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(1E,6E)-(3S,4S,8S,12S)-13-[(2R,6R)-6-(2-Hydroxy-ethyl)-3,6-dihydro-2H-pyran-2-yl]-3,8-bis-methoxymethoxy-12-methyl-1-((S)-4-methyl-3,6-dihydro-2H-pyran-2-yl)-10-methylene-trideca-1,6-dien-4-ol
CAS号:445306-67-2
英文名:(1E,6E)-(3S,4S,8S,12S)-13-[(2R,6R)-6-(2-Hydroxy-ethyl)-3,6-dihydro-2H-pyran-2-yl]-3,8-bis-methoxymethoxy-12-methyl-1-((S)-4-methyl-3,6-dihydro-2H-pyran-2-yl)-10-methylene-trideca-1,6-dien-4-ol
分子式:C32H52O8
分子量:564.75
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合成路线
259198-97-5
(3R)-4-(4-methoxybenzyloxy)-3-methylbutyraldehyde
445306-67-2
(1E,6E)-(3S,4S,8S,12S)-13-[(2R,6R)-6-(2-Hydroxy-ethyl)-3,6-dihydro-2H-pyran-2-yl]-3,8-bis-methoxymethoxy-12-methyl-1-((S)-4-methyl-3,6-dihydro-2H-pyran-2-yl)-10-methylene-trideca-1,6-dien-4-ol
259198-96-4
(3R)-4-(4-methoxybenzyloxy)-3-methylbutyrnitrile
445306-67-2
(1E,6E)-(3S,4S,8S,12S)-13-[(2R,6R)-6-(2-Hydroxy-ethyl)-3,6-dihydro-2H-pyran-2-yl]-3,8-bis-methoxymethoxy-12-methyl-1-((S)-4-methyl-3,6-dihydro-2H-pyran-2-yl)-10-methylene-trideca-1,6-dien-4-ol
259198-98-6
(4S,6R)-1-(p-methoxybenzyloxy)-2-methyl-6-hepten-4-ol
445306-67-2
(1E,6E)-(3S,4S,8S,12S)-13-[(2R,6R)-6-(2-Hydroxy-ethyl)-3,6-dihydro-2H-pyran-2-yl]-3,8-bis-methoxymethoxy-12-methyl-1-((S)-4-methyl-3,6-dihydro-2H-pyran-2-yl)-10-methylene-trideca-1,6-dien-4-ol
259198-99-7
(4S,6R)-4-(1-ethoxyallyloxy)-7-(p-methoxybenzyloxy)-6-methylhept-1-ene
445306-67-2
(1E,6E)-(3S,4S,8S,12S)-13-[(2R,6R)-6-(2-Hydroxy-ethyl)-3,6-dihydro-2H-pyran-2-yl]-3,8-bis-methoxymethoxy-12-methyl-1-((S)-4-methyl-3,6-dihydro-2H-pyran-2-yl)-10-methylene-trideca-1,6-dien-4-ol
302554-87-6
(S)-2-allyloxy-4-methyl-1-trityloxy-4-pentene
445306-67-2
(1E,6E)-(3S,4S,8S,12S)-13-[(2R,6R)-6-(2-Hydroxy-ethyl)-3,6-dihydro-2H-pyran-2-yl]-3,8-bis-methoxymethoxy-12-methyl-1-((S)-4-methyl-3,6-dihydro-2H-pyran-2-yl)-10-methylene-trideca-1,6-dien-4-ol
387392-14-5
(1S)-1-{(4R,5R)-5-[(1S)-1-hydroxy-3-methyl-3-butenyl]-2,2-dimethyl-1,3-dioxolan-4-yl}-3-methyl-3-buten-1-ol
445306-67-2
(1E,6E)-(3S,4S,8S,12S)-13-[(2R,6R)-6-(2-Hydroxy-ethyl)-3,6-dihydro-2H-pyran-2-yl]-3,8-bis-methoxymethoxy-12-methyl-1-((S)-4-methyl-3,6-dihydro-2H-pyran-2-yl)-10-methylene-trideca-1,6-dien-4-ol
66335-71-5
(S)-4-methyl-1-trityloxymethyl-3,6-dihydro-2H-pyran
445306-67-2
(1E,6E)-(3S,4S,8S,12S)-13-[(2R,6R)-6-(2-Hydroxy-ethyl)-3,6-dihydro-2H-pyran-2-yl]-3,8-bis-methoxymethoxy-12-methyl-1-((S)-4-methyl-3,6-dihydro-2H-pyran-2-yl)-10-methylene-trideca-1,6-dien-4-ol
