百科

(2E,4E,10E)-(6S,7S,8R,9S)-7,9-Dimethoxy-3,6,8-trimethyl-11-phenyl-undeca-2,4,10-trienoic acid (2,6-dihydroxy-1-trimethylsilanyl-hexyl)-amide

(2E,4E,10E)-(6S,7S,8R,9S)-7,9-Dimethoxy-3,6,8-trimethyl-11-phenyl-undeca-2,4,10-trienoic acid (2,6-dihydroxy-1-trimethylsilanyl-hexyl)-amide

CAS号：443123-82-8

英文名：(2E,4E,10E)-(6S,7S,8R,9S)-7,9-Dimethoxy-3,6,8-trimethyl-11-phenyl-undeca-2,4,10-trienoic acid (2,6-dihydroxy-1-trimethylsilanyl-hexyl)-amide

分子式：C31H51NO5Si

分子量：545.826

合成路线

6-(t-butyldimethylsilyloxy)-1-trimethylsilylhex-1-yne

6-(t-butyldimethylsilyloxy)-1-trimethylsilylhex-1-yne

(2E,4E,10E)-(6S,7S,8R,9S)-7,9-Dimethoxy-3,6,8-trimethyl-11-phenyl-undeca-2,4,10-trienoic acid (2,6-dihydroxy-1-trimethylsilanyl-hexyl)-amide

(2E,4E,10E)-(6S,7S,8R,9S)-7,9-Dimethoxy-3,6,8-trimethyl-11-phenyl-undeca-2,4,10-trienoic acid (2,6-dihydroxy-1-trimethylsilanyl-hexyl)-amide

1,1-dibromo-6-(tert-butyldimethylsiloxy)hex-1-ene

1,1-dibromo-6-(tert-butyldimethylsiloxy)hex-1-ene

(2E,4E,10E)-(6S,7S,8R,9S)-7,9-Dimethoxy-3,6,8-trimethyl-11-phenyl-undeca-2,4,10-trienoic acid (2,6-dihydroxy-1-trimethylsilanyl-hexyl)-amide

(2E,4E,10E)-(6S,7S,8R,9S)-7,9-Dimethoxy-3,6,8-trimethyl-11-phenyl-undeca-2,4,10-trienoic acid (2,6-dihydroxy-1-trimethylsilanyl-hexyl)-amide

6-Azido-6-trimethylsilanyl-hexane-1,5-diol

6-Azido-6-trimethylsilanyl-hexane-1,5-diol

(2E,4E,10E)-(6S,7S,8R,9S)-7,9-Dimethoxy-3,6,8-trimethyl-11-phenyl-undeca-2,4,10-trienoic acid (2,6-dihydroxy-1-trimethylsilanyl-hexyl)-amide

(2E,4E,10E)-(6S,7S,8R,9S)-7,9-Dimethoxy-3,6,8-trimethyl-11-phenyl-undeca-2,4,10-trienoic acid (2,6-dihydroxy-1-trimethylsilanyl-hexyl)-amide

上游原料

1,1-dibromo-6-(tert-butyldimethylsiloxy)hex-1-ene 6-(t-butyldimethylsilyloxy)-1-trimethylsilylhex-1-yne 6-Azido-6-trimethylsilanyl-hexane-1,5-diol

下游产品

(2E,4E,10E)-(6S,7S,8R,9S)-7,9-Dimethoxy-3,6,8-trimethyl-11-phenyl-undeca-2,4,10-trienoic acid [2-(tert-butyl-dimethyl-silanyloxy)-6-hydroxy-1-trimethylsilanyl-hexyl]-amide (2E,4E,10E)-(6S,7S,8R,9S)-7,9-Dimethoxy-3,6,8-trimethyl-11-phenyl-undeca-2,4,10-trienoic acid ((Z)-6-hydroxy-hex-1-enyl)-amide [5-(tert-Butyl-dimethyl-silanyloxy)-6-((2E,4E,10E)-(6S,7S,8R,9S)-7,9-dimethoxy-3,6,8-trimethyl-11-phenyl-undeca-2,4,10-trienoylamino)-6-trimethylsilanyl-hexanoylamino]-acetic acid methyl ester