百科

(S)-2-[(R)-2-(tert-Butyl-dimethyl-silanyloxy)-4-trimethylsilanyl-but-3-ynyl]-oxirane

(S)-2-[(R)-2-(tert-Butyl-dimethyl-silanyloxy)-4-trimethylsilanyl-but-3-ynyl]-oxirane

CAS号：446252-57-9

英文名：(S)-2-[(R)-2-(tert-Butyl-dimethyl-silanyloxy)-4-trimethylsilanyl-but-3-ynyl]-oxirane

分子式：C15H30O2Si2

分子量：298.569

合成路线

(R)-3-(tert butyldimethylsilyloxy)-1-trimethylsilyl-hex-5-en-1-yne

(R)-3-(tert butyldimethylsilyloxy)-1-trimethylsilyl-hex-5-en-1-yne

(S)-2-[(R)-2-(tert-Butyl-dimethyl-silanyloxy)-4-trimethylsilanyl-but-3-ynyl]-oxirane

(S)-2-[(R)-2-(tert-Butyl-dimethyl-silanyloxy)-4-trimethylsilanyl-but-3-ynyl]-oxirane

(R)-1-(trimethylsilyl)hex-5-en-1-yn-3-yl acetate

(R)-1-(trimethylsilyl)hex-5-en-1-yn-3-yl acetate

(S)-2-[(R)-2-(tert-Butyl-dimethyl-silanyloxy)-4-trimethylsilanyl-but-3-ynyl]-oxirane

(S)-2-[(R)-2-(tert-Butyl-dimethyl-silanyloxy)-4-trimethylsilanyl-but-3-ynyl]-oxirane

(R)-1-(trimethylsilyl)hex-5-en-1-yn-3-ol

(R)-1-(trimethylsilyl)hex-5-en-1-yn-3-ol

(S)-2-[(R)-2-(tert-Butyl-dimethyl-silanyloxy)-4-trimethylsilanyl-but-3-ynyl]-oxirane

(S)-2-[(R)-2-(tert-Butyl-dimethyl-silanyloxy)-4-trimethylsilanyl-but-3-ynyl]-oxirane

(+/-)-1-(trimethylsilyl)hex-5-en-1-yn-3-ol

(+/-)-1-(trimethylsilyl)hex-5-en-1-yn-3-ol

(S)-2-[(R)-2-(tert-Butyl-dimethyl-silanyloxy)-4-trimethylsilanyl-but-3-ynyl]-oxirane

(S)-2-[(R)-2-(tert-Butyl-dimethyl-silanyloxy)-4-trimethylsilanyl-but-3-ynyl]-oxirane

上游原料

(+/-)-1-(trimethylsilyl)hex-5-en-1-yn-3-ol (R)-3-(tert butyldimethylsilyloxy)-1-trimethylsilyl-hex-5-en-1-yne (R)-1-(trimethylsilyl)hex-5-en-1-yn-3-ol (R)-1-(trimethylsilyl)hex-5-en-1-yn-3-yl acetate

下游产品

(2R,4S,6R,8R)-2,8-Bis-(tert-butyl-dimethyl-silanyloxy)-1-{(4R,6S)-2,2-dimethyl-6-[(2R,4R)-2,4,5-tris-(tert-butyl-dimethyl-silanyloxy)-pentyl]-[1,3]dioxan-4-yl}-10-trimethylsilanyl-dec-9-yne-4,6-diol carbonic acid tert-butyl ester 5-(tert-butyl-dimethyl-silanyloxy)-1-[2-(tert-butyl-dimethyl-silanyloxy)-4-trimethylsilanyl-but-3-ynyl]-6-{2,2-dimethyl-6-[2,4,5-tris-(tert-butyl-dimethyl-silanyloxy)-pentyl]-[1,3]dioxan-4-yl}-hex-3-ynyl ester