百科

(1R,3S)-3-[(2S,5S,6S)-6-((1S)-2-hydroxy-1-methylethyl)-5-methyltetrahydro-2H-pyran-2-yl]-1-methyl-2-oxobutyl benzoate

(1R,3S)-3-[(2S,5S,6S)-6-((1S)-2-hydroxy-1-methylethyl)-5-methyltetrahydro-2H-pyran-2-yl]-1-methyl-2-oxobutyl benzoate

CAS号：460997-50-6

英文名：(1R,3S)-3-[(2S,5S,6S)-6-((1S)-2-hydroxy-1-methylethyl)-5-methyltetrahydro-2H-pyran-2-yl]-1-methyl-2-oxobutyl benzoate

分子式：C21H30O5

分子量：362.46

合成路线

ethyl (E),(4R)-4-((1R,2R)-2-{[(tert-butyldiphenylsilyl)oxy]methyl}cyclopropyl)pent-2-enoate

ethyl (E),(4R)-4-((1R,2R)-2-{[(tert-butyldiphenylsilyl)oxy]methyl}cyclopropyl)pent-2-enoate

(1R,3S)-3-[(2S,5S,6S)-6-((1S)-2-hydroxy-1-methylethyl)-5-methyltetrahydro-2H-pyran-2-yl]-1-methyl-2-oxobutyl benzoate

(1R,3S)-3-[(2S,5S,6S)-6-((1S)-2-hydroxy-1-methylethyl)-5-methyltetrahydro-2H-pyran-2-yl]-1-methyl-2-oxobutyl benzoate

(4S)-4-((1R,2R)-2-{[(tert-butyldiphenylsilyl)oxy]methyl}cyclopropyl)pentanal

(4S)-4-((1R,2R)-2-{[(tert-butyldiphenylsilyl)oxy]methyl}cyclopropyl)pentanal

(1R,3S)-3-[(2S,5S,6S)-6-((1S)-2-hydroxy-1-methylethyl)-5-methyltetrahydro-2H-pyran-2-yl]-1-methyl-2-oxobutyl benzoate

(1R,3S)-3-[(2S,5S,6S)-6-((1S)-2-hydroxy-1-methylethyl)-5-methyltetrahydro-2H-pyran-2-yl]-1-methyl-2-oxobutyl benzoate

(1S,3S,4S,7S)-7-((1R,2R)-2-{[(tert-butyldiphenylsilyl)oxy]methyl}cyclopropyl)-4-hydroxy-1,3-dimethyl-2-oxooctyl benzoate

(1S,3S,4S,7S)-7-((1R,2R)-2-{[(tert-butyldiphenylsilyl)oxy]methyl}cyclopropyl)-4-hydroxy-1,3-dimethyl-2-oxooctyl benzoate

(1R,3S)-3-[(2S,5S,6S)-6-((1S)-2-hydroxy-1-methylethyl)-5-methyltetrahydro-2H-pyran-2-yl]-1-methyl-2-oxobutyl benzoate

(1R,3S)-3-[(2S,5S,6S)-6-((1S)-2-hydroxy-1-methylethyl)-5-methyltetrahydro-2H-pyran-2-yl]-1-methyl-2-oxobutyl benzoate

上游原料

(4S)-4-((1R,2R)-2-{[(tert-butyldiphenylsilyl)oxy]methyl}cyclopropyl)pentanal ethyl (E),(4R)-4-((1R,2R)-2-{[(tert-butyldiphenylsilyl)oxy]methyl}cyclopropyl)pent-2-enoate (1S,3S,4S,7S)-7-((1R,2R)-2-{[(tert-butyldiphenylsilyl)oxy]methyl}cyclopropyl)-4-hydroxy-1,3-dimethyl-2-oxooctyl benzoate

下游产品

(2S)-2-((2S,5S,6S)-6-[(1S)-2-[(tert-butyldiphenylsilyl)oxy]-1-methylethyl]-5-methyltetrahydro-2H-pyran-2-yl)propanoic acid (S)-2-{(2S,5S,6S)-6-[(S)-2-(tert-Butyl-diphenyl-silanyloxy)-1-methyl-ethyl]-5-methyl-tetrahydro-pyran-2-yl}-propionaldehyde