百科

Dithiocarbonic acid O-{(1S,2S,4S,5S)-4-[2-((S)-1,3-dimethyl-4-oxo-cyclohex-2-enyl)-ethyl]-4,6,6-trimethyl-bicyclo[3.1.1]hept-2-yl} ester S-methyl ester

CAS号：455252-83-2

英文名：Dithiocarbonic acid O-{(1S,2S,4S,5S)-4-[2-((S)-1,3-dimethyl-4-oxo-cyclohex-2-enyl)-ethyl]-4,6,6-trimethyl-bicyclo[3.1.1]hept-2-yl} ester S-methyl ester

分子式：C22H34O2S2

分子量：394.634

合成路线

455252-78-5

(R)-6-[(1S,2S,4S,5S)-4-(tert-Butyl-dimethyl-silanyloxy)-2,6,6-trimethyl-bicyclo[3.1.1]hept-2-yl]-4-methyl-hexanal

455252-83-2

Dithiocarbonic acid O-{(1S,2S,4S,5S)-4-[2-((S)-1,3-dimethyl-4-oxo-cyclohex-2-enyl)-ethyl]-4,6,6-trimethyl-bicyclo[3.1.1]hept-2-yl} ester S-methyl ester

455252-88-7

(R)-8-[(1S,2S,4S,5S)-4-(tert-Butyl-dimethyl-silanyloxy)-2,6,6-trimethyl-bicyclo[3.1.1]hept-2-yl]-6-methyl-octan-3-ol

455252-83-2

Dithiocarbonic acid O-{(1S,2S,4S,5S)-4-[2-((S)-1,3-dimethyl-4-oxo-cyclohex-2-enyl)-ethyl]-4,6,6-trimethyl-bicyclo[3.1.1]hept-2-yl} ester S-methyl ester

55314-73-3

(S)-citronellyl magnesium bromide

455252-83-2

Dithiocarbonic acid O-{(1S,2S,4S,5S)-4-[2-((S)-1,3-dimethyl-4-oxo-cyclohex-2-enyl)-ethyl]-4,6,6-trimethyl-bicyclo[3.1.1]hept-2-yl} ester S-methyl ester

455252-80-9

tert-Butyl-{(1S,2S,4S,5S)-4-[2-((R)-3-ethyl-1-methyl-cyclopent-2-enyl)-ethyl]-4,6,6-trimethyl-bicyclo[3.1.1]hept-2-yloxy}-dimethyl-silane

455252-83-2

Dithiocarbonic acid O-{(1S,2S,4S,5S)-4-[2-((S)-1,3-dimethyl-4-oxo-cyclohex-2-enyl)-ethyl]-4,6,6-trimethyl-bicyclo[3.1.1]hept-2-yl} ester S-methyl ester

455252-81-0

(S)-4-{2-[(1S,2S,4S,5S)-4-(tert-Butyl-dimethyl-silanyloxy)-2,6,6-trimethyl-bicyclo[3.1.1]hept-2-yl]-ethyl}-2,4-dimethyl-cyclohex-2-enone

455252-83-2

Dithiocarbonic acid O-{(1S,2S,4S,5S)-4-[2-((S)-1,3-dimethyl-4-oxo-cyclohex-2-enyl)-ethyl]-4,6,6-trimethyl-bicyclo[3.1.1]hept-2-yl} ester S-methyl ester

上游原料

(S)-4-{2-[(1S,2S,4S,5S)-4-(tert-Butyl-dimethyl-silanyloxy)-2,6,6-trimethyl-bicyclo[3.1.1]hept-2-yl]-ethyl}-2,4-dimethyl-cyclohex-2-enone (R)-8-[(1S,2S,4S,5S)-4-(tert-Butyl-dimethyl-silanyloxy)-2,6,6-trimethyl-bicyclo[3.1.1]hept-2-yl]-6-methyl-octan-3-ol (R)-6-[(1S,2S,4S,5S)-4-(tert-Butyl-dimethyl-silanyloxy)-2,6,6-trimethyl-bicyclo[3.1.1]hept-2-yl]-4-methyl-hexanal (S)-citronellyl magnesium bromide tert-Butyl-{(1S,2S,4S,5S)-4-[2-((R)-3-ethyl-1-methyl-cyclopent-2-enyl)-ethyl]-4,6,6-trimethyl-bicyclo[3.1.1]hept-2-yloxy}-dimethyl-silane

下游产品

(4R,5R)-5-[2-((S)-1,3-Dimethyl-4-oxo-cyclohex-2-enyl)-ethyl]-4-isopropyl-5-methyl-cyclopent-1-enecarbaldehyde