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(6Z,9S)-1-(benzyloxy)-9-(tert-butyldimethylsilyloxy)-9-[(4R)-2,2-dimethyl-1,3-dioxolan-4-yl]non-6-en-2-yn-4-ol

(6Z,9S)-1-(benzyloxy)-9-(tert-butyldimethylsilyloxy)-9-[(4R)-2,2-dimethyl-1,3-dioxolan-4-yl]non-6-en-2-yn-4-ol

CAS号：444885-16-9

英文名：(6Z,9S)-1-(benzyloxy)-9-(tert-butyldimethylsilyloxy)-9-[(4R)-2,2-dimethyl-1,3-dioxolan-4-yl]non-6-en-2-yn-4-ol

分子式：C27H42O5Si

分子量：474.705

合成路线

tert-butyl{(1S)-1-[(4R)-2,2-dimethyl-1,3-dioxolan-4-yl]hept-6-en-3-ynyloxy}dimethylsilane

tert-butyl{(1S)-1-[(4R)-2,2-dimethyl-1,3-dioxolan-4-yl]hept-6-en-3-ynyloxy}dimethylsilane

(6Z,9S)-1-(benzyloxy)-9-(tert-butyldimethylsilyloxy)-9-[(4R)-2,2-dimethyl-1,3-dioxolan-4-yl]non-6-en-2-yn-4-ol

(6Z,9S)-1-(benzyloxy)-9-(tert-butyldimethylsilyloxy)-9-[(4R)-2,2-dimethyl-1,3-dioxolan-4-yl]non-6-en-2-yn-4-ol

1,2,3-trideoxy-4-O-(tert-butyldimethylsilyl)-5,6-O-isopropylidene-D-erythro-hex-1-ynitol

1,2,3-trideoxy-4-O-(tert-butyldimethylsilyl)-5,6-O-isopropylidene-D-erythro-hex-1-ynitol

(6Z,9S)-1-(benzyloxy)-9-(tert-butyldimethylsilyloxy)-9-[(4R)-2,2-dimethyl-1,3-dioxolan-4-yl]non-6-en-2-yn-4-ol

(6Z,9S)-1-(benzyloxy)-9-(tert-butyldimethylsilyloxy)-9-[(4R)-2,2-dimethyl-1,3-dioxolan-4-yl]non-6-en-2-yn-4-ol

上游原料

tert-butyl{(1S)-1-[(4R)-2,2-dimethyl-1,3-dioxolan-4-yl]hept-6-en-3-ynyloxy}dimethylsilane 1,2,3-trideoxy-4-O-(tert-butyldimethylsilyl)-5,6-O-isopropylidene-D-erythro-hex-1-ynitol

下游产品

(2R,3S,5Z)-11-(benzyloxy)-3-(tert-butyldimethylsilyloxy)undec-5-en-9-yne-1,2,8-triol