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(1S,2S,3R,4R,5R,6S)-1,2,3-Tris-benzyloxy-4-(tert-butyl-diphenyl-silanyloxymethyl)-bicyclo[3.1.0]hexane-6-carbonyl azide

(1S,2S,3R,4R,5R,6S)-1,2,3-Tris-benzyloxy-4-(tert-butyl-diphenyl-silanyloxymethyl)-bicyclo[3.1.0]hexane-6-carbonyl azide

CAS号：452081-64-0

英文名：(1S,2S,3R,4R,5R,6S)-1,2,3-Tris-benzyloxy-4-(tert-butyl-diphenyl-silanyloxymethyl)-bicyclo[3.1.0]hexane-6-carbonyl azide

分子式：C45H47N3O5Si

分子量：737.957

合成路线

3,4,5-tri-O-benzyl-7-O-[(tert-butyl)diphenylsilyl]-2,6-dideoxy-2,6-methylene-3,6a-cyclo-D-glycero-D-ido-heptonohydrazide

3,4,5-tri-O-benzyl-7-O-[(tert-butyl)diphenylsilyl]-2,6-dideoxy-2,6-methylene-3,6a-cyclo-D-glycero-D-ido-heptonohydrazide

(1S,2S,3R,4R,5R,6S)-1,2,3-Tris-benzyloxy-4-(tert-butyl-diphenyl-silanyloxymethyl)-bicyclo[3.1.0]hexane-6-carbonyl azide

(1S,2S,3R,4R,5R,6S)-1,2,3-Tris-benzyloxy-4-(tert-butyl-diphenyl-silanyloxymethyl)-bicyclo[3.1.0]hexane-6-carbonyl azide

(3aR)-4c,5t,6c-tris-benzyloxy-1-methyl-(3ar,6ac)-hexahydro-cyclopenta[c]isoxazole

(3aR)-4c,5t,6c-tris-benzyloxy-1-methyl-(3ar,6ac)-hexahydro-cyclopenta[c]isoxazole

(1S,2S,3R,4R,5R,6S)-1,2,3-Tris-benzyloxy-4-(tert-butyl-diphenyl-silanyloxymethyl)-bicyclo[3.1.0]hexane-6-carbonyl azide

(1S,2S,3R,4R,5R,6S)-1,2,3-Tris-benzyloxy-4-(tert-butyl-diphenyl-silanyloxymethyl)-bicyclo[3.1.0]hexane-6-carbonyl azide

1L-(1,2,4/3,5)-3,4,5-tri-O-benzyl-2-(dimethylamino)-1-(hydroxymethyl)cyclopentane-3,4,5-triol

1L-(1,2,4/3,5)-3,4,5-tri-O-benzyl-2-(dimethylamino)-1-(hydroxymethyl)cyclopentane-3,4,5-triol

(1S,2S,3R,4R,5R,6S)-1,2,3-Tris-benzyloxy-4-(tert-butyl-diphenyl-silanyloxymethyl)-bicyclo[3.1.0]hexane-6-carbonyl azide

(1S,2S,3R,4R,5R,6S)-1,2,3-Tris-benzyloxy-4-(tert-butyl-diphenyl-silanyloxymethyl)-bicyclo[3.1.0]hexane-6-carbonyl azide

1L-(1,4/5)-3,4,5-tri-O-benzyl-1-{[(tert-butyl)diphenylsilyloxy]methyl}-cyclopent-2-ene-3,4,5-triol

1L-(1,4/5)-3,4,5-tri-O-benzyl-1-{[(tert-butyl)diphenylsilyloxy]methyl}-cyclopent-2-ene-3,4,5-triol

(1S,2S,3R,4R,5R,6S)-1,2,3-Tris-benzyloxy-4-(tert-butyl-diphenyl-silanyloxymethyl)-bicyclo[3.1.0]hexane-6-carbonyl azide

(1S,2S,3R,4R,5R,6S)-1,2,3-Tris-benzyloxy-4-(tert-butyl-diphenyl-silanyloxymethyl)-bicyclo[3.1.0]hexane-6-carbonyl azide

1L-(1,2,4/3,5)-3,4,5-tri-O-benzyl-1-{[(tert-butyl)diphenylsilyloxy]methyl}-2-(dimethylamino)cyclopentane-3,4,5-triol

