百科

(3R,4R,5S,8R,9R,10R)-8-(tert-Butyl-dimethyl-silanyloxy)-10-(4-methoxy-benzyloxy)-3,5,9,11-tetramethyl-4-triethylsilanyloxy-dodec-1-en-6-one

(3R,4R,5S,8R,9R,10R)-8-(tert-Butyl-dimethyl-silanyloxy)-10-(4-methoxy-benzyloxy)-3,5,9,11-tetramethyl-4-triethylsilanyloxy-dodec-1-en-6-one

CAS号：443283-83-8

英文名：(3R,4R,5S,8R,9R,10R)-8-(tert-Butyl-dimethyl-silanyloxy)-10-(4-methoxy-benzyloxy)-3,5,9,11-tetramethyl-4-triethylsilanyloxy-dodec-1-en-6-one

分子式：C36H66O5Si2

分子量：635.077

合成路线

[3R,4S,4'S]-4-[acyl(4'-isopropyl-2'-oxazolidone)]-2-methylhex-5-en-3-ol

[3R,4S,4'S]-4-[acyl(4'-isopropyl-2'-oxazolidone)]-2-methylhex-5-en-3-ol

(3R,4R,5S,8R,9R,10R)-8-(tert-Butyl-dimethyl-silanyloxy)-10-(4-methoxy-benzyloxy)-3,5,9,11-tetramethyl-4-triethylsilanyloxy-dodec-1-en-6-one

(3R,4R,5S,8R,9R,10R)-8-(tert-Butyl-dimethyl-silanyloxy)-10-(4-methoxy-benzyloxy)-3,5,9,11-tetramethyl-4-triethylsilanyloxy-dodec-1-en-6-one

[3R,4R]-3-hydroxymethyl-5-methylhex-1-en-4-ol

[3R,4R]-3-hydroxymethyl-5-methylhex-1-en-4-ol

(3R,4R,5S,8R,9R,10R)-8-(tert-Butyl-dimethyl-silanyloxy)-10-(4-methoxy-benzyloxy)-3,5,9,11-tetramethyl-4-triethylsilanyloxy-dodec-1-en-6-one

(3R,4R,5S,8R,9R,10R)-8-(tert-Butyl-dimethyl-silanyloxy)-10-(4-methoxy-benzyloxy)-3,5,9,11-tetramethyl-4-triethylsilanyloxy-dodec-1-en-6-one

[3S,4R]-3,5-dimethyl-4-[(4-methoxybenzyl)oxy]hex-1-ene

[3S,4R]-3,5-dimethyl-4-[(4-methoxybenzyl)oxy]hex-1-ene

(3R,4R,5S,8R,9R,10R)-8-(tert-Butyl-dimethyl-silanyloxy)-10-(4-methoxy-benzyloxy)-3,5,9,11-tetramethyl-4-triethylsilanyloxy-dodec-1-en-6-one

(3R,4R,5S,8R,9R,10R)-8-(tert-Butyl-dimethyl-silanyloxy)-10-(4-methoxy-benzyloxy)-3,5,9,11-tetramethyl-4-triethylsilanyloxy-dodec-1-en-6-one

Toluene-4-sulfonic acid (2R,3R)-3-hydroxy-4-methyl-2-vinyl-pentyl ester

Toluene-4-sulfonic acid (2R,3R)-3-hydroxy-4-methyl-2-vinyl-pentyl ester

(3R,4R,5S,8R,9R,10R)-8-(tert-Butyl-dimethyl-silanyloxy)-10-(4-methoxy-benzyloxy)-3,5,9,11-tetramethyl-4-triethylsilanyloxy-dodec-1-en-6-one

(3R,4R,5S,8R,9R,10R)-8-(tert-Butyl-dimethyl-silanyloxy)-10-(4-methoxy-benzyloxy)-3,5,9,11-tetramethyl-4-triethylsilanyloxy-dodec-1-en-6-one

上游原料

[3R,4S,4'S]-4-[acyl(4'-isopropyl-2'-oxazolidone)]-2-methylhex-5-en-3-ol [3R,4R]-3-hydroxymethyl-5-methylhex-1-en-4-ol Toluene-4-sulfonic acid (2R,3R)-3-hydroxy-4-methyl-2-vinyl-pentyl ester [3S,4R]-3,5-dimethyl-4-[(4-methoxybenzyl)oxy]hex-1-ene

下游产品

(3R,4R,5S,8R,9R,10R)-8-(tert-Butyl-dimethyl-silanyloxy)-4-hydroxy-10-(4-methoxy-benzyloxy)-3,5,9,11-tetramethyl-dodec-1-en-6-one