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3,4,5-tri-O-benzyl-2,6-dideoxy-2,6-methylene-D-glycero-D-gulo-3,6a-cycloheptonic acid

3,4,5-tri-O-benzyl-2,6-dideoxy-2,6-methylene-D-glycero-D-gulo-3,6a-cycloheptonic acid

CAS号：452081-52-6

英文名：3,4,5-tri-O-benzyl-2,6-dideoxy-2,6-methylene-D-glycero-D-gulo-3,6a-cycloheptonic acid

分子式：C29H30O6

分子量：474.545

合成路线

ethyl 3,4,5-tri-O-benzyl-7-O-[(tert-butyl)diphenylsilyl]-2,6-dideoxy-2,6-methylene-D-glycero-D-gulo-3,6a-cycloheptonate

ethyl 3,4,5-tri-O-benzyl-7-O-[(tert-butyl)diphenylsilyl]-2,6-dideoxy-2,6-methylene-D-glycero-D-gulo-3,6a-cycloheptonate

3,4,5-tri-O-benzyl-2,6-dideoxy-2,6-methylene-D-glycero-D-gulo-3,6a-cycloheptonic acid

3,4,5-tri-O-benzyl-2,6-dideoxy-2,6-methylene-D-glycero-D-gulo-3,6a-cycloheptonic acid

(3aR)-4c,5t,6c-tris-benzyloxy-1-methyl-(3ar,6ac)-hexahydro-cyclopenta[c]isoxazole

(3aR)-4c,5t,6c-tris-benzyloxy-1-methyl-(3ar,6ac)-hexahydro-cyclopenta[c]isoxazole

3,4,5-tri-O-benzyl-2,6-dideoxy-2,6-methylene-D-glycero-D-gulo-3,6a-cycloheptonic acid

3,4,5-tri-O-benzyl-2,6-dideoxy-2,6-methylene-D-glycero-D-gulo-3,6a-cycloheptonic acid

1L-(1,2,4/3,5)-3,4,5-tri-O-benzyl-2-(dimethylamino)-1-(hydroxymethyl)cyclopentane-3,4,5-triol

1L-(1,2,4/3,5)-3,4,5-tri-O-benzyl-2-(dimethylamino)-1-(hydroxymethyl)cyclopentane-3,4,5-triol

3,4,5-tri-O-benzyl-2,6-dideoxy-2,6-methylene-D-glycero-D-gulo-3,6a-cycloheptonic acid

3,4,5-tri-O-benzyl-2,6-dideoxy-2,6-methylene-D-glycero-D-gulo-3,6a-cycloheptonic acid

1L-(1,4/5)-3,4,5-tri-O-benzyl-1-{[(tert-butyl)diphenylsilyloxy]methyl}-cyclopent-2-ene-3,4,5-triol

1L-(1,4/5)-3,4,5-tri-O-benzyl-1-{[(tert-butyl)diphenylsilyloxy]methyl}-cyclopent-2-ene-3,4,5-triol

3,4,5-tri-O-benzyl-2,6-dideoxy-2,6-methylene-D-glycero-D-gulo-3,6a-cycloheptonic acid

3,4,5-tri-O-benzyl-2,6-dideoxy-2,6-methylene-D-glycero-D-gulo-3,6a-cycloheptonic acid

1L-(1,2,4/3,5)-3,4,5-tri-O-benzyl-1-{[(tert-butyl)diphenylsilyloxy]methyl}-2-(dimethylamino)cyclopentane-3,4,5-triol

1L-(1,2,4/3,5)-3,4,5-tri-O-benzyl-1-{[(tert-butyl)diphenylsilyloxy]methyl}-2-(dimethylamino)cyclopentane-3,4,5-triol

3,4,5-tri-O-benzyl-2,6-dideoxy-2,6-methylene-D-glycero-D-gulo-3,6a-cycloheptonic acid

3,4,5-tri-O-benzyl-2,6-dideoxy-2,6-methylene-D-glycero-D-gulo-3,6a-cycloheptonic acid

N,N-dimethyl-N-{1L-(1,2,4/3,5)-3,4,5-tri-O-benzyl-1-{[(tert-butyl)diphenylsilyloxy]methyl}cyclopentane-3,4,5-triol-2-yl}amine oxide

N,N-dimethyl-N-{1L-(1,2,4/3,5)-3,4,5-tri-O-benzyl-1-{[(tert-butyl)diphenylsilyloxy]methyl}cyclopentane-3,4,5-triol-2-yl}amine oxide

3,4,5-tri-O-benzyl-2,6-dideoxy-2,6-methylene-D-glycero-D-gulo-3,6a-cycloheptonic acid

3,4,5-tri-O-benzyl-2,6-dideoxy-2,6-methylene-D-glycero-D-gulo-3,6a-cycloheptonic acid

上游原料

1L-(1,4/5)-3,4,5-tri-O-benzyl-1-{[(tert-butyl)diphenylsilyloxy]methyl}-cyclopent-2-ene-3,4,5-triol N,N-dimethyl-N-{1L-(1,2,4/3,5)-3,4,5-tri-O-benzyl-1-{[(tert-butyl)diphenylsilyloxy]methyl}cyclopentane-3,4,5-triol-2-yl}amine oxide (3aR)-4c,5t,6c-tris-benzyloxy-1-methyl-(3ar,6ac)-hexahydro-cyclopenta[c]isoxazole ethyl 3,4,5-tri-O-benzyl-7-O-[(tert-butyl)diphenylsilyl]-2,6-dideoxy-2,6-methylene-D-glycero-D-gulo-3,6a-cycloheptonate 1L-(1,2,4/3,5)-3,4,5-tri-O-benzyl-2-(dimethylamino)-1-(hydroxymethyl)cyclopentane-3,4,5-triol 1L-(1,2,4/3,5)-3,4,5-tri-O-benzyl-1-{[(tert-butyl)diphenylsilyloxy]methyl}-2-(dimethylamino)cyclopentane-3,4,5-triol

下游产品

Acetic acid (1R,2R,3R,4S,5S,6R)-6-azidocarbonyl-3,4,5-tris-benzyloxy-bicyclo[3.1.0]hex-2-ylmethyl ester 2,3,4-tri-O-benzyl-N-[(tert-butoxy)carbonyl]-5a-carba-2,5a-cyclo-β-D-glucopyranosylamine