R)-5-Benzyloxy-2-[(1R,3S)-1-benzyloxy-3-((2R,3S)-2-hydroxymethyl-3,6-dihydro-2H-pyran-3-yloxy)-3-phenylselanyl-propyl]-6-benzyloxymethyl-2-methyl-tetrahydro-pyran-3-ol

438002-74-5

Triisopropyl-((2R,4aR,6S,7R,8aS)-6-methyl-2-phenyl-6-vinyl-hexahydro-pyrano[3,2-d][1,3]dioxin-7-yloxy)-silane

438002-90-5

(2R,3R,5S,6R)-5-Benzyloxy-2-[(1R,3S)-1-benzyloxy-3-((2R,3S)-2-hydroxymethyl-3,6-dihydro-2H-pyran-3-yloxy)-3-phenylselanyl-propyl]-6-benzyloxymethyl-2-methyl-tetrahydro-pyran-3-ol

220864-32-4

((2S,3R,5S,6R)-5-Benzyloxy-6-benzyloxymethyl-2-methyl-2-vinyl-tetrahydro-pyran-3-yloxy)-triisopropyl-silane

438002-90-5

(2R,3R,5S,6R)-5-Benzyloxy-2-[(1R,3S)-1-benzyloxy-3-((2R,3S)-2-hydroxymethyl-3,6-dihydro-2H-pyran-3-yloxy)-3-phenylselanyl-propyl]-6-benzyloxymethyl-2-methyl-tetrahydro-pyran-3-ol

438002-45-0

(2R,3R,5S,6R)-5-Benzyloxy-6-benzyloxymethyl-2-methyl-3-triisopropylsilanyloxy-tetrahydro-pyran-2-carbaldehyde

438002-90-5

(2R,3R,5S,6R)-5-Benzyloxy-2-[(1R,3S)-1-benzyloxy-3-((2R,3S)-2-hydroxymethyl-3,6-dihydro-2H-pyran-3-yloxy)-3-phenylselanyl-propyl]-6-benzyloxymethyl-2-methyl-tetrahydro-pyran-3-ol

438002-46-1

(R)-1-((2S,3R,5S,6R)-5-Benzyloxy-6-benzyloxymethyl-2-methyl-3-triisopropylsilanyloxy-tetrahydro-pyran-2-yl)-but-3-en-1-ol

438002-90-5

(2R,3R,5S,6R)-5-Benzyloxy-2-[(1R,3S)-1-benzyloxy-3-((2R,3S)-2-hydroxymethyl-3,6-dihydro-2H-pyran-3-yloxy)-3-phenylselanyl-propyl]-6-benzyloxymethyl-2-methyl-tetrahydro-pyran-3-ol

370885-74-8

(R)-3-Benzyloxy-3-((2S,3R,5S,6R)-5-benzyloxy-6-benzyloxymethyl-2-methyl-3-triisopropylsilanyloxy-tetrahydro-pyran-2-yl)-propionaldehyde

438002-90-5

(2R,3R,5S,6R)-5-Benzyloxy-2-[(1R,3S)-1-benzyloxy-3-((2R,3S)-2-hydroxymethyl-3,6-dihydro-2H-pyran-3-yloxy)-3-phenylselanyl-propyl]-6-benzyloxymethyl-2-methyl-tetrahydro-pyran-3-ol

438002-48-3

[(2S,3R,5S,6R)-5-Benzyloxy-2-((R)-1-benzyloxy-but-3-enyl)-6-benzyloxymethyl-2-methyl-tetrahydro-pyran-3-yloxy]-triisopropyl-silane

438002-90-5

(2R,3R,5S,6R)-5-Benzyloxy-2-[(1R,3S)-1-benzyloxy-3-((2R,3S)-2-hydroxymethyl-3,6-dihydro-2H-pyran-3-yloxy)-3-phenylselanyl-propyl]-6-benzyloxymethyl-2-methyl-tetrahydro-pyran-3-ol

438002-84-7

(R)-4-Benzyloxy-4-((2S,3R,5S,6R)-5-benzyloxy-6-benzyloxymethyl-2-methyl-3-triisopropylsilanyloxy-tetrahydro-pyran-2-yl)-butane-1,2-diol

