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Acetic acid (1R,2R,3R,4S,5S,6R)-6-azidocarbonyl-3,4,5-tris-benzyloxy-bicyclo[3.1.0]hex-2-ylmethyl ester

Acetic acid (1R,2R,3R,4S,5S,6R)-6-azidocarbonyl-3,4,5-tris-benzyloxy-bicyclo[3.1.0]hex-2-ylmethyl ester

CAS号：452081-63-9

英文名：Acetic acid (1R,2R,3R,4S,5S,6R)-6-azidocarbonyl-3,4,5-tris-benzyloxy-bicyclo[3.1.0]hex-2-ylmethyl ester

分子式：C31H31N3O6

分子量：541.594

合成路线

3,4,5-tri-O-benzyl-2,6-dideoxy-2,6-methylene-D-glycero-D-gulo-3,6a-cycloheptonic acid

3,4,5-tri-O-benzyl-2,6-dideoxy-2,6-methylene-D-glycero-D-gulo-3,6a-cycloheptonic acid

Acetic acid (1R,2R,3R,4S,5S,6R)-6-azidocarbonyl-3,4,5-tris-benzyloxy-bicyclo[3.1.0]hex-2-ylmethyl ester

Acetic acid (1R,2R,3R,4S,5S,6R)-6-azidocarbonyl-3,4,5-tris-benzyloxy-bicyclo[3.1.0]hex-2-ylmethyl ester

N,N-dimethyl-N-{1L-(1,2,4/3,5)-3,4,5-tri-O-benzyl-1-{[(tert-butyl)diphenylsilyloxy]methyl}cyclopentane-3,4,5-triol-2-yl}amine oxide

N,N-dimethyl-N-{1L-(1,2,4/3,5)-3,4,5-tri-O-benzyl-1-{[(tert-butyl)diphenylsilyloxy]methyl}cyclopentane-3,4,5-triol-2-yl}amine oxide

Acetic acid (1R,2R,3R,4S,5S,6R)-6-azidocarbonyl-3,4,5-tris-benzyloxy-bicyclo[3.1.0]hex-2-ylmethyl ester

Acetic acid (1R,2R,3R,4S,5S,6R)-6-azidocarbonyl-3,4,5-tris-benzyloxy-bicyclo[3.1.0]hex-2-ylmethyl ester

(3aR)-4c,5t,6c-tris-benzyloxy-1-methyl-(3ar,6ac)-hexahydro-cyclopenta[c]isoxazole

(3aR)-4c,5t,6c-tris-benzyloxy-1-methyl-(3ar,6ac)-hexahydro-cyclopenta[c]isoxazole

Acetic acid (1R,2R,3R,4S,5S,6R)-6-azidocarbonyl-3,4,5-tris-benzyloxy-bicyclo[3.1.0]hex-2-ylmethyl ester

Acetic acid (1R,2R,3R,4S,5S,6R)-6-azidocarbonyl-3,4,5-tris-benzyloxy-bicyclo[3.1.0]hex-2-ylmethyl ester

1L-(1,2,4/3,5)-3,4,5-tri-O-benzyl-2-(dimethylamino)-1-(hydroxymethyl)cyclopentane-3,4,5-triol

1L-(1,2,4/3,5)-3,4,5-tri-O-benzyl-2-(dimethylamino)-1-(hydroxymethyl)cyclopentane-3,4,5-triol

Acetic acid (1R,2R,3R,4S,5S,6R)-6-azidocarbonyl-3,4,5-tris-benzyloxy-bicyclo[3.1.0]hex-2-ylmethyl ester

Acetic acid (1R,2R,3R,4S,5S,6R)-6-azidocarbonyl-3,4,5-tris-benzyloxy-bicyclo[3.1.0]hex-2-ylmethyl ester

上游原料

3,4,5-tri-O-benzyl-2,6-dideoxy-2,6-methylene-D-glycero-D-gulo-3,6a-cycloheptonic acid N,N-dimethyl-N-{1L-(1,2,4/3,5)-3,4,5-tri-O-benzyl-1-{[(tert-butyl)diphenylsilyloxy]methyl}cyclopentane-3,4,5-triol-2-yl}amine oxide (3aR)-4c,5t,6c-tris-benzyloxy-1-methyl-(3ar,6ac)-hexahydro-cyclopenta[c]isoxazole 1L-(1,2,4/3,5)-3,4,5-tri-O-benzyl-2-(dimethylamino)-1-(hydroxymethyl)cyclopentane-3,4,5-triol

下游产品

2,3,4-tri-O-benzyl-N-[(tert-butoxy)carbonyl]-5a-carba-2,5a-cyclo-β-D-glucopyranosylamine