百科

(2R,3R,5S,6R)-3-(tert-Butyl-dimethyl-silanyloxy)-5-methoxy-6-methoxymethyl-2-methyl-tetrahydro-pyran-2-carbaldehyde

(2R,3R,5S,6R)-3-(tert-Butyl-dimethyl-silanyloxy)-5-methoxy-6-methoxymethyl-2-methyl-tetrahydro-pyran-2-carbaldehyde

CAS号：455958-49-3

英文名：(2R,3R,5S,6R)-3-(tert-Butyl-dimethyl-silanyloxy)-5-methoxy-6-methoxymethyl-2-methyl-tetrahydro-pyran-2-carbaldehyde

分子式：C16H32O5Si

分子量：332.508

合成路线

(2S,3R,5S,6R)-2-(hydroxymethyl)-5-methoxy-6-(methoxymethyl)-2-methyltetrahydro-2H-pyran-3-ol

(2S,3R,5S,6R)-2-(hydroxymethyl)-5-methoxy-6-(methoxymethyl)-2-methyltetrahydro-2H-pyran-3-ol

(2R,3R,5S,6R)-3-(tert-Butyl-dimethyl-silanyloxy)-5-methoxy-6-methoxymethyl-2-methyl-tetrahydro-pyran-2-carbaldehyde

(2R,3R,5S,6R)-3-(tert-Butyl-dimethyl-silanyloxy)-5-methoxy-6-methoxymethyl-2-methyl-tetrahydro-pyran-2-carbaldehyde

(4aS,6R,7S,8aR)-6-Hydroxymethyl-2,2,4a-trimethyl-hexahydro-pyrano[3,2-d][1,3]dioxin-7-ol

(4aS,6R,7S,8aR)-6-Hydroxymethyl-2,2,4a-trimethyl-hexahydro-pyrano[3,2-d][1,3]dioxin-7-ol

(2R,3R,5S,6R)-3-(tert-Butyl-dimethyl-silanyloxy)-5-methoxy-6-methoxymethyl-2-methyl-tetrahydro-pyran-2-carbaldehyde

(2R,3R,5S,6R)-3-(tert-Butyl-dimethyl-silanyloxy)-5-methoxy-6-methoxymethyl-2-methyl-tetrahydro-pyran-2-carbaldehyde

上游原料

(4aS,6R,7S,8aR)-6-Hydroxymethyl-2,2,4a-trimethyl-hexahydro-pyrano[3,2-d][1,3]dioxin-7-ol (2S,3R,5S,6R)-2-(hydroxymethyl)-5-methoxy-6-(methoxymethyl)-2-methyltetrahydro-2H-pyran-3-ol

下游产品

tert-Butyl-[(2S,3R,5S,6R)-5-methoxy-2-((E)-(R)-5-methoxymethoxy-3-methyl-pent-1-enyl)-6-methoxymethyl-2-methyl-tetrahydro-pyran-3-yloxy]-dimethyl-silane (4aR,6R,7S,8aR)-7-Methoxy-2-[(2R,3S)-3-(4-methoxy-benzyloxy)-tetrahydro-pyran-2-ylmethyl]-6-methoxymethyl-4a-methyl-6,7,8,8a-tetrahydro-4aH-pyrano[3,2-b]pyran-4-one (4aS,5aR,6R,6aS,8R,9S,10aR,11aS,12aR)-4a,9-Dimethoxy-8-methoxymethyl-6a-methyl-tetradecahydro-1,5,7,11-tetraoxa-naphthacen-6-ol