百科

tert-butyl-[(2S,6S)-6-((4RS)-2,2-dimethyl[1,3]dioxolan-4-ylmethyl)-3-methyllenetetrahydropyran-2-ylmethoxy]dimethylsilane

tert-butyl-[(2S,6S)-6-((4RS)-2,2-dimethyl[1,3]dioxolan-4-ylmethyl)-3-methyllenetetrahydropyran-2-ylmethoxy]dimethylsilane

CAS号：444308-87-6

英文名：tert-butyl-[(2S,6S)-6-((4RS)-2,2-dimethyl[1,3]dioxolan-4-ylmethyl)-3-methyllenetetrahydropyran-2-ylmethoxy]dimethylsilane

分子式：C19H36O4Si

分子量：356.572

合成路线

acetyl (2R,3S,6R)-2-acetoxymethyl-6-((4RS)-2,2-dimethyl-[1,3]dioxolan-4-ylmethyl)-3,6-dihydro-2H-pyran-3-yl ester

acetyl (2R,3S,6R)-2-acetoxymethyl-6-((4RS)-2,2-dimethyl-[1,3]dioxolan-4-ylmethyl)-3,6-dihydro-2H-pyran-3-yl ester

tert-butyl-[(2S,6S)-6-((4RS)-2,2-dimethyl[1,3]dioxolan-4-ylmethyl)-3-methyllenetetrahydropyran-2-ylmethoxy]dimethylsilane

tert-butyl-[(2S,6S)-6-((4RS)-2,2-dimethyl[1,3]dioxolan-4-ylmethyl)-3-methyllenetetrahydropyran-2-ylmethoxy]dimethylsilane

(2R,3S,6S)-6-((4RS)-2,2-dimethyl-[1,3]dioxolan-4-ylmethyl)-2-hydroxymethyltetrahydropyran-3-ol

(2R,3S,6S)-6-((4RS)-2,2-dimethyl-[1,3]dioxolan-4-ylmethyl)-2-hydroxymethyltetrahydropyran-3-ol

tert-butyl-[(2S,6S)-6-((4RS)-2,2-dimethyl[1,3]dioxolan-4-ylmethyl)-3-methyllenetetrahydropyran-2-ylmethoxy]dimethylsilane

tert-butyl-[(2S,6S)-6-((4RS)-2,2-dimethyl[1,3]dioxolan-4-ylmethyl)-3-methyllenetetrahydropyran-2-ylmethoxy]dimethylsilane

上游原料

acetyl (2R,3S,6R)-2-acetoxymethyl-6-((4RS)-2,2-dimethyl-[1,3]dioxolan-4-ylmethyl)-3,6-dihydro-2H-pyran-3-yl ester (2R,3S,6S)-6-((4RS)-2,2-dimethyl-[1,3]dioxolan-4-ylmethyl)-2-hydroxymethyltetrahydropyran-3-ol

下游产品

{(2R,3R,6S)-6-[(2RS)-(3E)-2-(tert-butyldimethylsilanyloxy)-pent-3-enyl]-3-methyltetrahydropyran-2-yl}acetic acid [(2R,3R,6S)-6-((4RS)-2,2-dimethyl-[1,3]dioxolan-4-ylmethyl)-3-methyltetrahydropyran-2-yl]acetyl methyl ester [(2R,3R,6S)-6-((2RS)-2,3-dihydroxypropyl)-3-methyltetrahydropyran-2-yl]acetyl methyl ester