百科

(2R,3S,6S)-6-((4RS)-2,2-dimethyl-[1,3]dioxolan-4-ylmethyl)-2-hydroxymethyltetrahydropyran-3-ol

(2R,3S,6S)-6-((4RS)-2,2-dimethyl-[1,3]dioxolan-4-ylmethyl)-2-hydroxymethyltetrahydropyran-3-ol

CAS号：444309-03-9

英文名：(2R,3S,6S)-6-((4RS)-2,2-dimethyl-[1,3]dioxolan-4-ylmethyl)-2-hydroxymethyltetrahydropyran-3-ol

分子式：C12H22O5

分子量：246.3

合成路线

acetyl (2R,3S,6R)-2-acetoxymethyl-6-((4RS)-2,2-dimethyl-[1,3]dioxolan-4-ylmethyl)-3,6-dihydro-2H-pyran-3-yl ester

acetyl (2R,3S,6R)-2-acetoxymethyl-6-((4RS)-2,2-dimethyl-[1,3]dioxolan-4-ylmethyl)-3,6-dihydro-2H-pyran-3-yl ester

(2R,3S,6S)-6-((4RS)-2,2-dimethyl-[1,3]dioxolan-4-ylmethyl)-2-hydroxymethyltetrahydropyran-3-ol

(2R,3S,6S)-6-((4RS)-2,2-dimethyl-[1,3]dioxolan-4-ylmethyl)-2-hydroxymethyltetrahydropyran-3-ol

acetic acid 3-acetoxy-6-(2,3-dihydroxy-propyl)-3,6-dihydro-2H-pyran-2-ylmethyl ester

acetic acid 3-acetoxy-6-(2,3-dihydroxy-propyl)-3,6-dihydro-2H-pyran-2-ylmethyl ester

(2R,3S,6S)-6-((4RS)-2,2-dimethyl-[1,3]dioxolan-4-ylmethyl)-2-hydroxymethyltetrahydropyran-3-ol

(2R,3S,6S)-6-((4RS)-2,2-dimethyl-[1,3]dioxolan-4-ylmethyl)-2-hydroxymethyltetrahydropyran-3-ol

上游原料

acetyl (2R,3S,6R)-2-acetoxymethyl-6-((4RS)-2,2-dimethyl-[1,3]dioxolan-4-ylmethyl)-3,6-dihydro-2H-pyran-3-yl ester acetic acid 3-acetoxy-6-(2,3-dihydroxy-propyl)-3,6-dihydro-2H-pyran-2-ylmethyl ester

下游产品

(2R,3R,6S)-6-(2,2-Dimethyl-[1,3]dioxolan-4-ylmethyl)-3-methyl-2-(2,2,2-tris-methylsulfanyl-ethyl)-tetrahydro-pyran (2S,3R,6S)-6-((4RS)-2,2-dimethyl[1,3]dioxolan-4-ylmethyl)-3-methyltetrahydropyran-2-ylmethanol {(2R,3R,6S)-6-[(2RS)-(3E)-2-(tert-butyldimethylsilanyloxy)-pent-3-enyl]-3-methyltetrahydropyran-2-yl}acetic acid [(2R,3R,6S)-6-((4RS)-2,2-dimethyl-[1,3]dioxolan-4-ylmethyl)-3-methyltetrahydropyran-2-yl]acetyl methyl ester (2R,3S)-3-(tert-butyldimethylsilanyloxy)-4-(2-{(2S,3R,6S)-6-[2-(tert-butyldimethylsilanyloxy)pent-3-enyl]-3-methyltetrahydropyran-2-yl}acetylamino)-2-methylbutyric triisopropylsilanyl ester [(2R,3R,6S)-3-methyl-6-(2-oxoethyl)tetrahydropyran-2-yl]acetyl methyl ester [(2R,3R,6S)-6-((2RS)-2,3-dihydroxypropyl)-3-methyltetrahydropyran-2-yl]acetyl methyl ester (2R,6S)-2-(tert-butyldimethylsilanyloxymethyl)-6-((4RS)-2,2-dimethyl-[1,3]dioxolan-4-ylmethyl)dihydropyran-3-one (2R,3S)-3-(tert-butyldimethylsilanyloxy)-4-(2-{(2S,3R,6S)-6-[2-(tert-butyldimethylsilanyloxy)pent-3-enyl]-3-methyltetrahydropyran-2-yl}acetylamino)-2-methylbutyric acid tert-butyl-[(2S,6S)-6-((4RS)-2,2-dimethyl[1,3]dioxolan-4-ylmethyl)-3-methyllenetetrahydropyran-2-ylmethoxy]dimethylsilane tert-butyl-[(2S,3R,6S)-6-((4RS)-2,2-dimethyl[1,3]dioxolan-4-ylmethyl)-3-methyltetrahydropyran-2-ylmethoxy]dimethylsilane