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(E)-(4R,5S)-4-Benzyloxy-5-[(E)-(S)-5-(tert-butyl-dimethyl-silanyloxy)-hex-2-enoyloxy]-hex-2-enoic acid 2,2,2-trichloro-ethyl ester

(E)-(4R,5S)-4-Benzyloxy-5-[(E)-(S)-5-(tert-butyl-dimethyl-silanyloxy)-hex-2-enoyloxy]-hex-2-enoic acid 2,2,2-trichloro-ethyl ester

CAS号：455934-71-1

英文名：(E)-(4R,5S)-4-Benzyloxy-5-[(E)-(S)-5-(tert-butyl-dimethyl-silanyloxy)-hex-2-enoyloxy]-hex-2-enoic acid 2,2,2-trichloro-ethyl ester

分子式：C27H39Cl3O6Si

分子量：594.039

合成路线

(E)-(4R,5S)-5-(tert-Butyl-dimethyl-silanyloxy)-4-methanesulfonyloxy-hex-2-enoic acid methyl ester

(E)-(4R,5S)-5-(tert-Butyl-dimethyl-silanyloxy)-4-methanesulfonyloxy-hex-2-enoic acid methyl ester

(E)-(4R,5S)-4-Benzyloxy-5-[(E)-(S)-5-(tert-butyl-dimethyl-silanyloxy)-hex-2-enoyloxy]-hex-2-enoic acid 2,2,2-trichloro-ethyl ester

(E)-(4R,5S)-4-Benzyloxy-5-[(E)-(S)-5-(tert-butyl-dimethyl-silanyloxy)-hex-2-enoyloxy]-hex-2-enoic acid 2,2,2-trichloro-ethyl ester

(4R,5S,E)-methyl 5-(tert-butyldimethylsilyloxy)-4-hydroxyhex-2-enoate

(4R,5S,E)-methyl 5-(tert-butyldimethylsilyloxy)-4-hydroxyhex-2-enoate

(E)-(4R,5S)-4-Benzyloxy-5-[(E)-(S)-5-(tert-butyl-dimethyl-silanyloxy)-hex-2-enoyloxy]-hex-2-enoic acid 2,2,2-trichloro-ethyl ester

(E)-(4R,5S)-4-Benzyloxy-5-[(E)-(S)-5-(tert-butyl-dimethyl-silanyloxy)-hex-2-enoyloxy]-hex-2-enoic acid 2,2,2-trichloro-ethyl ester

上游原料

(E)-(4R,5S)-5-(tert-Butyl-dimethyl-silanyloxy)-4-methanesulfonyloxy-hex-2-enoic acid methyl ester (4R,5S,E)-methyl 5-(tert-butyldimethylsilyloxy)-4-hydroxyhex-2-enoate

下游产品

(E)-(4R,5S)-4-Benzyloxy-5-((E)-(S)-5-hydroxy-hex-2-enoyloxy)-hex-2-enoic acid 2,2,2-trichloro-ethyl ester (E)-(4R,5S)-4-Benzyloxy-5-{(E)-(S)-5-[(R)-3-(tert-butyl-dimethyl-silanyloxy)-butyryloxy]-hex-2-enoyloxy}-hex-2-enoic acid 2,2,2-trichloro-ethyl ester (E)-(4R,5S)-4-Benzyloxy-5-[(E)-(S)-5-((R)-3-hydroxy-butyryloxy)-hex-2-enoyloxy]-hex-2-enoic acid 2,2,2-trichloro-ethyl ester (+)-macrosphelide G (E)-(4R,5S)-4-Benzyloxy-5-[(E)-(S)-5-((R)-3-hydroxy-butyryloxy)-hex-2-enoyloxy]-hex-2-enoic acid