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(5Z,8S)-8-(tert-butyldimethylsilyloxy)-8-[(4R)-2,2-dimethyl-1,3-dioxolan-4-yl]-1-(trimethylsilyl)oct-5-en-1-yn-3-ol

(5Z,8S)-8-(tert-butyldimethylsilyloxy)-8-[(4R)-2,2-dimethyl-1,3-dioxolan-4-yl]-1-(trimethylsilyl)oct-5-en-1-yn-3-ol

CAS号：444885-25-0

英文名：(5Z,8S)-8-(tert-butyldimethylsilyloxy)-8-[(4R)-2,2-dimethyl-1,3-dioxolan-4-yl]-1-(trimethylsilyl)oct-5-en-1-yn-3-ol

分子式：C22H42O4Si2

分子量：426.737

合成路线

tert-butyl{(1S)-1-[(4R)-2,2-dimethyl-1,3-dioxolan-4-yl]hept-6-en-3-ynyloxy}dimethylsilane

tert-butyl{(1S)-1-[(4R)-2,2-dimethyl-1,3-dioxolan-4-yl]hept-6-en-3-ynyloxy}dimethylsilane

(5Z,8S)-8-(tert-butyldimethylsilyloxy)-8-[(4R)-2,2-dimethyl-1,3-dioxolan-4-yl]-1-(trimethylsilyl)oct-5-en-1-yn-3-ol

(5Z,8S)-8-(tert-butyldimethylsilyloxy)-8-[(4R)-2,2-dimethyl-1,3-dioxolan-4-yl]-1-(trimethylsilyl)oct-5-en-1-yn-3-ol

1,2,3-trideoxy-4-O-(tert-butyldimethylsilyl)-5,6-O-isopropylidene-D-erythro-hex-1-ynitol

1,2,3-trideoxy-4-O-(tert-butyldimethylsilyl)-5,6-O-isopropylidene-D-erythro-hex-1-ynitol

(5Z,8S)-8-(tert-butyldimethylsilyloxy)-8-[(4R)-2,2-dimethyl-1,3-dioxolan-4-yl]-1-(trimethylsilyl)oct-5-en-1-yn-3-ol

(5Z,8S)-8-(tert-butyldimethylsilyloxy)-8-[(4R)-2,2-dimethyl-1,3-dioxolan-4-yl]-1-(trimethylsilyl)oct-5-en-1-yn-3-ol

1-[2',2'-dimethyl-(4'R)-1',3'-dioxolan-4'-yl]-(1S)-3-butyn-1-ol

1-[2',2'-dimethyl-(4'R)-1',3'-dioxolan-4'-yl]-(1S)-3-butyn-1-ol

(5Z,8S)-8-(tert-butyldimethylsilyloxy)-8-[(4R)-2,2-dimethyl-1,3-dioxolan-4-yl]-1-(trimethylsilyl)oct-5-en-1-yn-3-ol

(5Z,8S)-8-(tert-butyldimethylsilyloxy)-8-[(4R)-2,2-dimethyl-1,3-dioxolan-4-yl]-1-(trimethylsilyl)oct-5-en-1-yn-3-ol

(2RS,7S)-7-(tert-butyldimethyl-silanyloxy)-7-[(4R)-2,2-dimethyl-1,3-dioxalan-4-yl]-4-heptene-1,2-diol

(2RS,7S)-7-(tert-butyldimethyl-silanyloxy)-7-[(4R)-2,2-dimethyl-1,3-dioxalan-4-yl]-4-heptene-1,2-diol

(5Z,8S)-8-(tert-butyldimethylsilyloxy)-8-[(4R)-2,2-dimethyl-1,3-dioxolan-4-yl]-1-(trimethylsilyl)oct-5-en-1-yn-3-ol

(5Z,8S)-8-(tert-butyldimethylsilyloxy)-8-[(4R)-2,2-dimethyl-1,3-dioxolan-4-yl]-1-(trimethylsilyl)oct-5-en-1-yn-3-ol

上游原料

(2RS,7S)-7-(tert-butyldimethyl-silanyloxy)-7-[(4R)-2,2-dimethyl-1,3-dioxalan-4-yl]-4-heptene-1,2-diol tert-butyl{(1S)-1-[(4R)-2,2-dimethyl-1,3-dioxolan-4-yl]hept-6-en-3-ynyloxy}dimethylsilane 1,2,3-trideoxy-4-O-(tert-butyldimethylsilyl)-5,6-O-isopropylidene-D-erythro-hex-1-ynitol 1-[2',2'-dimethyl-(4'R)-1',3'-dioxolan-4'-yl]-(1S)-3-butyn-1-ol

下游产品

(1S,3Z)-1-[(4R)-2,2-dimethyl-1,3-dioxolan-4-yl]oct-3-en-7-yne-1,6-diol