1L-(1,2,4/3,5)-3,4,5-tri-O-benzyl-1-{[(tert-butyl)diphenylsilyloxy]methyl}-2-(dimethylamino)cyclopentane-3,4,5-triol

(1S,2S,3R,4R,5R,6S)-1,2,3-Tris-benzyloxy-4-(tert-butyl-diphenyl-silanyloxymethyl)-bicyclo[3.1.0]hexane-6-carbonyl azide

(1S,2S,3R,4R,5R,6S)-1,2,3-Tris-benzyloxy-4-(tert-butyl-diphenyl-silanyloxymethyl)-bicyclo[3.1.0]hexane-6-carbonyl azide

N,N-dimethyl-N-{1L-(1,2,4/3,5)-3,4,5-tri-O-benzyl-1-{[(tert-butyl)diphenylsilyloxy]methyl}cyclopentane-3,4,5-triol-2-yl}amine oxide

N,N-dimethyl-N-{1L-(1,2,4/3,5)-3,4,5-tri-O-benzyl-1-{[(tert-butyl)diphenylsilyloxy]methyl}cyclopentane-3,4,5-triol-2-yl}amine oxide

(1S,2S,3R,4R,5R,6S)-1,2,3-Tris-benzyloxy-4-(tert-butyl-diphenyl-silanyloxymethyl)-bicyclo[3.1.0]hexane-6-carbonyl azide

(1S,2S,3R,4R,5R,6S)-1,2,3-Tris-benzyloxy-4-(tert-butyl-diphenyl-silanyloxymethyl)-bicyclo[3.1.0]hexane-6-carbonyl azide

ethyl 3,4,5-tri-O-benzyl-7-O-[(tert-butyl)diphenylsilyl]-2,6-dideoxy-2,6-methylene-D-glycero-D-ido-3,6a-cycloheptonate

ethyl 3,4,5-tri-O-benzyl-7-O-[(tert-butyl)diphenylsilyl]-2,6-dideoxy-2,6-methylene-D-glycero-D-ido-3,6a-cycloheptonate

(1S,2S,3R,4R,5R,6S)-1,2,3-Tris-benzyloxy-4-(tert-butyl-diphenyl-silanyloxymethyl)-bicyclo[3.1.0]hexane-6-carbonyl azide

(1S,2S,3R,4R,5R,6S)-1,2,3-Tris-benzyloxy-4-(tert-butyl-diphenyl-silanyloxymethyl)-bicyclo[3.1.0]hexane-6-carbonyl azide

上游原料

1L-(1,4/5)-3,4,5-tri-O-benzyl-1-{[(tert-butyl)diphenylsilyloxy]methyl}-cyclopent-2-ene-3,4,5-triol ethyl 3,4,5-tri-O-benzyl-7-O-[(tert-butyl)diphenylsilyl]-2,6-dideoxy-2,6-methylene-D-glycero-D-ido-3,6a-cycloheptonate 3,4,5-tri-O-benzyl-7-O-[(tert-butyl)diphenylsilyl]-2,6-dideoxy-2,6-methylene-3,6a-cyclo-D-glycero-D-ido-heptonohydrazide N,N-dimethyl-N-{1L-(1,2,4/3,5)-3,4,5-tri-O-benzyl-1-{[(tert-butyl)diphenylsilyloxy]methyl}cyclopentane-3,4,5-triol-2-yl}amine oxide (3aR)-4c,5t,6c-tris-benzyloxy-1-methyl-(3ar,6ac)-hexahydro-cyclopenta[c]isoxazole 1L-(1,2,4/3,5)-3,4,5-tri-O-benzyl-2-(dimethylamino)-1-(hydroxymethyl)cyclopentane-3,4,5-triol 1L-(1,2,4/3,5)-3,4,5-tri-O-benzyl-1-{[(tert-butyl)diphenylsilyloxy]methyl}-2-(dimethylamino)cyclopentane-3,4,5-triol

下游产品

2,3,4-tri-O-benzyl-N-[(tert-butoxy)carbonyl]-5a-carba-2,5a-cyclo-α-D-glucopyranosylamine