218898-32-9
(S)-3,6-dihydro-4-methyl-2H-pyran-2-carbaldehyde
445306-67-2
(1E,6E)-(3S,4S,8S,12S)-13-[(2R,6R)-6-(2-Hydroxy-ethyl)-3,6-dihydro-2H-pyran-2-yl]-3,8-bis-methoxymethoxy-12-methyl-1-((S)-4-methyl-3,6-dihydro-2H-pyran-2-yl)-10-methylene-trideca-1,6-dien-4-ol
302554-94-5
(2S)-2-(4-methoxybenzyloxy)-4-methyl-3,6-dihydro-2H-pyran
445306-67-2
(1E,6E)-(3S,4S,8S,12S)-13-[(2R,6R)-6-(2-Hydroxy-ethyl)-3,6-dihydro-2H-pyran-2-yl]-3,8-bis-methoxymethoxy-12-methyl-1-((S)-4-methyl-3,6-dihydro-2H-pyran-2-yl)-10-methylene-trideca-1,6-dien-4-ol
385809-18-7
(2S)-2-(4R,5R)-2,2-dimethyl-5-[(2S)-4-methyl-3,6-dihydro-2H-pyran-2-yl]-1,3-dioxolan-4-yl-4-methyl-3,6-dihydro-2H-pyran
445306-67-2
(1E,6E)-(3S,4S,8S,12S)-13-[(2R,6R)-6-(2-Hydroxy-ethyl)-3,6-dihydro-2H-pyran-2-yl]-3,8-bis-methoxymethoxy-12-methyl-1-((S)-4-methyl-3,6-dihydro-2H-pyran-2-yl)-10-methylene-trideca-1,6-dien-4-ol
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上游原料
(4S,6R)-4-(1-ethoxyallyloxy)-7-(p-methoxybenzyloxy)-6-methylhept-1-ene
(2S)-2-(4R,5R)-2,2-dimethyl-5-[(2S)-4-methyl-3,6-dihydro-2H-pyran-2-yl]-1,3-dioxolan-4-yl-4-methyl-3,6-dihydro-2H-pyran
(S)-3,6-dihydro-4-methyl-2H-pyran-2-carbaldehyde
(3R)-4-(4-methoxybenzyloxy)-3-methylbutyraldehyde
(4S,5S)-4,5-bis-1-[(S)-allyloxy-3-methylbut-3-enyl]-2,2-dimethyl-[1,3]-dioxolane
(4S,6R)-1-(p-methoxybenzyloxy)-2-methyl-6-hepten-4-ol
(1S)-1-{(4R,5R)-5-[(1S)-1-hydroxy-3-methyl-3-butenyl]-2,2-dimethyl-1,3-dioxolan-4-yl}-3-methyl-3-buten-1-ol
(3R)-4-(4-methoxybenzyloxy)-3-methylbutyrnitrile
(S)-4-methyl-1-trityloxymethyl-3,6-dihydro-2H-pyran
(1S,2S)-1,2-bis-[4-methyl-3,6-dihydro-2H-pyran-(2S)-yl]-ethane-1,2-diol
(2S)-2-(4-methoxybenzyloxy)-4-methyl-3,6-dihydro-2H-pyran
(S)-2-allyloxy-4-methyl-1-trityloxy-4-pentene
(6S)-6-(4-methoxybenzyloxy)-4-methyl-5,6-dihydro-2H-pyran-2-one
下游产品
(3E,9E)-(1R,7S,11S,15S,17R)-11-Methoxymethoxy-7-[(E)-(S)-1-methoxymethoxy-3-((S)-4-methyl-3,6-dihydro-2H-pyran-2-yl)-allyl]-15-methyl-13-methylene-6,21-dioxa-bicyclo[15.3.1]henicosa-3,9,19-trien-5-one
C.2-C.3-(E) des-epoxy-laulimalide
(Z)-4-{(2R,6R)-6-[(7E,12E)-(2S,6S,10S,11S)-6,11-Bis-methoxymethoxy-2-methyl-13-((S)-4-methyl-3,6-dihydro-2H-pyran-2-yl)-4-methylene-10-triethylsilanyloxy-trideca-7,12-dienyl]-5,6-dihydro-2H-pyran-2-yl}-but-2-enoic acid 2-trimethylsilanyl-ethyl ester