百科

(3R,5R,9S)-3,9-Bis-(tert-butyl-dimethyl-silanyloxy)-10-{(4R,6S)-2,2-dimethyl-6-[(2R,4R)-2,4,5-tris-(tert-butyl-dimethyl-silanyloxy)-pentyl]-[1,3]dioxan-4-yl}-1-trimethylsilanyl-deca-1,7-diyn-5-ol

CAS号：446252-52-4

英文名：(3R,5R,9S)-3,9-Bis-(tert-butyl-dimethyl-silanyloxy)-10-{(4R,6S)-2,2-dimethyl-6-[(2R,4R)-2,4,5-tris-(tert-butyl-dimethyl-silanyloxy)-pentyl]-[1,3]dioxan-4-yl}-1-trimethylsilanyl-deca-1,7-diyn-5-ol

分子式：C54H112O8Si6

分子量：1057.98

合成路线

260393-73-5

(R)-3-(tert butyldimethylsilyloxy)-1-trimethylsilyl-hex-5-en-1-yne

446252-52-4

(3R,5R,9S)-3,9-Bis-(tert-butyl-dimethyl-silanyloxy)-10-{(4R,6S)-2,2-dimethyl-6-[(2R,4R)-2,4,5-tris-(tert-butyl-dimethyl-silanyloxy)-pentyl]-[1,3]dioxan-4-yl}-1-trimethylsilanyl-deca-1,7-diyn-5-ol

446252-41-1

(R)-1-(trimethylsilyl)hex-5-en-1-yn-3-yl acetate

446252-52-4

(3R,5R,9S)-3,9-Bis-(tert-butyl-dimethyl-silanyloxy)-10-{(4R,6S)-2,2-dimethyl-6-[(2R,4R)-2,4,5-tris-(tert-butyl-dimethyl-silanyloxy)-pentyl]-[1,3]dioxan-4-yl}-1-trimethylsilanyl-deca-1,7-diyn-5-ol

260393-72-4

(R)-1-(trimethylsilyl)hex-5-en-1-yn-3-ol

446252-52-4

(3R,5R,9S)-3,9-Bis-(tert-butyl-dimethyl-silanyloxy)-10-{(4R,6S)-2,2-dimethyl-6-[(2R,4R)-2,4,5-tris-(tert-butyl-dimethyl-silanyloxy)-pentyl]-[1,3]dioxan-4-yl}-1-trimethylsilanyl-deca-1,7-diyn-5-ol

94012-68-7

(+/-)-1-(trimethylsilyl)hex-5-en-1-yn-3-ol

446252-52-4

(3R,5R,9S)-3,9-Bis-(tert-butyl-dimethyl-silanyloxy)-10-{(4R,6S)-2,2-dimethyl-6-[(2R,4R)-2,4,5-tris-(tert-butyl-dimethyl-silanyloxy)-pentyl]-[1,3]dioxan-4-yl}-1-trimethylsilanyl-deca-1,7-diyn-5-ol

上游原料

(+/-)-1-(trimethylsilyl)hex-5-en-1-yn-3-ol (R)-3-(tert butyldimethylsilyloxy)-1-trimethylsilyl-hex-5-en-1-yne (R)-1-(trimethylsilyl)hex-5-en-1-yn-3-ol (R)-1-(trimethylsilyl)hex-5-en-1-yn-3-yl acetate

下游产品

(2R,4S,6R,8R)-2,8-Bis-(tert-butyl-dimethyl-silanyloxy)-1-{(4R,6S)-2,2-dimethyl-6-[(2R,4R)-2,4,5-tris-(tert-butyl-dimethyl-silanyloxy)-pentyl]-[1,3]dioxan-4-yl}-10-trimethylsilanyl-dec-9-yne-4,6-diol