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(E)-(7S,8R,9R)-9-Benzyloxy-7,8-bis-(tert-butyl-dimethyl-silanyloxy)-dodec-5-enoic acid methyl ester

(E)-(7S,8R,9R)-9-Benzyloxy-7,8-bis-(tert-butyl-dimethyl-silanyloxy)-dodec-5-enoic acid methyl ester

CAS号：444987-76-2

英文名：(E)-(7S,8R,9R)-9-Benzyloxy-7,8-bis-(tert-butyl-dimethyl-silanyloxy)-dodec-5-enoic acid methyl ester

分子式：C32H58O5Si2

分子量：578.971

合成路线

(E)-6-iodo-5-hexen-1-ol

(E)-6-iodo-5-hexen-1-ol

(E)-(7S,8R,9R)-9-Benzyloxy-7,8-bis-(tert-butyl-dimethyl-silanyloxy)-dodec-5-enoic acid methyl ester

(E)-(7S,8R,9R)-9-Benzyloxy-7,8-bis-(tert-butyl-dimethyl-silanyloxy)-dodec-5-enoic acid methyl ester

(2S,3R)-hexane-1,2,3-triol

(2S,3R)-hexane-1,2,3-triol

(E)-(7S,8R,9R)-9-Benzyloxy-7,8-bis-(tert-butyl-dimethyl-silanyloxy)-dodec-5-enoic acid methyl ester

(E)-(7S,8R,9R)-9-Benzyloxy-7,8-bis-(tert-butyl-dimethyl-silanyloxy)-dodec-5-enoic acid methyl ester

((4S,5R)-2,2-Dimethyl-5-propyl-[1,3]dioxolan-4-yl)-methanol

((4S,5R)-2,2-Dimethyl-5-propyl-[1,3]dioxolan-4-yl)-methanol

(E)-(7S,8R,9R)-9-Benzyloxy-7,8-bis-(tert-butyl-dimethyl-silanyloxy)-dodec-5-enoic acid methyl ester

(E)-(7S,8R,9R)-9-Benzyloxy-7,8-bis-(tert-butyl-dimethyl-silanyloxy)-dodec-5-enoic acid methyl ester

(R)-1-((S)-2,2-Diethyl-[1,3]dioxolan-4-yl)-butan-1-ol

(R)-1-((S)-2,2-Diethyl-[1,3]dioxolan-4-yl)-butan-1-ol

(E)-(7S,8R,9R)-9-Benzyloxy-7,8-bis-(tert-butyl-dimethyl-silanyloxy)-dodec-5-enoic acid methyl ester

(E)-(7S,8R,9R)-9-Benzyloxy-7,8-bis-(tert-butyl-dimethyl-silanyloxy)-dodec-5-enoic acid methyl ester

(2S,3R)-3-benzyloxy-hexane-1,2-diol

(2S,3R)-3-benzyloxy-hexane-1,2-diol

(E)-(7S,8R,9R)-9-Benzyloxy-7,8-bis-(tert-butyl-dimethyl-silanyloxy)-dodec-5-enoic acid methyl ester

(E)-(7S,8R,9R)-9-Benzyloxy-7,8-bis-(tert-butyl-dimethyl-silanyloxy)-dodec-5-enoic acid methyl ester

(2S,3R)-3-Benzyloxy-2-(tert-butyl-dimethyl-silanyloxy)-hexan-1-ol

(2S,3R)-3-Benzyloxy-2-(tert-butyl-dimethyl-silanyloxy)-hexan-1-ol

(E)-(7S,8R,9R)-9-Benzyloxy-7,8-bis-(tert-butyl-dimethyl-silanyloxy)-dodec-5-enoic acid methyl ester

(E)-(7S,8R,9R)-9-Benzyloxy-7,8-bis-(tert-butyl-dimethyl-silanyloxy)-dodec-5-enoic acid methyl ester

{(R)-1-[(S)-1,2-Bis-(tert-butyl-dimethyl-silanyloxy)-ethyl]-butoxymethyl}-benzene

{(R)-1-[(S)-1,2-Bis-(tert-butyl-dimethyl-silanyloxy)-ethyl]-butoxymethyl}-benzene

(E)-(7S,8R,9R)-9-Benzyloxy-7,8-bis-(tert-butyl-dimethyl-silanyloxy)-dodec-5-enoic acid methyl ester

(E)-(7S,8R,9R)-9-Benzyloxy-7,8-bis-(tert-butyl-dimethyl-silanyloxy)-dodec-5-enoic acid methyl ester

上游原料

((4S,5R)-2,2-Dimethyl-5-propyl-[1,3]dioxolan-4-yl)-methanol (2S,3R)-3-benzyloxy-hexane-1,2-diol (R)-1-((S)-2,2-Diethyl-[1,3]dioxolan-4-yl)-butan-1-ol (E)-6-iodo-5-hexen-1-ol (2S,3R)-hexane-1,2,3-triol (2S,3R)-3-Benzyloxy-2-(tert-butyl-dimethyl-silanyloxy)-hexan-1-ol {(R)-1-[(S)-1,2-Bis-(tert-butyl-dimethyl-silanyloxy)-ethyl]-butoxymethyl}-benzene

下游产品

(E)-(7S,8R,9R)-7,8-Bis-(tert-butyl-dimethyl-silanyloxy)-9-hydroxy-dodec-5-enoic acid methyl ester (E)-(7S,8R,9R)-7,8-Bis-(tert-butyl-dimethyl-silanyloxy)-9-hydroxy-dodec-5-enoic acid herbarumin I (E)-(8S,9R,10R)-8,9-Bis-(tert-butyl-dimethyl-silanyloxy)-10-propyl-3,4,5,8,9,10-hexahydro-oxecin-2-one