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(2R,4R,5S,6S)-7-(4-Methoxy-benzyloxy)-4,6-dimethyl-5-triethylsilanyloxy-heptane-2,3-diol

(2R,4R,5S,6S)-7-(4-Methoxy-benzyloxy)-4,6-dimethyl-5-triethylsilanyloxy-heptane-2,3-diol

CAS号：473758-99-5

英文名：(2R,4R,5S,6S)-7-(4-Methoxy-benzyloxy)-4,6-dimethyl-5-triethylsilanyloxy-heptane-2,3-diol

分子式：C23H42O5Si

分子量：426.662

合成路线

(−)-(2R,4S,5S,6S)-5-hydroxy-7-((4-methoxybenzyl)oxy)-4,6-dimethyl-3-oxoheptan-2-yl benzoate

(−)-(2R,4S,5S,6S)-5-hydroxy-7-((4-methoxybenzyl)oxy)-4,6-dimethyl-3-oxoheptan-2-yl benzoate

(2R,4R,5S,6S)-7-(4-Methoxy-benzyloxy)-4,6-dimethyl-5-triethylsilanyloxy-heptane-2,3-diol

(2R,4R,5S,6S)-7-(4-Methoxy-benzyloxy)-4,6-dimethyl-5-triethylsilanyloxy-heptane-2,3-diol

(R,E)-3-((dicyclohexylboraneyl)oxy)pent-3-en-2-yl benzoate

(R,E)-3-((dicyclohexylboraneyl)oxy)pent-3-en-2-yl benzoate

(2R,4R,5S,6S)-7-(4-Methoxy-benzyloxy)-4,6-dimethyl-5-triethylsilanyloxy-heptane-2,3-diol

(2R,4R,5S,6S)-7-(4-Methoxy-benzyloxy)-4,6-dimethyl-5-triethylsilanyloxy-heptane-2,3-diol

上游原料

(R,E)-3-((dicyclohexylboraneyl)oxy)pent-3-en-2-yl benzoate (−)-(2R,4S,5S,6S)-5-hydroxy-7-((4-methoxybenzyl)oxy)-4,6-dimethyl-3-oxoheptan-2-yl benzoate

下游产品

N-((Z)-(3R,4R,5R)-3,5-Dimethyl-6-oxo-4-triethylsilanyloxy-hex-1-enyl)-N-methyl-formamide 2-Dimethylamino-propionic acid (Z)-(2S,3R,4R)-6-(formyl-methyl-amino)-2,4-dimethyl-3-triethylsilanyloxy-hex-5-enyl ester Isobutyric acid (5E,11Z)-(1S,2R,3S,4S,8R,9R,10R)-1-(2-benzyloxy-ethyl)-12-(formyl-methyl-amino)-2,4,8,10-tetramethyl-7-oxo-3,9-bis-triethylsilanyloxy-dodeca-5,11-dienyl ester N-[(Z)-(3R,4R,5S)-6-(4-Methoxy-benzyloxy)-3,5-dimethyl-4-triethylsilanyloxy-hex-1-enyl]-N-methyl-formamide N-((Z)-(3R,4R,5S)-6-Hydroxy-3,5-dimethyl-4-triethylsilanyloxy-hex-1-enyl)-N-methyl-formamide Isobutyric acid (Z)-(1S,2R,3S,4S,8R,9R,10R)-1-(2-benzyloxy-ethyl)-12-(formyl-methyl-amino)-9-hydroxy-2,4,8,10-tetramethyl-7-oxo-3-triethylsilanyloxy-dodec-11-enyl ester Isobutyric acid (5E,11Z)-(1S,2R,3S,4S,8R,9R,10R)-1-(2-benzyloxy-ethyl)-12-(formyl-methyl-amino)-9-hydroxy-2,4,8,10-tetramethyl-7-oxo-3-triethylsilanyloxy-dodeca-5,11-dienyl ester (2S,3S,4S)-5-(4-methoxybenzyloxy)-2,4-dimethyl-3-(triethylsilyloxy)pentanal Isobutyric acid (5E,11Z)-(1S,2S,3S,4S,8R,9R,10R)-1-(2-benzyloxy-ethyl)-12-(formyl-methyl-amino)-3-hydroxy-2,4,8,10-tetramethyl-7-oxo-9-triethylsilanyloxy-dodeca-5,11-dienyl ester [(Z)-(3R,4R,5R)-7-(Formyl-methyl-amino)-3,5-dimethyl-2-oxo-4-triethylsilanyloxy-hept-6-enyl]-phosphonic acid dimethyl ester