438002-90-5

(2R,3R,5S,6R)-5-Benzyloxy-2-[(1R,3S)-1-benzyloxy-3-((2R,3S)-2-hydroxymethyl-3,6-dihydro-2H-pyran-3-yloxy)-3-phenylselanyl-propyl]-6-benzyloxymethyl-2-methyl-tetrahydro-pyran-3-ol

438002-56-3

[(2S,3R,5S,6R)-5-Benzyloxy-6-benzyloxymethyl-2-((R)-1-benzyloxy-2-(2R,4aR,8aS)-4,4a,6,8a-tetrahydro-pyrano[3,2-d][1,3]dioxin-2-yl-ethyl)-2-methyl-tetrahydro-pyran-3-yloxy]-triisopropyl-silane

438002-90-5

(2R,3R,5S,6R)-5-Benzyloxy-2-[(1R,3S)-1-benzyloxy-3-((2R,3S)-2-hydroxymethyl-3,6-dihydro-2H-pyran-3-yloxy)-3-phenylselanyl-propyl]-6-benzyloxymethyl-2-methyl-tetrahydro-pyran-3-ol

上游原料

(R)-4-Benzyloxy-4-((2S,3R,5S,6R)-5-benzyloxy-6-benzyloxymethyl-2-methyl-3-triisopropylsilanyloxy-tetrahydro-pyran-2-yl)-butane-1,2-diol (R)-3-Benzyloxy-3-((2S,3R,5S,6R)-5-benzyloxy-6-benzyloxymethyl-2-methyl-3-triisopropylsilanyloxy-tetrahydro-pyran-2-yl)-propionaldehyde (2R,4aR,6S,7R,8aS)-6-Methyl-2-phenyl-6-vinyl-hexahydro-pyrano[3,2-d][1,3]dioxin-7-ol ((2S,3R,5S,6R)-5-Benzyloxy-6-benzyloxymethyl-2-methyl-2-vinyl-tetrahydro-pyran-3-yloxy)-triisopropyl-silane [(2S,3R,5S,6R)-5-Benzyloxy-2-((R)-1-benzyloxy-but-3-enyl)-6-benzyloxymethyl-2-methyl-tetrahydro-pyran-3-yloxy]-triisopropyl-silane (2R,3S,5R,6S)-2-Hydroxymethyl-6-methyl-5-triisopropylsilanyloxy-6-vinyl-tetrahydro-pyran-3-ol (R)-1-((2S,3R,5S,6R)-5-Benzyloxy-6-benzyloxymethyl-2-methyl-3-triisopropylsilanyloxy-tetrahydro-pyran-2-yl)-but-3-en-1-ol {(2R,3S)-3-[(1S,3R)-3-Benzyloxy-3-((2S,3R,5S,6R)-5-benzyloxy-6-benzyloxymethyl-2-methyl-3-triisopropylsilanyloxy-tetrahydro-pyran-2-yl)-1-phenylselanyl-propoxy]-3,6-dihydro-2H-pyran-2-yl}-methanol [(2S,3R,5S,6R)-5-Benzyloxy-6-benzyloxymethyl-2-((R)-1-benzyloxy-2-(2R,4aR,8aS)-4,4a,6,8a-tetrahydro-pyrano[3,2-d][1,3]dioxin-2-yl-ethyl)-2-methyl-tetrahydro-pyran-3-yloxy]-triisopropyl-silane Triisopropyl-((2R,4aR,6S,7R,8aS)-6-methyl-2-phenyl-6-vinyl-hexahydro-pyrano[3,2-d][1,3]dioxin-7-yloxy)-silane (2R,3R,5S,6R)-5-Benzyloxy-6-benzyloxymethyl-2-methyl-3-triisopropylsilanyloxy-tetrahydro-pyran-2-carbaldehyde

下游产品

(E)-3-((2S,3R,5S,6R)-5-Benzyloxy-2-{(1R,3S)-1-benzyloxy-3-[(2R,3S)-2-(tert-butyl-dimethyl-silanyloxymethyl)-3,6-dihydro-2H-pyran-3-yloxy]-3-phenylselanyl-propyl}-6-benzyloxymethyl-2-methyl-tetrahydro-pyran-3-yloxy)-acrylic acid methyl ester