百科

(1S,2R,3R,5S)-3,5-Bis-(tert-butyl-dimethyl-silanyloxy)-2-((2Z,5Z)-octa-2,5-dienyl)-cyclopentanecarbaldehyde

(1S,2R,3R,5S)-3,5-Bis-(tert-butyl-dimethyl-silanyloxy)-2-((2Z,5Z)-octa-2,5-dienyl)-cyclopentanecarbaldehyde

CAS号：444797-16-4

英文名：(1S,2R,3R,5S)-3,5-Bis-(tert-butyl-dimethyl-silanyloxy)-2-((2Z,5Z)-octa-2,5-dienyl)-cyclopentanecarbaldehyde

分子式：C26H50O3Si2

分子量：466.844

合成路线

(4aR,5R,7S,7aR)-5,7-Bis-(tert-butyl-dimethyl-silanyloxy)-hexahydro-cyclopenta[c]pyran-3-one

(4aR,5R,7S,7aR)-5,7-Bis-(tert-butyl-dimethyl-silanyloxy)-hexahydro-cyclopenta[c]pyran-3-one

(1S,2R,3R,5S)-3,5-Bis-(tert-butyl-dimethyl-silanyloxy)-2-((2Z,5Z)-octa-2,5-dienyl)-cyclopentanecarbaldehyde

(1S,2R,3R,5S)-3,5-Bis-(tert-butyl-dimethyl-silanyloxy)-2-((2Z,5Z)-octa-2,5-dienyl)-cyclopentanecarbaldehyde

4-iodo-1-ethylbut-1-yne

4-iodo-1-ethylbut-1-yne

(1S,2R,3R,5S)-3,5-Bis-(tert-butyl-dimethyl-silanyloxy)-2-((2Z,5Z)-octa-2,5-dienyl)-cyclopentanecarbaldehyde

(1S,2R,3R,5S)-3,5-Bis-(tert-butyl-dimethyl-silanyloxy)-2-((2Z,5Z)-octa-2,5-dienyl)-cyclopentanecarbaldehyde

上游原料

(4aR,5R,7S,7aR)-5,7-Bis-(tert-butyl-dimethyl-silanyloxy)-hexahydro-cyclopenta[c]pyran-3-one 4-iodo-1-ethylbut-1-yne

下游产品

(4Z,8E)-(S)-9-[(1S,2R,3R,5S)-3,5-Bis-(tert-butyl-dimethyl-silanyloxy)-2-((2Z,5Z)-octa-2,5-dienyl)-cyclopentyl]-7-hydroxy-nona-4,8-dienoic acid methyl ester