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(3R,5S,9R,11R)-3,9,11,12-Tetrakis-(tert-butyl-dimethyl-silanyloxy)-1-trimethylsilanyl-dodeca-1,7-diyn-5-ol

(3R,5S,9R,11R)-3,9,11,12-Tetrakis-(tert-butyl-dimethyl-silanyloxy)-1-trimethylsilanyl-dodeca-1,7-diyn-5-ol

CAS号：446252-66-0

英文名：(3R,5S,9R,11R)-3,9,11,12-Tetrakis-(tert-butyl-dimethyl-silanyloxy)-1-trimethylsilanyl-dodeca-1,7-diyn-5-ol

分子式：C39H82O5Si5

分子量：771.493

合成路线

(R)-3-(tert butyldimethylsilyloxy)-1-trimethylsilyl-hex-5-en-1-yne

(R)-3-(tert butyldimethylsilyloxy)-1-trimethylsilyl-hex-5-en-1-yne

(3R,5S,9R,11R)-3,9,11,12-Tetrakis-(tert-butyl-dimethyl-silanyloxy)-1-trimethylsilanyl-dodeca-1,7-diyn-5-ol

(3R,5S,9R,11R)-3,9,11,12-Tetrakis-(tert-butyl-dimethyl-silanyloxy)-1-trimethylsilanyl-dodeca-1,7-diyn-5-ol

2-[(R)-2-(tert-Butyl-dimethyl-silanyloxy)-4-trimethylsilanyl-but-3-ynyl]-oxirane

2-[(R)-2-(tert-Butyl-dimethyl-silanyloxy)-4-trimethylsilanyl-but-3-ynyl]-oxirane

(3R,5S,9R,11R)-3,9,11,12-Tetrakis-(tert-butyl-dimethyl-silanyloxy)-1-trimethylsilanyl-dodeca-1,7-diyn-5-ol

(3R,5S,9R,11R)-3,9,11,12-Tetrakis-(tert-butyl-dimethyl-silanyloxy)-1-trimethylsilanyl-dodeca-1,7-diyn-5-ol

(+/-)-1-(trimethylsilyl)hex-5-en-1-yn-3-ol

(+/-)-1-(trimethylsilyl)hex-5-en-1-yn-3-ol

(3R,5S,9R,11R)-3,9,11,12-Tetrakis-(tert-butyl-dimethyl-silanyloxy)-1-trimethylsilanyl-dodeca-1,7-diyn-5-ol

(3R,5S,9R,11R)-3,9,11,12-Tetrakis-(tert-butyl-dimethyl-silanyloxy)-1-trimethylsilanyl-dodeca-1,7-diyn-5-ol

(R)-1-(trimethylsilyl)hex-5-en-1-yn-3-ol

(R)-1-(trimethylsilyl)hex-5-en-1-yn-3-ol

(3R,5S,9R,11R)-3,9,11,12-Tetrakis-(tert-butyl-dimethyl-silanyloxy)-1-trimethylsilanyl-dodeca-1,7-diyn-5-ol

(3R,5S,9R,11R)-3,9,11,12-Tetrakis-(tert-butyl-dimethyl-silanyloxy)-1-trimethylsilanyl-dodeca-1,7-diyn-5-ol

(R)-1-(trimethylsilyl)hex-5-en-1-yn-3-yl acetate

(R)-1-(trimethylsilyl)hex-5-en-1-yn-3-yl acetate

(3R,5S,9R,11R)-3,9,11,12-Tetrakis-(tert-butyl-dimethyl-silanyloxy)-1-trimethylsilanyl-dodeca-1,7-diyn-5-ol

(3R,5S,9R,11R)-3,9,11,12-Tetrakis-(tert-butyl-dimethyl-silanyloxy)-1-trimethylsilanyl-dodeca-1,7-diyn-5-ol

上游原料

(+/-)-1-(trimethylsilyl)hex-5-en-1-yn-3-ol (R)-3-(tert butyldimethylsilyloxy)-1-trimethylsilyl-hex-5-en-1-yne 2-[(R)-2-(tert-Butyl-dimethyl-silanyloxy)-4-trimethylsilanyl-but-3-ynyl]-oxirane (R)-1-(trimethylsilyl)hex-5-en-1-yn-3-ol (R)-1-(trimethylsilyl)hex-5-en-1-yn-3-yl acetate

下游产品

(2R,4R,8R,10R)-1,2,4,10-Tetrakis-(tert-butyl-dimethyl-silanyloxy)-8-hydroxy-12-trimethylsilanyl-dodec-11-yn-6-one