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(5S,8R,9R)-8-tert-butyldiphenylsiloxymethyl-9-hydroxy-9-methoxycarbonyl-1,7-dioxaspiro[4.4]non-3-ene-2,6-dione

(5S,8R,9R)-8-tert-butyldiphenylsiloxymethyl-9-hydroxy-9-methoxycarbonyl-1,7-dioxaspiro[4.4]non-3-ene-2,6-dione

CAS号：440641-05-4

英文名：(5S,8R,9R)-8-tert-butyldiphenylsiloxymethyl-9-hydroxy-9-methoxycarbonyl-1,7-dioxaspiro[4.4]non-3-ene-2,6-dione

分子式：C26H28O8Si

分子量：496.581

合成路线

methyl (3R)-4-tert-butyldiphenylsiloxy-3-(5-phenylthio-2-furoyloxy)-2-oxobutanoate

methyl (3R)-4-tert-butyldiphenylsiloxy-3-(5-phenylthio-2-furoyloxy)-2-oxobutanoate

(5R,8R,9S)-8-(tert-butyldiphenylsiloxymethyl)-9-hydroxy-9-methoxycarbonyl-1,7-dioxaspiro[4.4]non-3-ene-2,6-dione

(5R,8R,9S)-8-(tert-butyldiphenylsiloxymethyl)-9-hydroxy-9-methoxycarbonyl-1,7-dioxaspiro[4.4]non-3-ene-2,6-dione

(5R,8R,9R)-8-tert-butyldiphenylsiloxymethyl-9-hydroxy-9-methoxycarbonyl-1,7-dioxaspiro[4.4]non-3-ene-2,6-dione

(5R,8R,9R)-8-tert-butyldiphenylsiloxymethyl-9-hydroxy-9-methoxycarbonyl-1,7-dioxaspiro[4.4]non-3-ene-2,6-dione

(5S,8R,9S)-8-tert-butyldiphenylsiloxymethyl-9-hydroxy-9-methoxycarbonyl-1,7-dioxaspiro[4.4]non-3-ene-2,6-dione

(5S,8R,9S)-8-tert-butyldiphenylsiloxymethyl-9-hydroxy-9-methoxycarbonyl-1,7-dioxaspiro[4.4]non-3-ene-2,6-dione

(5S,8R,9R)-8-tert-butyldiphenylsiloxymethyl-9-hydroxy-9-methoxycarbonyl-1,7-dioxaspiro[4.4]non-3-ene-2,6-dione

(5S,8R,9R)-8-tert-butyldiphenylsiloxymethyl-9-hydroxy-9-methoxycarbonyl-1,7-dioxaspiro[4.4]non-3-ene-2,6-dione

(5R,8R,9S)-8-(tert-butyldiphenylsiloxymethyl)-9-hydroxy-9-methoxycarbonyl-1,7-dioxaspiro[4.4]non-3-ene-2,6-dione

(5R,8R,9S)-8-(tert-butyldiphenylsiloxymethyl)-9-hydroxy-9-methoxycarbonyl-1,7-dioxaspiro[4.4]non-3-ene-2,6-dione

(5R,8R,9R)-8-tert-butyldiphenylsiloxymethyl-9-hydroxy-9-methoxycarbonyl-1,7-dioxaspiro[4.4]non-3-ene-2,6-dione

(5R,8R,9R)-8-tert-butyldiphenylsiloxymethyl-9-hydroxy-9-methoxycarbonyl-1,7-dioxaspiro[4.4]non-3-ene-2,6-dione

(5S,8R,9S)-8-tert-butyldiphenylsiloxymethyl-9-hydroxy-9-methoxycarbonyl-1,7-dioxaspiro[4.4]non-3-ene-2,6-dione

(5S,8R,9S)-8-tert-butyldiphenylsiloxymethyl-9-hydroxy-9-methoxycarbonyl-1,7-dioxaspiro[4.4]non-3-ene-2,6-dione

(5S,8R,9R)-8-tert-butyldiphenylsiloxymethyl-9-hydroxy-9-methoxycarbonyl-1,7-dioxaspiro[4.4]non-3-ene-2,6-dione

(5S,8R,9R)-8-tert-butyldiphenylsiloxymethyl-9-hydroxy-9-methoxycarbonyl-1,7-dioxaspiro[4.4]non-3-ene-2,6-dione

methyl (2S,3R)-4-tert-butyldiphenylsiloxy-3-(5-(4-methylphenoxy)-2-furoyloxy)-2-hydroxybutanoate

methyl (2S,3R)-4-tert-butyldiphenylsiloxy-3-(5-(4-methylphenoxy)-2-furoyloxy)-2-hydroxybutanoate

(5S,8R,9R)-8-tert-butyldiphenylsiloxymethyl-9-hydroxy-9-methoxycarbonyl-1,7-dioxaspiro[4.4]non-3-ene-2,6-dione

(5S,8R,9R)-8-tert-butyldiphenylsiloxymethyl-9-hydroxy-9-methoxycarbonyl-1,7-dioxaspiro[4.4]non-3-ene-2,6-dione

methyl (2S,3R)-4-tert-butyldiphenylsiloxy-3-(5-methoxy-2-furoyloxy)-2-(tetrahydro-2H-pyran-2-yloxy)butanoate

methyl (2S,3R)-4-tert-butyldiphenylsiloxy-3-(5-methoxy-2-furoyloxy)-2-(tetrahydro-2H-pyran-2-yloxy)butanoate

(5S,8R,9R)-8-tert-butyldiphenylsiloxymethyl-9-hydroxy-9-methoxycarbonyl-1,7-dioxaspiro[4.4]non-3-ene-2,6-dione

(5S,8R,9R)-8-tert-butyldiphenylsiloxymethyl-9-hydroxy-9-methoxycarbonyl-1,7-dioxaspiro[4.4]non-3-ene-2,6-dione

上游原料

methyl (2S,3R)-4-tert-butyldiphenylsiloxy-3-(5-(4-methylphenoxy)-2-furoyloxy)-2-hydroxybutanoate (5R,8R,9S)-8-(tert-butyldiphenylsiloxymethyl)-9-hydroxy-9-methoxycarbonyl-1,7-dioxaspiro[4.4]non-3-ene-2,6-dione methyl (2S,3R)-4-tert-butyldiphenylsiloxy-3-(5-methoxy-2-furoyloxy)-2-(tetrahydro-2H-pyran-2-yloxy)butanoate methyl (3R)-4-tert-butyldiphenylsiloxy-3-(5-phenylthio-2-furoyloxy)-2-oxobutanoate

下游产品

(5R,8R,9S)-8-(tert-butyldiphenylsiloxymethyl)-9-hydroxy-9-methoxycarbonyl-1,7-dioxaspiro[4.4]non-3-ene-2,6-dione (5S,8R,9S)-8-tert-butyldiphenylsiloxymethyl-9-hydroxy-9-methoxycarbonyl-1,7-dioxaspiro[4.4]non-3-ene-2,6-dione (5R,8R,9R)-8-tert-butyldiphenylsiloxymethyl-9-hydroxy-9-methoxycarbonyl-1,7-dioxaspiro[4.4]non-3-ene-2,6-dione