百科

(2R,3S,4S,5R,6S)-3-Benzyloxy-2-methyl-5-phenylsulfanyl-6-((3aS,4R,6R,7R,7aS)-2,2,6-trimethyl-4-phenylsulfanyl-tetrahydro-[1,3]dioxolo[4,5-c]pyran-7-yloxy)-tetrahydro-pyran-4-ol

(2R,3S,4S,5R,6S)-3-Benzyloxy-2-methyl-5-phenylsulfanyl-6-((3aS,4R,6R,7R,7aS)-2,2,6-trimethyl-4-phenylsulfanyl-tetrahydro-[1,3]dioxolo[4,5-c]pyran-7-yloxy)-tetrahydro-pyran-4-ol

CAS号：439915-09-0

英文名：(2R,3S,4S,5R,6S)-3-Benzyloxy-2-methyl-5-phenylsulfanyl-6-((3aS,4R,6R,7R,7aS)-2,2,6-trimethyl-4-phenylsulfanyl-tetrahydro-[1,3]dioxolo[4,5-c]pyran-7-yloxy)-tetrahydro-pyran-4-ol

分子式：C34H40O7S2

分子量：624.807

合成路线

Thiocarbonic acid O-[(2R,3R,4S,5R,6S)-3-benzyloxy-2-methyl-5-phenylsulfanyl-6-((3aS,4R,6R,7R,7aS)-2,2,6-trimethyl-4-phenylsulfanyl-tetrahydro-[1,3]dioxolo[4,5-c]pyran-7-yloxy)-tetrahydro-pyran-4-yl] ester S-methyl ester

Thiocarbonic acid O-[(2R,3R,4S,5R,6S)-3-benzyloxy-2-methyl-5-phenylsulfanyl-6-((3aS,4R,6R,7R,7aS)-2,2,6-trimethyl-4-phenylsulfanyl-tetrahydro-[1,3]dioxolo[4,5-c]pyran-7-yloxy)-tetrahydro-pyran-4-yl] ester S-methyl ester

(2R,3S,4S,5R,6S)-3-Benzyloxy-2-methyl-5-phenylsulfanyl-6-((3aS,4R,6R,7R,7aS)-2,2,6-trimethyl-4-phenylsulfanyl-tetrahydro-[1,3]dioxolo[4,5-c]pyran-7-yloxy)-tetrahydro-pyran-4-ol

(2R,3S,4S,5R,6S)-3-Benzyloxy-2-methyl-5-phenylsulfanyl-6-((3aS,4R,6R,7R,7aS)-2,2,6-trimethyl-4-phenylsulfanyl-tetrahydro-[1,3]dioxolo[4,5-c]pyran-7-yloxy)-tetrahydro-pyran-4-ol

Phenyl 4-O-benzyl-1-thio-α-D-rhamnopyranoside

Phenyl 4-O-benzyl-1-thio-α-D-rhamnopyranoside

(2R,3S,4S,5R,6S)-3-Benzyloxy-2-methyl-5-phenylsulfanyl-6-((3aS,4R,6R,7R,7aS)-2,2,6-trimethyl-4-phenylsulfanyl-tetrahydro-[1,3]dioxolo[4,5-c]pyran-7-yloxy)-tetrahydro-pyran-4-ol

(2R,3S,4S,5R,6S)-3-Benzyloxy-2-methyl-5-phenylsulfanyl-6-((3aS,4R,6R,7R,7aS)-2,2,6-trimethyl-4-phenylsulfanyl-tetrahydro-[1,3]dioxolo[4,5-c]pyran-7-yloxy)-tetrahydro-pyran-4-ol

Phenyl 2,3-O-isopropylidene-1-thio-α-D-rhamnopyranoside

Phenyl 2,3-O-isopropylidene-1-thio-α-D-rhamnopyranoside

(2R,3S,4S,5R,6S)-3-Benzyloxy-2-methyl-5-phenylsulfanyl-6-((3aS,4R,6R,7R,7aS)-2,2,6-trimethyl-4-phenylsulfanyl-tetrahydro-[1,3]dioxolo[4,5-c]pyran-7-yloxy)-tetrahydro-pyran-4-ol

(2R,3S,4S,5R,6S)-3-Benzyloxy-2-methyl-5-phenylsulfanyl-6-((3aS,4R,6R,7R,7aS)-2,2,6-trimethyl-4-phenylsulfanyl-tetrahydro-[1,3]dioxolo[4,5-c]pyran-7-yloxy)-tetrahydro-pyran-4-ol

Phenyl 4-O-benzyl-2,3-O-isopropylidene-1-thio-α-D-rhamnopyranoside

Phenyl 4-O-benzyl-2,3-O-isopropylidene-1-thio-α-D-rhamnopyranoside

(2R,3S,4S,5R,6S)-3-Benzyloxy-2-methyl-5-phenylsulfanyl-6-((3aS,4R,6R,7R,7aS)-2,2,6-trimethyl-4-phenylsulfanyl-tetrahydro-[1,3]dioxolo[4,5-c]pyran-7-yloxy)-tetrahydro-pyran-4-ol

(2R,3S,4S,5R,6S)-3-Benzyloxy-2-methyl-5-phenylsulfanyl-6-((3aS,4R,6R,7R,7aS)-2,2,6-trimethyl-4-phenylsulfanyl-tetrahydro-[1,3]dioxolo[4,5-c]pyran-7-yloxy)-tetrahydro-pyran-4-ol

上游原料

Phenyl 2,3-O-isopropylidene-1-thio-α-D-rhamnopyranoside Phenyl 4-O-benzyl-1-thio-α-D-rhamnopyranoside Phenyl 4-O-benzyl-2,3-O-isopropylidene-1-thio-α-D-rhamnopyranoside Thiocarbonic acid O-[(2R,3R,4S,5R,6S)-3-benzyloxy-2-methyl-5-phenylsulfanyl-6-((3aS,4R,6R,7R,7aS)-2,2,6-trimethyl-4-phenylsulfanyl-tetrahydro-[1,3]dioxolo[4,5-c]pyran-7-yloxy)-tetrahydro-pyran-4-yl] ester S-methyl ester

下游产品

Thiocarbonic acid O-[(2R,3R,4S,5R,6S)-3-((2S,3R,4S,5S,6R)-5-benzyloxy-4-hydroxy-6-methyl-3-phenylsulfanyl-tetrahydro-pyran-2-yloxy)-6-(4-methoxy-phenoxy)-2-methyl-5-phenylsulfanyl-tetrahydro-pyran-4-yl] ester S-methyl ester